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Hole Burning Imaging Studies of Cancerous and Analogous Normal Ovarian Tissues Utilizing Organelle Specific Dyes

Description: Presented in this dissertation is the successful demonstration that nonphotochemical hole burning (NPWB) imaging can be used to study in vitro tissue cellular systems for discerning differences in cellular ultrastructures due to cancer development. This has been accomplished with the surgically removed cancerous ovarian and analogous normal peritoneal tissues from the same patient and the application of a fluorescent mitochondrion specific dye, Molecular Probe MitoFluor Far Red 680 (MF680), com… more
Date: December 19, 2004
Creator: Matsuzaki, Satoshi
Partner: UNT Libraries Government Documents Department
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Studies in ion source development for application in heavy ion fusion

Description: The overall purpose of these experiments is to contribute to the development of ion injector technology in order to produce a driver for use in a heavy-ion-fusion (HIF) power generating facility. The overall beam requirements for HIF are quite demanding; a short list of the constraints is the following: (1) Low cost (a large portion of overall cost will come from the beam system); (2) Bright, low emittance beam; (3) Total beam energy 5MJ; (4) Spot size 3mm (radius); (5) Pulse Duration 10ns; (6)… more
Date: May 30, 2004
Creator: Kapica, Jonathan G.
Partner: UNT Libraries Government Documents Department
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Diffusion in silicon isotope heterostructures

Description: The simultaneous diffusion of Si and the dopants B, P, and As has been studied by the use of a multilayer structure of isotopically enriched Si. This structure, consisting of 5 pairs of 120 nm thick natural Si and {sup 28}Si enriched layers, enables the observation of {sup 30}Si self-diffusion from the natural layers into the {sup 28}Si enriched layers, as well as dopant diffusion from an implanted source in an amorphous Si cap layer, via Secondary Ion Mass Spectrometry (SIMS). The dopant diffu… more
Date: May 14, 2004
Creator: Silvestri, Hughes Howland
Partner: UNT Libraries Government Documents Department
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Nuclear reactions with 11C and 14O radioactive ion beams

Description: Radioactive ion beams (RIBs) have been shown to be a useful tool for studying proton-rich nuclides near and beyond the proton dripline and for evaluating nuclear models. To take full advantage of RIBs, Elastic Resonance Scattering in Inverse Kinematics with Thick Targets (ERSIKTT), has proven to be a reliable experimental tool for investigations of proton unbound nuclei. Following several years of effort, Berkeley Experiments with Accelerated Radioactive Species (BEARS), a RIBs capability, has … more
Date: December 9, 2004
Creator: Guo, Fanqing
Partner: UNT Libraries Government Documents Department
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Femtosecond nonlinear spectroscopy at surfaces: Second-harmonic probing of hole burning at the Si(111)7x7 surface and fourier-transform sum-frequency vibrational spectroscopy

Description: The high temporal resolution and broad bandwidth of a femtosecond laser system are exploited in a pair of nonlinear optical studies of surfaces. The dephasing dynamics of resonances associated with the adatom dangling bonds of the Si(111)7 x 7 surface are explored by transient second-harmonic hole burning, a process that can be described as a fourth-order nonlinear optical process. Spectral holes produced by a 100 fs pump pulse at about 800 nm are probed by the second harmonic signal of a 100 f… more
Date: November 24, 2004
Creator: McGuire, John Andrew
Partner: UNT Libraries Government Documents Department
open access

GaAs Blocked-Impurity-Band Detectors for Far-Infrared Astronomy

Description: High-purity and doped GaAs films have been grown by Liquid-phase epitaxy (LPE) for development of a blocked impurity band (BIB) detector for far-infrared radiation. The film growth process developed has resulted in the capability to grow GaAs with a net active impurity concentration below 1 x 10{sup 13} cm{sup -3}, ideal for the blocking layer of the BIB detector. The growth of n-type LPE GaAs films with donor concentrations below the metal-insulator transition, as required for the absorbing la… more
Date: December 21, 2004
Creator: Cardozo, Benjamin Lewin
Partner: UNT Libraries Government Documents Department
open access

Solidification at the High and Low Rate Extreme

Description: The microstructures formed upon solidification are strongly influenced by the imposed growth rates on an alloy system. Depending on the characteristics of the solidification process, a wide range of growth rates is accessible. The prevailing solidification mechanisms, and thus the final microstructure of the alloy, are governed by these imposed growth rates. At the high rate extreme, for instance, one can have access to novel microstructures that are unattainable at low growth rates. While the … more
Date: December 19, 2004
Creator: Meco, Halim
Partner: UNT Libraries Government Documents Department
open access

Fabrication of Ceramic Layer-by-Layer Infrared Wavelength Photonic Band Gap Crystals

Description: Photonic band gap (PBG) crystals, also known as photonic crystals, are periodic dielectric structures which form a photonic band gap that prohibit the propagation of electromagnetic (EM) waves of certain frequencies at any incident angles. Photonic crystals have several potential applications including zero-threshold semiconductor lasers, the inhibition of spontaneous emission, dielectric mirrors, and wavelength filters. If defect states are introduced in the crystals, light can be guided from … more
Date: December 19, 2004
Creator: Kang, Henry Hao-Chuan
Partner: UNT Libraries Government Documents Department
open access

Benchmarking: More Aspects of High Performance Computing

Description: The original HPL algorithm makes the assumption that all data can be fit entirely in the main memory. This assumption will obviously give a good performance due to the absence of disk I/O. However, not all applications can fit their entire data in memory. These applications which require a fair amount of I/O to move data to and from main memory and secondary storage, are more indicative of usage of an Massively Parallel Processor (MPP) System. Given this scenario a well designed I/O architectur… more
Date: December 19, 2004
Creator: Ravindrudu, Rahul
Partner: UNT Libraries Government Documents Department
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Coupling Temperature Control with Electrochemically Modulated Liquid Chromatography: Fundamental Aspects and Applications

Description: The primary focus of the doctoral research presented herein has been the integration of temperature control into electrochemically modulated liquid chromatography (EMLC). The combination of temperature control and the tunable characteristics of carbonaceous EMLC stationary phases have been invaluable in deciphering the subtleties of the retention mechanism. The effects of temperature and E{sub app} on the retention of several naphthalene disulfonates were therefore examined by the van' Hoff rel… more
Date: December 19, 2004
Creator: Ponton, Lisa M.
Partner: UNT Libraries Government Documents Department
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Morphological Control of Multifunctional Mesoporous Silica Nanomaterials for Catalysis Applications

Description: I found an efficient method to control the morphology of the organically monofunctionalized mesoporous silica materials by introducing different types of organoalkoxysilanes in a base-catalyzed co-condensation reaction. The monofunctionalized materials exhibit different particle morphologies relative to the pure MCM-41 material. The concentration dependence of the morphology is a critical factor to determine the final particle shape. A proposed mechanism of the shape evolution is also offered. … more
Date: December 19, 2004
Creator: Huh, Seong
Partner: UNT Libraries Government Documents Department
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Recombination and propagation of quasiparticles in cuprate superconductors

Description: Rapid developments in time-resolved optical spectroscopy have led to renewed interest in the nonequilibrium state of superconductors and other highly correlated electron materials. In these experiments, the nonequilibrium state is prepared by the absorption of short (less than 100 fs) laser pulses, typically in the near-infrared, that perturb the density and energy distribution of quasiparticles. The evolution of the nonequilibrium state is probed by time resolving the changes in the optical re… more
Date: May 20, 2004
Creator: Gedik, Nuh
Partner: UNT Libraries Government Documents Department
open access

Rates and progenitors of type Ia supernovae

Description: The remarkable uniformity of Type Ia supernovae has allowed astronomers to use them as distance indicators to measure the properties and expansion history of the Universe. However, Type Ia supernovae exhibit intrinsic variation in both their spectra and observed brightness. The brightness variations have been approximately corrected by various methods, but there remain intrinsic variations that limit the statistical power of current and future observations of distant supernovae for cosmological… more
Date: August 16, 2004
Creator: Wood-Vasey, William Michael
Partner: UNT Libraries Government Documents Department
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Development of Chiral LC-MS Methods for small Molecules and Their Applications in the Analysis of Enantiomeric Composition and Pharmacokinetic Studies

Description: The purpose of this research was to develop sensitive LC-MS methods for enantiomeric separation and detection, and then apply these methods for determination of enantiomeric composition and for the study of pharmacokinetic and pharmacodynamic properties of a chiral nutraceutical. Our first study, evaluated the use of reverse phase and polar organic mode for chiral LC-API/MS method development. Reverse phase methods containing high water were found to decrease ionization efficiency in electrospr… more
Date: December 19, 2004
Creator: Desai, Meera Jay
Partner: UNT Libraries Government Documents Department
open access

Microstructural Development in Al-Si Powder During Rapid Solidification

Description: Powder metallurgy has become an increasingly important form of metal processing because of its ability to produce materials with superior mechanical properties. These properties are due in part to the unique and often desirable microstructures which arise as a result of the extreme levels of undercooling achieved, especially in the finest size powder, and the subsequent rapid solidification which occurs. A better understanding of the fundamental processes of nucleation and growth is required to… more
Date: December 19, 2004
Creator: Genau, Amber Lynn
Partner: UNT Libraries Government Documents Department
open access

Critical Behavior of Thermal Expansion and Magnetostriction in the Vicinity of the First order transition at the Curie Point of Gd5(SixGe1-x)4

Description: Thermal expansion (TE) and magnetostriction (MS) measurements have been conducted for Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} with a series of x values to study its critical behavior in the vicinity of transition temperatures. It was found that the Curie temperature of Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} for x 0 {approx} 0.5 is dependent on magnetic field, direction of change of temperature (Tc on cooling was lower than Tc on heating), purity of Gd starting material, compositions, material pr… more
Date: December 19, 2004
Creator: Han, Mangui
Partner: UNT Libraries Government Documents Department
open access

Catalyzed hydrogenation of nitrogen and ethylene on metal (Fe, Pt) single crystal surfaces and effects of coadsorption: A sum frequency generation vibrational spectroscopy study

Description: High-pressure catalytic reactions and associated processes, such as adsorption have been studied on a molecular level on single crystal surfaces. Sum Frequency Generation (SFG) vibrational spectroscopy together with Auger Electron Spectroscopy (AES), Temperature Programmed Desorption (TPD) and Gas Chromatography (GC) were used to investigate the nature of species on catalytic surfaces and to measure the catalytic reaction rates. Special attention has been directed at studying high-pressure reac… more
Date: December 15, 2004
Creator: Westerberg, Staffan Per Gustav
Partner: UNT Libraries Government Documents Department
open access

Ultrasonic Concentration in a Line-Driven Cylindrical Tube

Description: The fractionation of particles from their suspending fluid or noninvasive micromanipulation of particles in suspension has many applications ranging from the recovery of valuable reagents from process flows to the fabrication of microelectromechanical devices. Techniques based on size, density, solubility, or electromagnetic properties exist for fulfilling these needs, but many particles have traits that preclude their use such as small size, neutral buoyancy, or uniform electromagnetic charact… more
Date: December 15, 2004
Creator: Goddard, G.R.
Partner: UNT Libraries Government Documents Department
open access

Evidence for neutrino oscillations in the Sudbury Neutrino Observatory

Description: The Sudbury Neutrino Observatory (SNO) is a large-volume heavy water Cerenkov detector designed to resolve the solar neutrino problem. SNO observes charged-current interactions with electron neutrinos, neutral-current interactions with all active neutrinos, and elastic-scattering interactions primarily with electron neutrinos with some sensitivity to other flavors. This dissertation presents an analysis of the solar neutrino flux observed in SNO in the second phase of operation, while {approx}2… more
Date: August 10, 2004
Creator: Marino, Alysia Diane
Partner: UNT Libraries Government Documents Department
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Performance Study and Dynamic Optimization Design for Thread Pool Systems

Description: Thread pools have been widely used by many multithreaded applications. However, the determination of the pool size according to the application behavior still remains problematic. To automate this process, in this thesis we have developed a set of performance metrics for quantitatively analyzing thread pool performance. For our experiments, we built a thread pool system which provides a general framework for thread pool research. Based on this simulation environment, we studied the performance … more
Date: December 19, 2004
Creator: Xu, Dongping
Partner: UNT Libraries Government Documents Department
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Potential Vorticity Evolution in the Co-orbital Region of Embedded Protoplanets

Description: This thesis presents two-dimensional hydrodynamic disk simulations with embedded protoplanets, emphasizing the non-linear dynamics in the co-orbital region. In particular, it demonstrates how a protoplanetary disk responds to embedded low mass planets at the inviscid limit. Since the potential vorticity (PV) flow is not conserved, due to the spiral shocks and possibly boundary layer effects emanating from the planet, the PV profile develops inflection points which eventually render the flow uns… more
Date: September 1, 2004
Creator: Koller, J.
Partner: UNT Libraries Government Documents Department
open access

Tunable coherent radiation at soft X-ray wavelengths: Generation and interferometric applications

Description: The availability of high power, spectrally and spatially coherent soft x-rays (SXR) would facilitate a wide variety of experiments as this energy region covers the primary resonances of many magnetic and biological materials. Specifically, there are the carbon and oxygen K-edges that are critical for biological imaging in the water window and the L-edges of iron, nickel, and cobalt for which imaging and scattering studies can be performed. A new coherent soft X-ray branchline at the Advanced Li… more
Date: July 1, 2004
Creator: Rosfjord, Kristine Marie
Partner: UNT Libraries Government Documents Department
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Sum frequency generation (SFQ) vibrational spectroscopy studies of combustion reactions on platinum single crystal surfaces

Description: We have studied the dissociation of CO catalyzed by platinum single crystals. At 40 torr of CO, the Pt(111) crystal dissociates CO at 673 K. Under the same conditions, Pt(100) dissociates CO at 500 K, and Pt(557) dissociates CO at 548 K. Hence, the CO dissociation reaction is a structure sensitive reaction. SFG was used to monitor the CO top site resonance as the platinum crystals were heated to the dissociation temperature when exposed to 40 torr of CO. In all three systems, the CO resonance s… more
Date: January 15, 2004
Creator: Gaughan, Jessica S.
Partner: UNT Libraries Government Documents Department
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