Acid-Base Equilibria in Tertiary Butyl Alcohol

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From abstract: "The dissociation of acids in tertiary butyl alcohol has been studied by potentiometric, spectrophotometric, and conductimetric methods. Values for the over-all dissociation of perchloric and picric acids and several tetrabutylammonium salts were estimated by the Fuoss-Kraus treatment of conductance data. Potentiometric studies were carried out at constant ionic strength in order to minimize activity coefficient variations. An acidity scale was established from potentiometric measurements at a glass electrode, and conductance values of dissociation constants. A method was developed for the evaluation of the over-all dissociation constant of weak acids using potentiometric data for hydrogen ion activities and conductance … continued below

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24 pages : illustrations.

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Marple, Leland & Fritz, James S. (James Sherwood), 1924- August 6, 1962.

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  • Ames Laboratory
    Publisher Info: Ames Laboratory, Iowa State University.
    Place of Publication: Ames, Iowa

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From abstract: "The dissociation of acids in tertiary butyl alcohol has been studied by potentiometric, spectrophotometric, and conductimetric methods. Values for the over-all dissociation of perchloric and picric acids and several tetrabutylammonium salts were estimated by the Fuoss-Kraus treatment of conductance data. Potentiometric studies were carried out at constant ionic strength in order to minimize activity coefficient variations. An acidity scale was established from potentiometric measurements at a glass electrode, and conductance values of dissociation constants. A method was developed for the evaluation of the over-all dissociation constant of weak acids using potentiometric data for hydrogen ion activities and conductance data for the corresponding anion activities. Over-all dissociation constants are reported for perchloric acid, picric acid, 2,4-dinitrophenol, and benzoic acid. Apparent dissociation constants from potentiometric measurements at a constant ionic strength were determined for hydrobromic, nitric, hydrochloric, picric, and p-toluenesulfonic acids."

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24 pages : illustrations.

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Includes bibliographical references (page 19).

"Contribution No. 1205. Work was performed in the Ames Laboratory of the U.S. Atomic Energy Commission."

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  • Report No.: IS-524
  • SuDoc Number: Y 3.At 7:22/IS-524
  • Accession or Local Control No: metadc1201533
  • Archival Resource Key: ark:/67531/metadc1201533

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Technical Report Archive and Image Library

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  • August 6, 1962

Added to The UNT Digital Library

  • Aug. 27, 2019, 3:53 p.m.

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  • April 1, 2020, 3:25 p.m.

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Marple, Leland & Fritz, James S. (James Sherwood), 1924-. Acid-Base Equilibria in Tertiary Butyl Alcohol, report, August 6, 1962; Ames, Iowa. (https://digital.library.unt.edu/ark:/67531/metadc1201533/: accessed March 15, 2025), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT Libraries Government Documents Department.

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