Kinetics of the [beta]-[delta]phase transition in PBX9501.
Description:
The initial step in the thermal decomposition of HMX is the solid state phase transition from the centrosymmetric beta form to the noncentrosymmetric delta form. The symmetry change makes the phase transition amenable to the application of second harmonic generation (SHG) as a probe of transition kinetics. We have used SHG to study the temperature dependence of the kinetics for unconfined PBX9501 and HMX. Spatially resolved SHG measurements have shown a nucleation and growth mechanism for the s…
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Date:
January 1, 2001
Creator:
Smilowitz, L. B. (Laura B.); Henson, B. F. (Bryan F.); Asay, B. W. (Blaine W.); Dickson, P. M. (Peter M.) & Robinson, J. M. (Jeanne M.)
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