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Thermal conductivity and tritium retention in Li{sub 2}O and Li{sub 2}ZrO{sub 3}

Description: Lithium oxide (Li{sub 2}O) and lithium zirconate (Li{sub 2}ZrO{sub 3}) are promising ceramic breeder materials for fusion reactor blankets. The thermal and tritium transport databases for these materials are reviewed. Algorithms are presented for predicting both the temperature distribution and the retained tritium profile across sintered-product and pebble-bed regions. Sample design calculations are also performed to demonstrate the relative advantages of each breeder ceramic. For Li{sub 2}O, … more
Date: August 1, 1997
Creator: Billone, M.C.
Partner: UNT Libraries Government Documents Department
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NOVEL CERAMIC MEMBRANE FOR HIGH TEMPERATURE CARBON DIOXIDE SEPARATION

Description: The Objective of this research program is to develop a dense, non porous ceramic membrane for separation of carbon dioxide from flue gas at high temperatures (400-600 C). The research has been focused on addressing several fundamental issues of lithium zirconate (Li{sub 2}ZrO{sub 3}). In the 2nd half research, we conducted various kinds of experiments to understand the CO{sub 2} sorption/desorption mechanism on the pure and modified Li{sub 2}ZrO{sub 3} with the help of TGA, DSC TGA and XRD. DSC… more
Date: September 1, 2001
Creator: Ida, Jun-ichi; Yang, Zhaohui & Lin, Jerry Y.S.
Partner: UNT Libraries Government Documents Department
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A method to remove Ammonia using a Proton-Conducting Ceramic Membrane

Description: An apparatus and method for decomposing NH{sub 3}. A fluid containing NH{sub 3} is passed in contact with a tubular membrane that is a homogeneous mixture of a ceramic and a first metal, with the ceramic being selected from one or more of a cerate having the formula of M' Ce{sub 1-x} M''O{sub 3-{delta}}, zirconates having the formula M'Zr{sub 1-x} M''3-{delta}, stannates having the formula M'Sn{sub 1-x}M''O{sub 3}-{delta}, where M' is a group IIA metal, M'' is a dopant metal of one or more of C… more
Date: September 22, 1999
Creator: Balachandran, Uthamalingam & Bose, Arun C.
Partner: UNT Libraries Government Documents Department
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Properties and orientation of antiferroelectric lead zirconate thin films grown by MOCVD.

Description: Single-phase polycrystalline PbZrO{sub 3} (PZ) thin films, 3000-6000 {angstrom} thick, have been grown by metal-organic chemical vapor deposition (MOCVD) on (111)Pt/Ti/SiO{sub 2}/Si substrates at {approximately}525 C. X-ray diffraction analysis indicated that the PZ films grown on (111)Pt/Ti/SiO{sub 2}/Si (Pt/Ti/Si) showed preferred pseudocubic (110) orientation. In contrast, PZ films grown on 150 {angstrom} thick PbTiO{sub 3} (PT) template layers exhibited a pseudocubic (100) preferred orienta… more
Date: December 21, 1998
Creator: Chen, N.
Partner: UNT Libraries Government Documents Department
open access

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Final report

Description: This project has investigated new metal oxide catalysts for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as CO. Significant progress in catalyst development has been made during the course of the project. We have found that fluorite oxides, CeO{sub 2} and ZrO{sub 2}, and rare earth zirconates such as Gd{sub 2}Zr{sub 2}O{sub 7} are active and stable catalysts for reduction Of SO{sub 2} by CO. More than 95% sulfur yield was achieved at reaction temper… more
Date: June 1, 1995
Creator: Liu, W.; Flytzani-Stephanopoulos, M. & Sarofim, A.F.
Partner: UNT Libraries Government Documents Department
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A Versatile two-step process for immobilizing excess plutonium.

Description: As a consequence of weapon stockpile reduction and the associated shutdown of weapons production facilities, approximately 50 metric tons of plutonium (both weapons-grade and non-weapons-grade) has been declared excess by the US. Recent experiments demonstrated the feasibility of using high-level waste stored at the Idaho Chemical Processing Plant to immobilize plutonium. The most effective plutonium host phase identified in these experiments was a plutonium zirconate solid solution. Results of… more
Date: May 18, 1998
Creator: O'Holleran, T. P.
Partner: UNT Libraries Government Documents Department
open access

NOVEL CERAMIC MEMBRANE FOR HIGH TEMPERATURE CARBON DIOXIDE SEPARATION

Description: This project is aimed at demonstrating technical feasibility for a lithium zirconate based dense ceramic membrane for separation of carbon dioxide from flue gas at high temperature. The research work conducted in this reporting period was focused on several fundamental issues of lithium zirconate important to the development of the dense inorganic membrane. These fundamental issues include material synthesis of lithium zirconate, phases and microstructure of lithium zirconate and structure chan… more
Date: March 1, 2001
Creator: Lin, Jerry Y.S. & Ida, Jun-ichi
Partner: UNT Libraries Government Documents Department
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