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Effects of Vegetation on Radon Transport Processes in Soil

Description: A large component of radon entry cannot be explained by pressure differences between the soil and inside the structures. The persistence of this radon entry even when the house is pressurized by 1 Pa indicates that it must be due to molecular diffusion. The radon entry rate as measured by accumulators below ground level (soil + concrete) is roughly 2 times greater than that measured above ground level (concrete alone). The soil permeability is about 10{sup {minus}12} m{sup 2} and does not chang… more
Date: January 1, 1991
Creator: Borak, T.B.
open access

Role of Polycrystallinity in Cdte and Cuinse Sub 2 Photovoltaic Cells

Description: The polycrystalline nature of thin-film CdTe and CuInSe{sub 2} solar cells continues to be a major factor in several individual losses that limit overall cell efficiency. This report describes progress in the quantitative separation of these losses, including both measurement and analysis procedures. It also applies these techniques to several individual cells to help document the overall progress with CdTe and CuInSe{sub 2} cells. Notably, CdTe cells from Photon Energy have reduced window phot… more
Date: January 1, 1991
Creator: Sites, J.R. (Colorado State Univ., Fort Collins, CO (United States))
open access

Role of polycrystallinity in CdTe and CuInSe{sub 2} photovoltaic cells. Annual subcontract report, 1 April 1990--31 March 1991

Description: The polycrystalline nature of thin-film CdTe and CuInSe{sub 2} solar cells continues to be a major factor in several individual losses that limit overall cell efficiency. This report describes progress in the quantitative separation of these losses, including both measurement and analysis procedures. It also applies these techniques to several individual cells to help document the overall progress with CdTe and CuInSe{sub 2} cells. Notably, CdTe cells from Photon Energy have reduced window phot… more
Date: December 31, 1991
Creator: Sites, J. R.
open access

Diosmacycloalkanes as Models for the Formation of Hydrocarbons From Surface Methylenes. Progress Report, November 1, 1991--October 31, 1992

Description: We are making progress on our investigation of the mechanism of olefin exchange with Os{sub 2}(C{sub 2}H{sub 4})(CO){sub 8}. We are probing this system by kinetic study of the reaction of Os{sub 2}(C{sub 2}H{sub 4})(CO){sub 8} with butyl acrylate (BA) under various pressures of ethylene.
Date: May 1, 1992
Creator: Norton, J. R.
open access

Capillary discharge extreme ultraviolet lasers. [Colorado State Univ. , Ft. Collins]

Description: The project objective is to explore the generation of soft X-ray laser radiation in a plasma column created by a fast capillary discharge. The proposed capillary lasing scheme offers the potential for compact, simple and efficient soft X-ray laser sources. For this purpose a compact, fast pulse generator which produces 100 kA current pulses with a risetime of 11 ns was constructed. Initial experiments were conducted in evacuated capillaries, in which the plasma is produced by ablation of the ca… more
Date: August 1, 1992
Creator: Rocca, J. J.
open access

Capillary discharge extreme ultraviolet lasers. Progress report, December 15, 1991--December 14, 1992

Description: The project objective is to explore the generation of soft X-ray laser radiation in a plasma column created by a fast capillary discharge. The proposed capillary lasing scheme offers the potential for compact, simple and efficient soft X-ray laser sources. For this purpose a compact, fast pulse generator which produces 100 kA current pulses with a risetime of 11 ns was constructed. Initial experiments were conducted in evacuated capillaries, in which the plasma is produced by ablation of the ca… more
Date: August 1, 1992
Creator: Rocca, J. J.
open access

Effects of Vegetation of Radon Transport Processes in Soil: The Origins and Pathways of {Sup 222}Rn Entering Into Basement Structures. Final Report, March 15, 1987--May 15, 1993

Description: The entry rate of {sup 22}Rn into a basement structure was measured continuously. These measurements demonstrated that radon entry did not vanish even when the structure was slightly pressurized. This persistent entry has been determined to be dominated by diffusion through the floor and walls and a combination of diffusion and convection through the floor-wall joint. The highest indoor radon concentrations occurred during calm periods when the pressure differentials between the inside and outs… more
Date: August 1, 1992
Creator: Borak, T. B.
open access

Evaluation of Aftermarket Fuel Delivery Systems for Natural Gas and Lpg Vehicles

Description: This study was designed to evaluate the effectiveness of aftermarket fuel delivery systems for vehicles fueled by compressed natural gas (CNG) and liquefied petroleum gas (LPG). Most of the CNG and LPG vehicles studied were converted to the alternative fuel after purchase. There are wide variations in the quality of the conversion hardware and the installation. This leads to questions about the overall quality of the converted vehicles, in terms of emissions, safety, and performance. There is a… more
Date: September 1, 1992
Creator: Willson, B.
open access

Evaluation of Aftermarket Fuel Delivery Systems for Natural Gas and Lpg Vehicles

Description: This study was designed to evaluate the effectiveness of aftermarket fuel delivery systems for vehicles fueled by compressed natural gas (CNG) and liquefied petroleum gas (LPG). Most of the CNG and LPG vehicles studied were converted to the alternative fuel after purchase. There are wide variations in the quality of the conversion hardware and the installation. This leads to questions about the overall quality of the converted vehicles, in terms of emissions, safety, and performance. There is a… more
Date: September 1, 1992
Creator: Willson, B. (Colorado State Univ., Fort Collins, CO (United States))
open access

Role of polycrystallinity in CdTe and CuInSe[sub 2] photovoltaic cells

Description: The limiting role of polycrystallinity in thin-film solar calls has been reduced somewhat during the past year, and efficiencies of both CdTe and CuInSe[sub 2] cells are approaching 15%. Quantitative separation of loss mechanisms shows that individual losses, with the exception of forward recombination current, can be made comparable to their single crystal counterparts. One general manifestation of the extraneous trapping states in that the voltage of all polycrystalline thin-film cells drifts… more
Date: November 1, 1992
Creator: Sites, J.R. (Colorado State Univ., Fort Collins, CO (United States))
open access

Role of polycrystallinity in CdTe and CuInSe{sub 2} photovoltaic cells. Annual subcontract report, 1 April 1991--31 March 1992

Description: The limiting role of polycrystallinity in thin-film solar calls has been reduced somewhat during the past year, and efficiencies of both CdTe and CuInSe{sub 2} cells are approaching 15%. Quantitative separation of loss mechanisms shows that individual losses, with the exception of forward recombination current, can be made comparable to their single crystal counterparts. One general manifestation of the extraneous trapping states in that the voltage of all polycrystalline thin-film cells drifts… more
Date: November 1, 1992
Creator: Sites, J. R.
open access

Chemically modified electrodes and related solution studies

Description: This report is divided into 5 sections: Ru[sub 4]/Fe complexes of tetra(4[prime]-methyl-2,2[prime]-bipyridine)porphyrin--catalytic epoxidation of olefins; water oxidation catalysis by doubly linked [mu]-oxo ruthenium complexes; polymer films formed by oxidation of transition metal electrodes into solutions of bisbipyridinealkane ligands; polymer films containing [CpMo([mu]-S)][sub 2]S[sub 2]CHR dinuclear clusters;and conducting polymer films for catalyst incorporation.
Date: April 1, 1993
Creator: Elliott, C.M.
open access

Chemically modified electrodes and related solution studies. Final technical report, January 15, 1991--January 14, 1992

Description: This report is divided into 5 sections: Ru{sub 4}/Fe complexes of tetra(4{prime}-methyl-2,2{prime}-bipyridine)porphyrin--catalytic epoxidation of olefins; water oxidation catalysis by doubly linked {mu}-oxo ruthenium complexes; polymer films formed by oxidation of transition metal electrodes into solutions of bisbipyridinealkane ligands; polymer films containing [CpMo({mu}-S)]{sub 2}S{sub 2}CHR dinuclear clusters;and conducting polymer films for catalyst incorporation.
Date: April 1, 1993
Creator: Elliott, C. M.
open access

Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes

Description: The report is divided into: vibrational models for surface ethylidenes (on catalyst surfaces); alpha vs beta hydrogen elimination in formation of propene from an osmacyclobutane; mechanism of formation and fragmentation of diosmacyclobutanes; reaction of dienes and allenes with diosmacyclobutanes; structure of Os(CO)[sub 4](C[sub 2]H[sub 4]), an osmacyclopropane; and reaction of [mu]-oxobis [(trifluoromethanesulfanato) (phenyl)iodine(III)] with Group 14 propargyl derivatives and a propargyl eth… more
Date: May 1, 1993
Creator: Norton, J.R.
open access

Diosmacycloalkanes as Models for the Formation of Hydrocarbons From Surface Methylenes. Progress Report, November 1, 1992--October 31, 1993

Description: The report is divided into: vibrational models for surface ethylidenes (on catalyst surfaces); alpha vs beta hydrogen elimination in formation of propene from an osmacyclobutane; mechanism of formation and fragmentation of diosmacyclobutanes; reaction of dienes and allenes with diosmacyclobutanes; structure of Os(CO){sub 4}(C{sub 2}H{sub 4}), an osmacyclopropane; and reaction of {mu}-oxobis [(trifluoromethanesulfanato) (phenyl)iodine(III)] with Group 14 propargyl derivatives and a propargyl eth… more
Date: May 1, 1993
Creator: Norton, J. R.
open access

Photoinduced Charge Separation in Linked Donor-Chromophore-Acceptor Systems

Description: Focus has been mainly on preparation and characterization of triply bridged dinuclear complexes containing a tris-2-2'- bipyridineruthenium chromophore and a second tris-bipyridine metal complex which is to serve as electron donor or acceptor, and of linked RuL[sub 3]-containing D-C-A complexes where D is a phenothiazine donor and A is a diquat type acceptor. (DLC)
Date: June 1, 1993
Creator: Elliott, C.M.
open access

Photoinduced Charge Separation in Linked Donor-Chromophore-Acceptor Systems. Progress Report, September 1, 1993--May 31, 1993

Description: Focus has been mainly on preparation and characterization of triply bridged dinuclear complexes containing a tris-2-2`- bipyridineruthenium chromophore and a second tris-bipyridine metal complex which is to serve as electron donor or acceptor, and of linked RuL{sub 3}-containing D-C-A complexes where D is a phenothiazine donor and A is a diquat type acceptor. (DLC)
Date: June 1, 1993
Creator: Elliott, C. M.
open access

Development of a gas-to-particle conversion model for use in three-dimensional global sulfur budget studies. Final report, 1 August 1991--30 June 1992

Description: A fully-parameterized model for the formation and growth of aerosols via gas-to-particle conversion has been developed and tested. A particularly significant contribution is a new method for the prediction of numbers of particles nucleated using information on the vapor source rate, relative humidity, and preexisting aerosol alone, thus eliminating the need to solve a system of coupled ODEs. Preliminary tests indicate substantial reduction in computational costs, but it is recommended that the … more
Date: August 1, 1993
Creator: Kreidenweis, S. M.
open access

Advanced NMR approaches in the characterization of coal. Final technical report, September 1, 1990--August 31, 1993

Description: This project addressed two main goals and one much smaller one. The main goals were (1) to improve the significance, reliability and information content in high-resolution NMR (nuclear magnetic resonance) characterization of coal samples and (2) to develop chemically informative NMR imaging techniques for coal. The minor goal was to explore advanced features of dynamic nuclear polarization (DNP) as a technique for coal characterization; this included the development of two DNP probes and the ex… more
Date: September 30, 1993
Creator: Maciel, G. E.
open access

Grassland/Atmosphere Response to Changing Climate: Coupling Regional and Local Scales. Final Report

Description: The objectives of the study were: to evaluate the response of grassland ecosystems to atmospheric change at regional and site scales, and to develop multiscaled modeling systems to relate ecological and atmospheric models with different spatial and temporal resolutions. A menu-driven shell was developed to facilitate use of models at different temporal scales and to facilitate exchange information between models at different temporal scales. A detailed ecosystem model predicted that C{sub 3} te… more
Date: October 1, 1993
Creator: Coughenour, M. B.; Kittel, T. G. F.; Pielke, R. A. & Eastman, J.
open access

Parameterization of Convective Clouds Mesoscale Convective Systems, and Convective-Generated Cirrus. Final Report, September 15, 1990--October 31, 1993

Description: The overall goal of this research is to develop a scheme to parameterize diabatic heating, moisture/water substance, and momentum transports, and precipitation from mesoscale convective systems (MCSs) for use in general circulation models (GCMs). Our approach is to perform explicit cloud-resolving simulations of MCSs in the spirit of the GEWEX Cloud Systems Study (GCSS), by using the Regional Atmospheric Modeling System (RAMS) developed at Colorado State University (CSU). We then perform statis… more
Date: November 5, 1993
Creator: Cotton, W. R.
open access

Role of polycrystallinity in CdTe and CuInSe{sub 2} photovoltaic cells. Annual subcontract report, 1 April 1992--31 March 1993

Description: This report describes work to conduct several investigations of thin-film polycrystalline solar cells. (1) An analysis of high-efficiency solar cells fabricated at the University of South Florida showed significant reduction in forward recombination current, and the cells were stable over a 3-month test period. (2) Transient voltage effects were documented in a large number of polycrystalline cells and were attributed to long-lived trapping states sensitive to voltage changes near one-half open… more
Date: February 1, 1994
Creator: Sites, J. R.
open access

Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes. Final report

Description: Assignment of the vibrational modes Of Os{sub 2}(CO){sub 8}(CHCH{sub 3}) and Os(CO){sub 4}(C{sub 2}H{sub 4)} has given fingerprint vibrational spectra for the following species when chemisorbed on metal catalyst surfaces: ethylidene and ethylene bound in a metallacyclopropane mode. The formation and fragmentation of diosmacyclobutanes have been shown to involve slippage of the outgoing olefin onto a single osmium, and associative exchange of the olefin from that site. The incorporation of vinyl… more
Date: April 25, 1994
Creator: Norton, J. R.
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