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- The Absolute Abundance of the Chromium Isotopes in Some Secondary Minerals
- From abstract: "Isotopic assays have been made on the chromium in samples from fourteen different chrominiferous minerals from different geographic and meteoritic sources. The results of the assays indicate that it is not possible to unequivocally state that variations in isotopic compositions have been observed."
- Acid-Base Equilibria in Tertiary Butyl Alcohol
- From abstract: "The dissociation of acids in tertiary butyl alcohol has been studied by potentiometric, spectrophotometric, and conductimetric methods. Values for the over-all dissociation of perchloric and picric acids and several tetrabutylammonium salts were estimated by the Fuoss-Kraus treatment of conductance data. Potentiometric studies were carried out at constant ionic strength in order to minimize activity coefficient variations. An acidity scale was established from potentiometric measurements at a glass electrode, and conductance values of dissociation constants. A method was developed for the evaluation of the over-all dissociation constant of weak acids using potentiometric data for hydrogen ion activities and conductance data for the corresponding anion activities. Over-all dissociation constants are reported for perchloric acid, picric acid, 2,4-dinitrophenol, and benzoic acid. Apparent dissociation constants from potentiometric measurements at a constant ionic strength were determined for hydrobromic, nitric, hydrochloric, picric, and p-toluenesulfonic acids."
- Acid-Base Reactions and Kinetics of the Halates in Fused Nitrates
- From Abstract : "The mechanism of the reactions of the halates, bromate, chlorate, and iodate, with dichromate in fused alkali nitrates has been shown to involve a fast equilibrium followed by a slow rate determining strip to give oxygen and halogen gases as final products." Experiments outlined serve as insight into the structure of fused salts or fused electrolytes.
- Acid-Base Reactions in Fused Salts. Dichromate-Bromate Reaction
- Technical report. From Abstract : "The reaction of Lewis acid and base, Cr2O7= and BrO3_, in fused KNO3 - NaNO3 mixtures has been shown to involve an equilibrium followed by a slow decomposition to gaseous products."
- The Adsorption and Surface Reactions of Hydrocarbons on Clean Iridium
- From abstract: "The adsorption of ethane, ethylene and acetylene on clean iridium in a field emission microscope has been found to cause characteristic changes in the work function of the iridium surface. Further changes, which are time and temperature dependent, result when such surfaces are heated. Flash filament experiments have shown that the changes in work function upon heating are due to desorption reactions and that the desorbed product consists principally of hydrogen. By assuming a linear relationship between surface coverage and work function, it has been possible to determine the desorption kinetics from the observed rates of work function change at various temperatures. The results are consistent with a mechanism involving stepwise surface dehydrogenation in which a pair of hydrogen atoms is removed from the hydrocarbon molecule in each step, followed by desoption of the adsorbed hydrogen. At very high temperatures the remaining carbon atoms are removed, presumably by evaporation."
- Analysis of Carbon Monoxide-Nitrogen Mixtures by High Resolution Mass Spectrometry
- From abstract: "A single focusing mass spectrometer has been converted into a double focusing instrument. Relatively high resolution is obtained by decreasing the slit widths and minimizing the ion-optic aberrations. A relatively low ion accelerating voltage (2000 volts) is utilized compared to those normally used for high resolution work. The entire construction was performed at these laboratories. Essentially all of the original equipment was reused in the double focusing system. Although the original source slit was decreased from 10 to 0.4 mils and the source α value was decreased from 0.04 to 0.008 radians, sufficient sensitivity is obtained for quantitative gas analysis with the ordinary electrometer tube amplifiers utilizing 4 x 10[^]10 ohms input grid resistors and 100 per cent inverse feedback. Carbon monoxide-nitrogen mixtures were analyzed quantitatively. The results indicate that direct quantitative analysis can be obtained on mixtures ranging from 99 per cent to 10 per cent carbon monoxide in nitrogen. Analysis of lower percentages may be made possible through indirect reading of the peak should it be necessary. It appears that the instrument should be adaptable to research problems concerning these two gases. The immediate problem posed is the analysis of oxygen and nitrogen in metals. Other applications may be possible such as analysis of metastable fragment ions of hydrocarbons or identification of doublet peaks requiring high resolution."
- Analysis of Mixtures of Alcohols by Acylation
- From abstract: "Recently a general chemical method for the analysis of mixtures of alcohols appeared, using pyridine catalyzed acetylation and second order kinetics to determine the amount of the faster reacting component. The use of 0.25M isobutyric anhydride in pyridine containing 0.0025M perchloric acid as catalyst promotes the rate of the reaction and diminishes the time necessary to perform an analysis. A mathematical treatment of the data and kinetic plot reduces the number of kinetic points to only four or five. The mixtures are primarily composed of isomers."
- Angular Distribution of Relativistic Atomic K-Shell Photoelectrons
- From abstract: "Using the high energy limit of the exact Coulomb wave function for the outgoing electron, the differential cross section, correct to three orders in aZ, is calculated for the K-shell photoeffect. An analytic expression, exact in aZ, is obtained for the differential cross section for the special case in which the electron emerges in the forward direction."
- The Application of Wax Laps to Vibratory Polishers
- From introduction: "In this paper the adaptation of the wax lab surface vibratory polisher is described. The wax lap requires little maintenance during the life of the lap. It is not necessary to remove any of the holding devices on the bowl to clean and recondition the lap. The bowl is merely washed out, recharged and placed in operation. The wax lap will not wrinkle or tear, nor is it necessary to change it each day such as the silk or nylon cloths."
- Automatic Recording Surface Balance
- From introduction: "We have previously described simple modifications of a 'Cenco' hydrophil balance which allowed automatic recording of monolayer compression characteristics. This note describes the torsion balance and trough designed and built in this Laboratory as a result of our experience with the previous instrument."
- Bismuth
- This report provides a broad and in depth discussion of bismuth, discussing the properties of bismuth--including physical, electrochemical, and chemical properties. It then discusses the processes by which bismuth is detected and how bismuth can be separated and isolated, with discussions of dissolution, precipitation, and extraction.
- Boiling Points and Surface Tensions of Mixtures of Benzyl Acetate With Dioxan, Aniline and Meta-Cresol
- Technical report. From Abstract : "Accurate measurements on boiling points and surface tensions of mixtures of benzyl acetate with dioxan, aniline and meta-cresol over the entire range of concentration are reported. The results have been analysed in terms of quasi-crystalline model which is partially successful in representing the composition dependence of heats of mixing, boiling points and surface tension except for composition dependence of boiling points of benzyl acetate and meta-cresol."
- Calcium
- Technical report outlining the element calcium as well as its occurrences, physical properties, chemical properties, methods of manufacture, economic aspects, and uses.
- Cation Exchange in Acetone-Water-Hydrochloric Acid
- Abstract: Distribution coefficients have been measured for the partition of metal ions between cation exchange resin and acetone-water-hydrochloric acid solutions. the differences in distribution coefficients of metal ions are greater in acetone-water media than in aqueous media of the same hydrochloric acid concentration. Using distribution coefficient data, conditions for column separations of mixtures can be selected. Column separations of metal ion mixtures can be effected by eluting with acetone-water-hydrochloric acid solutions of different compositions. Successful separations of a number of mixtures are reported.
- Cation Exchange Separation of Divalent Metal Ions From Rare Earths
- From abstract: "The divalent metal ions of calcium, magnesium, nickel, and strontium are eluted from a cation exchange column with 1.5M nitric acid and separated from trivalent rare earths, aluminum and yttrium. Prior sequential elution of other metal ions with hydrochloric acid in acetone-water or with dilute hydrofluoric acid does not interfere with the present separation method."
- Chapter 48: Analytical Chemistry of Cobalt
- This report provides a detailed discussion of the analytical chemistry of cobalt, including an introduction, the properties of cobalt, the sampling of cobalt-bearing materials, the separation and isolation of cobalt, the detection and identification of cobalt, the determination of cobalt, and the specific methods for determining cobalt.
- Chemical Binding in the Water Molecule
- From Introduction : "This analysis partitions the electron density and the electronic pair density of the molecule into components corresponding promoted atomic states, to quasiclassical coulombic interactions of these promoted states, and to interactions resulting from the sharing of electrons between atoms."
- Complex Systems of the Rare Earth Metals With Glycolate, Lactate, and α-Hydroxyisobutyrate Ligands
- From Abstract : "The solubilities of the individual rare earth lactates and α-hysroxyisobutyrates in water at 20 and 60° were determined for comparison with the rare earth glycolate solubilities determined earlier."
- Consequent Procedures in Conventional Computers
- Abstract. The use of consequent procedures in designing programming systems and languages for real-time, on-line or multi-programming applications is discussed. Consequent procedures differ from normal procedures in that the flow control between procedures is defined by the consequences of the previous procedure rather than by the programmer. The use of these concepts leads to comparatively simple system and language design for general purpose systems. Interactions with the external world of human and non-human users are simply described and implemented.
- The Crystal Structure of Bis(Meta-Chlorobenzoyl) Methane
- Technical report. From Abstract : "The crystal structure of bis(meta-chlorobenzoyl) methane has been determined by three dimensional anisotropic least squares refinement of scintillation counter data. The molecule was found to be nearly planar with a maximum deviation from the least squares molecular plane of 0.068Å and an average deviation of 0.023Å. Fourier transform techniques to locate phenyl rings provided the key to the structure determination. The intramolecular bond distances and thermal parameters of the oxygen atoms support a resonant, enol ring with a symmetric, intramolecular hydrogen bond. The structure confirms conslusions from the structure of bis(meta-bromobenzoyl) methane where the symmetry of the molecule was forced by the crystal symmetry."
- Crystal Structure of Bis (Meta-Chlorobenzoyl) Methane
- Technical report. From Abstract : "The determination of the crystal structure of bis(meta-chlorobenzoyl)-methane was undertaken by x-ray methods in an effort to clarify the ambiguous position of the hydrogen atom on the enolic form of β - diketones and hence in intramolecular hydrogen bonds."
- The Crystal Structure of Bismuth Subchloride
- Technical report. From Abstract : "The stoichiometric formula of the lower chloride in the BiCl3-Bi system has been established as Bi12Cl14 (BiCl1.167) through a dingle crystal, X-ray determination of its structure. ... Previous studies of the Bi-Cl3-Bi system are re-examined in the light of the structural results."
- The Crystal Structure of LiCuCl3-2H2O*
- This report undertakes research to study LiCuCl3-2H2O is from a structural standpoint, revealing the oxygen positions. The study uses the Levy-Bussing anisotropic temperature factor treatment and least squares program to determine a discrepancy factor for the visually determined intensities. The structure of the molecule is also found to have interesting magnetic properties which has inspired a new study at Brookhaven.
- Crystalline Field Splittings in Holmium and Dysprosium Ethylsulfates
- From report : "It has become apparent that pragmatic resonance data alone are insufficient to correctly evaluate crystal field parameters for rare-earth ethylsulfates, and that heat capacity data above 20°K are a useful aid in determining whether low lying levels obtained by absorption spectroscopy have been correctly identified."
- Design and Test of a Diaphragm Pump for Liquid Metals
- Technical report. From Abstract : "Details are provided on the construction and operation of a two-stage diaphragm pump successfully used for the first time in liquid metal service. From the results of 5,376 hr. test of the pump it was concluded that it is well suited to the pumping of liquid metals at low flow rates where pulsating flow can be tolerated and also where remote operation is required. Operating temperatures and pressures are limited only by the availability of suitable materials of construction."
- Discussion of Quadrupole Precession
- From abstract: "In this paper the motion of a nucleus with an intrinsic quadrupole moment in an external electrostatic field gradient is discussed from a classical point of view. It is shown that in the classical approximation the angular momentum may precess about the direction of strongest field gradient or about the direction of intermediate field gradient, but not about the direction of weakest field gradient. The classical precession frequencies are found to be related to the quantum mechanical dipole transition frequencies."
- Effect of Oxygen on Mechanical Properties of Niobium
- From abstract: "The effects of oxygen on some mechanical properties of niobium were studied over the composition range of 20 ppm to 2400 ppm oxygen. The tensile properties of samples of these compositions were studied over the temperature range from room temperature to 500°C. Hardness values were obtained at room temperature only. The following observations and conclusions were made during these studies: 1. Oxygen additions to high purity niobium increase both the yield and tensile strengths of niobium at all temperatures investigated. As the temperature is increased above 250°C the effect of the first 200 ppm of oxygen has more influence than further additions on these strengths of niobium. 2. Strain aging behavior is observed. The peaks in the tensile strength versus temperature curves can be predicted with reliability by the relationship proposed by Cottrell, 3. A mechanism is proposed which, along with Cottrell's segregated atmosphere mechanism, can account for the serrated stress-strain curves obtained. This mechanism offers an explanation of the occurrence of serrations at room temperature, and the mechanism is composition dependent."
- An Electrical Pass-Through for Clean, High Vacuum Use
- This report describes the method and research that led to the development of a "new type of mechanical seal for a high-voltage, vacuum pass-through...for use in a general utility 60º sector mass spectrometer." (From introductory paragraph)
- Electrical Properties of the Tungsten Bronzes
- From abstract: "The electrical resistivity of NaxWO3, LixWO3, and KxWO3 has been measured at 300°K. The range of x-values was 0.25 < x < 0.9. All resistivities were characteristic of a metal and lie on a single curve. An extrapolation of the conductivity curve to zero conductivity indicated that the tungsten bronzes should be semiconductors for x < 0.25. The resistivities that have been measured for tungsten bronzes with x < 0.25 showed semiconducting behavior. The resistivity of LixWO3 exhibited an anomalous peak in the ρ vs Τ cuve. The Hall coefficient of Li0.37WO3 indicated one free electron per alkali atom as was previously found for NaxWO3. The Seebeck coefficient of NaxWO3 depended linearly on x[superscript]-2/3 as expected from free electron theory. The implications of these and some other data are discussed."
- Electrical Resistivity of Rare-Earth Alloys
- From abstract: "Resistivities of solid solution alloys in the systems Gd-Lu, Tb-Lu, Gd-Er, and Y-Lu were measured from 4.2-320°K to determine the behavior of the resistivity in alloy systems with magnetic phenomena arising from localized magnetic moments. A large contribution to the residual resistivity is caused by the random distribution of these localized moments through the lattice. An analysis of the lattice resistivity of the metals shows large variations across the heavy rare-earth series which are possibly correlated with the change of c/a ratio of the metals and the attendent changes in the Fermi surface geometry."
- Electron Deficient Compounds: IX. The Structure of Stannous Chloride
- This report discusses the structure of stannous chloride along with tables and figures detailing findings.
- Electron Requirements of Bonds in Metal Borides
- From abstract: "Electrical measurements have been made on CaB6, SrB6, BaB6, YB2, YB4, YB6, and YB12 for the purpose of testing models of the electronic structure of the boron atoms in the four boride types represented. The compounds CaB6, SrB6, and BaB6 were found to be semiconductors. The Hall coefficients of YB4 was also measured, but could not be interpreted because the free electron theory does not provide a theoretical value for comparison with experiment. The results are in agreement with the models proposed."
- Electronic Spectra of Catacondensed and Pericondensed Aromatic Hydrocarbons
- From abstract: "The electronic spectra arising from the excitations of pi-electrons in homo-nuclear conjugated bond systems are calculated for 37 aromatic hydrocarbons. The theoretical approach used takes into account overlap effects between different a atoms, correlation between different electrons, variations in internuclear distances, and the influence of non-conjugated neighbors, hydrogen and carbon. Four types of approximations are carried trough for the molecules in order to obtain an estimate of the inadequacies of the theory. From the calculated transition energies and oscillator strengths, theoretical spectra are synthesized and compared with observed spectra. In order to help the interpretation, a decomposition of the transition dipoles into atomic contributions is introduced. The spectra of alternant molecules are succesfully predicted, but the limits of the underlying assumptions appear to be exceeded in the applications to non-alternant systems. The calculations are markedly successful for the peri-condensed systems, which had presented an obstacle to previous treatments. It is found that the calculated spectra are fairly sensitive to small variations in interatomic distances. calculations with exact atomic positions, where available, give considerably better agreement with experimental spectra. The calculations lead to an understanding of the general spectral pattern found in all aromatic hydrocarbons. On this basis the possibility of a general nomenclature of electronic transitions is examined."
- The Enhancement of Acidity of Very Weak Acids in Tertiary Butyl Alcohol
- Technical report. From Abstract : "The acidity of a solution of acid, HX, and salt, MX, is affected by both the concentration of X- and M+ owing to incomplete dissociation of the salt, MX. it was possible to increase the acidity of a solution of 2,6-di-tert-butylphenol - tetrabutylammonium 2,6-di-tert-butylphenolate relative to a dilute solution of tetrabutylammonium hydroxide by increasing the tetrabutylammonium bromide content. This indicates that the dissociation constant of the hydroxide base is sufficiently large that extensive dissociation occurs in dilute solutions. The addition of tetrabutylammonium bromide is therefore recommended as a general method for increasing the acidity and improving the titration characteristics of extremely weak acids."
- The Equation of State of Solids at Low Temperature
- Technical report describing and evaluating the the three experimental methods for obtaining equation of state data at low temperatures; (1) approximate measurement of the PVT relationship by a piston-displacement technique, (2) the measurement of a heat capacity at constant volume as a function of molar volume and temperature, and (3) direct measurement of the pressure variation of the elastic constants using ultrasonic techniques. X-ray methods also might be applicable.
- An Experimental Approach to a Simplified Band Structure of the Rare Earth Metals
- Technical report. From Abstract : "A number of the physical properties from which we can obtain both direct and indirect information concerning the band structures of metals, have been measured for most of the rare earth metals. It was thought that it would be desirable to review ans examine these data and try to tie them together. For this purpose the very low and room temperature heat capacities, Hall coefficients, magnetic susceptibilities, spectral data and electrical resistivities were examined."
- Experimental Training Model for Closed Chest Cardiac Massage Developed at the Ames Laboratory
- From introduction: "This article describes a training aid that was at the Ames Laboratory in order to give the plant protection group of the Laboratory an opportunity to practice closed chest cardiac massage on a simulated model. Details of the model are given so that professional or semi-professional people who may be faced with a sudden emergency requiring immediate action may duplicate this training aid."
- Flame Spectra of Vanadium, Niobium, Rhenium, Titanium and Molybdenum
- Abstract Line spectra of vanadium, niobium, titanium, molybdenum and rhenium of sufficient intensity to allow detection at the 1–10 p.p.m. level can be excited in fuel-rich, oxy-acetylene flames. For the strongest lines of tungsten, the sensitivity of detection is 90 p.p.m. Weak lines of zirconium, hafnium, osmium, tantalum and uranium are also observed in these flames. Recordings of the spectra are given along with wavelength tables of the strongest lines.
- Formation Constants of the Complex Species Formed by Interaction of Rare-Earth Nitrilotriacetate Complexes with an Equivalent Amount of Base
- From abstract: "The formation constants of the RChOH- species, formed by interaction of individual rare-earth nitrilotriacetate species and KOH at 25°C and an ionic strength of 0.1, have been determined by the potentiometric method, i.e., computed from the pH values of equilibrium mixtures containing varying proportions of rare-earth complex and base. The relationship of these constants to the ion-exchange separation of rare earths at high pH has been discussed."
- Gamma Ray Efficiencies for Well Type Scintillation Crystals
- From Abstract : "Gamma ray efficiencies for various sized well type NaI(Ti) crystals have been calculated using an IBM 704 digital computer. The adjustable parameters in the program are the gamma ray energy, the heights and diameters of the crystal and the well, the thickness of the well lining, and the positions of the (point) source inside the well. Some typical results are presented in graphical form."
- gem-Bis(disubstitutedphosphinyl)alkanes. II. Extraction Properties of Bis(di-n-hexlphosphinyl)methane
- From abstract: "Bis(di-n-hexylphosphinyl)methane, HDPM, [(C6H13)2P(O)]2CH2, has been studied as an extractant for a variety of metals. HDPM was evaluated as an extractant for uranium(VI) and compared with tri-n-octylphosphine oxide, TOPO, (C8H13)3PO. In nonpolar solvents, HDPM forms a polymeric-like substance with compounds of uranium(VI). Viscosity measurements indicate that the molecular weight of this polymeric-like substance is about 100 times greater than the corresponding complex with TOPO. Polymer formation occurs only when nonpolar solvents are used as diluents for HDPM and is easily avoided by using polar solvents such as 1,2-aichlorobenzene. HDPM forms 1:1 and 2:1 complexes with uranium(VI) nitrate. Equilibrium constants for these complexes as well as that for the 2:1 TOPO complex were calculated and it was shown that the over-all constant is at least ten times larger for the HDPM complex than for the TOPO complex. The effect of concentration of various mineral acids, extractant concentration, temperature, and diluents on the extraction of uranium are discussed."
- High Pressure Research at Low Temperatures
- Two principle reasons exist for the extension of high pressure research to temperatures near absolute zero. First, the comparison of certain data with theory (such as the pressure-volume relationship) is more meaningful if the effects of thermal vibrations can be ignored. Second, there are phenomena which can be studied only at low temperatures. These include superconductivity, the properties of solid helium and other inert gases, some electronic phenomena, etc.
- High Purity Calcium
- Technical report. From Introduction : "For more than a century, methods employed in preparing calcium were based largely on electrowinning and the most successful were based on [Sir Humphrey] Davy's process. ... In general, the metal was of adequate quality for the industrial applications of the time, and although by 1940 some strides had been made in the purification of calcium, interests in the better grades of the metal were limited essentially to experimental work of academic concern."
- The Hydrolysis of the Rare-Earth Carbides
- From introductory paragraph: "This report concerns the hydrolysis of rare-earth dicarbides, sesquicarbides, solid solutions of carbon in rare-earth metals as well as rare-earth carbon alloys of varying compositions. Many of the carbide samples used in this study were those which had been studied by Gschneider (9)(7) and had been preserved in evacuated, sealed tubes. Some additional preparations of the sesquicarbides were made especially for these studies. The hydrolytic reactions were carried out in water and hydrochloric acid solutions of varying concentrations. Assay of the gaseous products was by mass spectrometry and gas chromatography. Both instruments were carefully calibrated with pure hydrocarbons and hydrogen and mixture thereof."
- III. Crystalline Complexes of Bis(Di-2-Ethylbutylphosphinyl) Methahe With Uranium(VI) Nitrate and With Thorium Nitrate
- Technical report. From Abstract : "Bis(di-2-ethylbutylphosphinyl)methane, EBDPM, forms complexes with uranium (VI) nitrate and thorium (IV) nitrate in which EBDPM acts as a bidentate ligand and the nitrato groups appear to be coordinated. The complex with uranium (VI) is a monomer, UO2(NO3)29EBDPM), while the complex with thorium in a dimer, [Th(NO3)4]2(EBDPM)3. Both complexes are of high thermal stability."
- Indicator Transition Ranges in Tertiary Butyl Alcohol
- Technical report. From Abstract : "The approximate transition ranges of a number of common indicators in tertiary butyl alcohol are given in terms of potentials measured with a glass-two phase salt bridge-SCE electrode system. Potential control was obtained by the addition of a sulfuric acid-malonic acid mixture and titration with tetrabutylammonium hydroxide. In general, the sulfonphthaleins are recommended for the titration of strong to medium strength acids, and Azo Violet, o-nitroaniline, and a p-nitro-p-aminoazobenzene for very weak acids."
- The Inference of Adsorption from Differential Double Layer Capacitance Measurements
- From Abstract : "Dependence of boundary tension and capacitance at the mercury-aqueous 0.1 N HClO4 interface on polarization and organic solute concentration were determined for the colutes n-amyl alcohol and phenol. ... An earlier treatment proposed by this Laboratory based on a (non-thermodynamic) assumption of linear variation of surface charge density with coverage appears adequately justified for inference of fractional surface coverages near the electrocapillary maximum, but must be considered approximate for evaluation of molar area at full coverage in cases where linear variation of charge with coverage has not been demonstrated."
- Internal Conversion Coefficients of the 2+-0+, E2 Transitions in Even-Even Sm152[over]90 and Gd152[over]88
- From abstract: "To investigate the deviation of the internal conversion coefficients of E2 transitions from theoretical computations and their dependence on nuclear deformation, the total internal conversion coefficient of the 121.8-kev 2+-0+ transition in ellipsoidal Sm152[over]90 was measured to be 1.135 ± 0.010 with a high accuracy coincidence-sum method. The K-shell to total internal conversion ratio was determined to be 0.588 ± 0.003 with a [beta] spectrometer...The experiment revealed no deviation from theory nor indications of strong dependence on nuclear deformation; it therefore did not confirm recent beliefs in this regard. The details of the coincidence-sum method were described. The K electron to total electron capture ratio, from Eu152 to the 1.53 Mev state in Sm152 was also measured to be 0.79±0.02."
- Ion-Exchange Methods for Obtaining Pure Metals
- This technical report details a process by which ion exchange was used for separation of rare earth metals in a highly pure form. Two techniques for resolving mixtures are described: ion-exchange elution chromatography and ion-exchange displacement chromatography.
- The Isotope Shift of the Uranium Ka1 X Ray
- Technical report. From Introduction : "The nuclear volume dependent isotope shift of optical spectral lines has long been a very useful means for studying the changes in the nuclear size or shape for different isotopes of heavy elements."