An experimental study was made of the mass transport of chromium in poly- thermal Inconel-fluoride fuel systems. The transport of chromium was followed by toe technique of adding radioactive Cr/sup 51/ to the system as either CrF/sub 2/ , in the salt or as elemental chromium in the solid phase. The rates of diffusion of chromium in Inconel at 600, 700, 800, and 900 deg C were determined by an electropolishing technique. Polythermal studies were carried out by three methods, tilting capsules, thermal-convection loops, and pumping loops. Tilting- capsule experiments indicated that the preferred location for chromium deposition on the …
continued below
Publisher Info:
Battelle Memorial Inst., Columbus, Ohio
Place of Publication:
Columbus, Ohio
Provided By
UNT Libraries Government Documents Department
Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.
Descriptive information to help identify this report.
Follow the links below to find similar items on the Digital Library.
Description
An experimental study was made of the mass transport of chromium in poly- thermal Inconel-fluoride fuel systems. The transport of chromium was followed by toe technique of adding radioactive Cr/sup 51/ to the system as either CrF/sub 2/ , in the salt or as elemental chromium in the solid phase. The rates of diffusion of chromium in Inconel at 600, 700, 800, and 900 deg C were determined by an electropolishing technique. Polythermal studies were carried out by three methods, tilting capsules, thermal-convection loops, and pumping loops. Tilting- capsule experiments indicated that the preferred location for chromium deposition on the wall was in the region of maximum temperature but the conclusions were not clear cut. Thermal convection loops operated for 125 and 288 hr showed radioactivity profile which could be attributed to simple exchange, with some distortion in the 288 hr case. The duration of these experiments was evidently insufficient io allow equilibrium to be reached in the salt. A thermal- convection loop operated for 400 hr showed distortion in the exchange radioactivity profile which indicated a favorable position for chromium deposition at a point about 100 deg F below the maximum wall temperature, and on the upstream side of the flow. A pumping loop of Inconel and salt mix gave an activity profile which was very similar to that of the 400-hr thermalconvection loop, indicating a favorable deposition point 100 deg F below maximuim temperature on the upstream side. One hypothesis advanced is that the long-term corrosion rate of chromium in the Inconel-salt system is controlled by the rate of diffusion of chromium into the wall at a temperature about 100 deg F below the maximum temperature on the upstream side. (auth)
This report is part of the following collection of related materials.
Office of Scientific & Technical Information Technical Reports
Reports, articles and other documents harvested from the Office of Scientific and Technical Information.
Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.
Price, Robert B.; Sunderman, Duane N.; Pobereskin, Meyer & Calkins, George D.A TRACER STUDY OF THE TRANSPORT OF CHROMIUM IN FLUORIDE FUEL SYSTEMS,
report,
June 18, 1957;
Columbus, Ohio.
(https://digital.library.unt.edu/ark:/67531/metadc865944/:
accessed May 10, 2024),
University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu;
crediting UNT Libraries Government Documents Department.
