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Acid-Base Equilibria in Tertiary Butyl Alcohol

Description: From abstract: "The dissociation of acids in tertiary butyl alcohol has been studied by potentiometric, spectrophotometric, and conductimetric methods. Values for the over-all dissociation of perchloric and picric acids and several tetrabutylammonium salts were estimated by the Fuoss-Kraus treatment of conductance data. Potentiometric studies were carried out at constant ionic strength in order to minimize activity coefficient variations. An acidity scale was established from potentiometric mea… more
Date: August 6, 1962
Creator: Marple, Leland & Fritz, James S. (James Sherwood), 1924-
Partner: UNT Libraries Government Documents Department
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The Crystal Structure of LiCuCl3-2H2O*

Description: This report undertakes research to study LiCuCl3-2H2O is from a structural standpoint, revealing the oxygen positions. The study uses the Levy-Bussing anisotropic temperature factor treatment and least squares program to determine a discrepancy factor for the visually determined intensities. The structure of the molecule is also found to have interesting magnetic properties which has inspired a new study at Brookhaven.
Date: 1960
Creator: Vossos, Peter H.; Fitzwater, D. R. & Rundle, R. E.
Partner: UNT Libraries Government Documents Department
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Pyrometallurgical Reprocessing of Thorium-Uranium Fuel

Description: From summary: "A proposed metallurgical procedure for reporocessing Th-U233 fuel has been outlined. Some basic experimental data pertinent to the proposed process which has been published elsewhere has been reviewed and some new data presented. In the dissolution of thorium-uranium alloy in magnesium the data show that protactinium precipitates with the uranium and cerium remains in the magnesium-rich solution. It is expected that yttrium, other light rare earth elements, the alkali and alkalin… more
Date: 1961
Creator: Chiotti, P.; Woerner, P. F. & Parry, S. J. S.
Partner: UNT Libraries Government Documents Department
open access

Ternary Compounds Between Thorium Monocarbide and Thorium Dihydride

Description: From abstract: "The thorium-hydrogen-carbon system was studied by measuring hydrogen equilibrium pressures at various compositions and temperatures. Two compounds, ThC·ThH2 and ThC·2ThH2, were found and characterized. ThC·ThH2 has a hexagonal closest-packed lattice with ao=3.816Å and co=6.302Å. ThC·2ThH2 has a monoclinic lattice with ao=6.50Å, bo=3.80Å, co=10.91Å and β = 119°. The enthalpies of formation for each compound were determined."
Date: 1961
Creator: Peterson, D. T. & Rexer, J.
Partner: UNT Libraries Government Documents Department
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