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BRAZING OF CERAMICS. Progress Report

Description: Brazing alloys such as 48 Ti-48 Zr-4 Be (wt%) and 49 Ti-49 Cu-2 Be (wt%) have been found to readily flow on oxide and graphite ceramics. Two demonstrati on fuel element assemblies were fabricated to illustrate the usefulness of these procedures for nuclear applications. One of these assemblies contained graphite tubes and end caps which were brazed to a molybdenum hanger. The second demonstration fuel element was composed of a compartmented aluminum oxide plate to which aluminum oxide cover pla… more
Date: November 1, 1962
Creator: Fox, C.W.
Partner: UNT Libraries Government Documents Department
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Effect of Heat Flux on the Corrosion of Aluminum by Water. Part Iii. Final Report on Tests Relative to the High-Flux Isotope Reactor

Description: The effect of very high heat fluxes on the corrosion of 1100 and 6061 aluminum alloys by water was investigated. The test conditions generally simulated those expected to exist during operation of the High-Flux lsotope Reactor. At heat fluxes between 1 and 2 x l0/sup 6/ Btu/hr-ft/sup 2/ and with coolant temperatures and velocities in the ranges of 13l to 250 deg F and 3l to 51 fps, respectively, a layer of boehmite ( alpha Al/sub 2/O/sub 3/- H/sub 2/0), which has low thermal conductivity, forme… more
Date: December 20, 1961
Creator: Griess, J. C.; Savage, H. C.; Rainwater, J. G.; Mauney, T. H. & English, J. L.
Partner: UNT Libraries Government Documents Department
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PROCESSES FOR RECOVERY OF URANIUM AND THORIUM FROM GRAPHITE-BASE FUEL ELEMENTS. PART II

Description: Laboratory-scale tests on methods for recovering uranium and thorium from graphite-base reactor fuel elements are reported. The 90% HNO/sub 3/ process, which involves simultaneous disintegration and leaching in 21 M HNO/sub 3/, is applicable to all fuel elenments which do not contain coated fuel particles. Leaching of irradiated (0.001% burnup) fuels containing 3 and 12% uranlum recovered approximates 99.3 and 99.9%, respectively, of the uranium in two 4-hr leaches with boiling acid. The graphi… more
Date: November 30, 1961
Creator: Ferris, L.M.; Kibbey, A.H. & Bradley, M.J.
Partner: UNT Libraries Government Documents Department
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Chemical Processing Technology Quarterly Progress Report, January-March 1961

Description: Studies are reported on aqueous zirconium processing, dissolution of BeO- UO/sub 2/ ceramic fuel, the aqueous stainless steel process, the behavior of dibutyl phosphates, use of boron (boric acid) solution to assure critical safety, fluidized bed calcination, conversion of amorphous alumina to alpha alumina, the Demonstrational Waste Calcining Facility, removal of long-lived radioisotopes from waste solutions, separation of iron, nickel, and chromiun from stainless steel waste solutions, electr… more
Date: October 31, 1962
Creator: Bower, J. R.
Partner: UNT Libraries Government Documents Department
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Low Temperature Thermoluminescence of Gamma Irradiated Potassium Dihydrogen Phosphate

Description: Thermoluminescence in potassium dihydrogen phosphate (KDP) induced by Co/ sup 60/ gamma irradiation at liquid nitrogen temperature (-198 deg C) was investigated. Glow curves in the temperature range --196 to 0 deg C were measured for a series of gamma exposure dosages ranging from 10/sup 4/ roentgen to 5 x 10/sup 6/ roentgen. The heating rate used for glow curve measurements was 12 deg C per minute. Twice recrystallized Mallinckrodt reagent grade potassium dihydrogen phosphate, with a grain siz… more
Date: October 19, 1962
Creator: Sims, T. M.
Partner: UNT Libraries Government Documents Department
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The Fluid-Bed Calculation of Radioactive Waste

Description: Liquid radioactive wastes are converted into solids, with volume reduction factors of 3 to 8, by flash drying on finely screened, porous, inert solid particles (e.g. alumina) in a fluidized bed at 320 to 550 deg C. The wastes may be either aluminum nitrate-containing wastes from the processing of MTR-type fuel elements, or Purex Process wastes. Ruthenium is found to be the only volatile fission product in this temperature range. Methods are described for its removal from the fluidizing gas. (T.… more
Date: May 1, 1961
Creator: Loeding, J. W.; Carls, E. L.; Anastasia, L. J. & Jonke, A. A.
Partner: UNT Libraries Government Documents Department
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DISSOLUTION OF BeO-AND Al$sub 2$O$sub 3$-BASE REACTOR FUEL ELEMENTS. PART I

Description: Aqueous methods for recovering uranium from BeO- and Al/sub 2/O/sub 3/- base gas-cooled-reactor fuel elements are being evaluated. Two methods for processing Hastelloy-X--clad pelletized BeO-base fuels containing 60 to 70% UO/ sub 2/, such as the GCRE and MGCR, seem feasible. One method involves mechanical stripping or chopping of the cladding followed by leaching of the uranium from the fuel pellets with boiling 6-l3M HNO/sub 3/. In the other method the cladding and UO/sub 2/ are dissolved in … more
Date: February 14, 1962
Creator: Warren, K S; Ferris, L M & Kibbey, A H
Partner: UNT Libraries Government Documents Department
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Phase Transformations in Alumina. Technical Report, May to December 1961

Description: e transformation studies showed that synthetic aluminas produced in the laboratory were not transformed to alpha alumina at 400 to 700' deg n the presence of nitric acid and water vapor. Amorphous aluminn produced in the pilot plant was transformed to alpha alumina. This indicated that the amorphous alumina produced in the pilot plant is structurally predisposed to form alpha alumina. Most additives did not appear to have any special effects. Lithium formed zeta alumina, LiAl/sub 5/O/sub 8/. Ph… more
Date: December 1, 1961
Creator: Eding, H J; Huggins, M L & Brown, A G
Partner: UNT Libraries Government Documents Department
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Development of a Fluidized Bed Calcination Process for Aluminum Nitrate Wastes in a Two-Foot-Square Plant Calciner. Part 2. Factors Affecting the Intra-Particle Porosity of Alumina

Description: A seven- to twenty-fold volume reduction can be obtained from fluidized bed calcination of aqueous aluminum nitrate wastes, depending on the operating conditions employed and their effect on the intra-panticle porosity and absolute density of the calcined alumina. Among the calcining variables, only the bed temperature and the fuel aluminum concentration had a significant effect on the intra-particle porosity of alumina generated during studies conducted primarily in a two-foot-square fluidized… more
Date: July 25, 1962
Creator: Wheeler, B. R.; Grimmett, E. S. & Buckham, J. A.
Partner: UNT Libraries Government Documents Department
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FUEL ELEMENT DEVELOPMENT PROGRAM FOR THE PEBBLE BED REACTOR. Final Report

Description: >The basic fuel element consisted of a uniform dispersion of fuel in a 1 1/2 inch diameter graphite sphere. Ceramic coatings for the retention of fission products were studied. It was found-that molecularly deposited'' ceramics such as alumina, siliconized silicon carbide, and pyrolytic carbon were excellent barriers to fission product leakage. The most advantageous location for ceramic coatings was found to be on the individual fuel particles, where the coating was subject to smaller forces an… more
Date: April 30, 1961
Partner: UNT Libraries Government Documents Department
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Chemical Processing Technology Quarterly Progress Report, October-December 1961

Description: The ICPP processed Al fuel, prtncipally of the MTR-ETR type, durtng this quarter. Newly designed and installed processing equipment exhibited excellent operating performance. This included direct-air-pulsed extraction, stripping and scrub columns, and a cascade-controlled continuous evaporator in first cycle product concentration service. Aqueous zirconium fuel processing studies continued with the objective of adapting the hydrofluoric acid process to continuous dissolution-complexing to incre… more
Date: March 28, 1962
Creator: Bower, J. R.
Partner: UNT Libraries Government Documents Department
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CHEMICAL PROCESSING OF COATED PARTICLE FUELS

Description: BS>Laboratory studies on the processing of graphite-base fuel elements containing pyrolytic carbon- or Al/sub 2/O/sub 3/-coated particles are reviewed. Potential processes for recovering U and Th from irradiated elements include grinding followed by acid leaching, and, burning and subsequent dissolution of the oxide ash. Disintegration in 90% HNO/sub 3/ was briefly evaluated as a method for determining the integrity of coated particles dispersed in graphite matrices. (auth)
Date: April 1, 1962
Creator: Ferris, L.M.
Partner: UNT Libraries Government Documents Department
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EXPERIMENTAL ATTEMPTS TO STABILIZE A CUBIC FORM OF BeO

Description: Binary mixtures of BeO with the oxides Al/sub 2/O/sub 3/, CaO, Li/sub 2/ O, MgO, Sc/sub 2/O/sub 3/, TiO/sub 2/, Y/sub 2/O/sub 3/, and ZrO/sub 2/ were fired to temperatures in excess of 2050 deg C in an attempt to produce a stabilized cubic crystalline modification of BeO. No evidence was observed in microscopic and x-ray diffraction analyses of the cooled specimens that a cubic form of BeO had formed in the experiment. (auth)
Date: December 22, 1961
Creator: Thoma, R.E.; Friedman, H.A. & McVay, T.N.
Partner: UNT Libraries Government Documents Department
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Chemical Processing Technology Quarterly Progress Report, January-March 1962

Description: The processing of Al fuel, principally of the MTR-ETR type, is reported. Processing rate averaged 90% of flow sheet values for the entire operating period, and a U recovery of 99.85% was achieved. Aqueous Zr fuel processing studles continued with the objective of adapting the HF process to continuous dissolution-complexing in order to increase the capacity of the ICPP process while using as much existing equipment as possible to minimize costs. Good results were indicated in a 190-hr run dissol… more
Date: June 29, 1962
Creator: Bower, J. R.
Partner: UNT Libraries Government Documents Department
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Annual Progress Report on Fuel Element Development for FY 1962

Description: Activities in a project aimed at the improvement of fuel elements for high flux test reactors are reported. The investigation of new fuel compositions, distributions, and geometries is being undertaken to increase fuel life, to improve the flux distribution, and to provide a means of safely reaching higher reactor operating power and power density in these reactors. The effects of nuclear irradiation on the fuel and structural materials is being studied to predict the performance of these mater… more
Date: August 15, 1962
Creator: Gibson, G. W. & Francis, W. C.
Partner: UNT Libraries Government Documents Department
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