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The production of fuels and chemicals from food processing wastes using a novel fermenter separator

Description: During 1991, considerable progress was made on the waste utilization project. Two small Wisconsin companies have expressed an interest in promoting and developing the ICRS technology. Pilot plant sites at (1) Hopkinton, IA, for a sweet whey plant, and Beaver Dam WI, for an acid whey site have been under development siting ICRS operations. The Hopkinton, IA site is owned and operated by Permeate Refining Inc., who have built a batch ethanol plant across the street from Swiss Valley Farms cheddar… more
Date: December 1, 1991
Creator: Dale, M.C.; Venkatesh, K.V.; Choi, Hojoon; Moelhman, M.; Saliceti, L.; Okos, M.R. et al.
Partner: UNT Libraries Government Documents Department
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Catalytic hydrogenation of carbon monoxide

Description: This project is focused on developing strategies to accomplish the reduction and hydrogenation of carbon monoxide to produce organic oxygenates at mild conditions. Our approaches to this issue are based on the recognition that rhodium macrocycles have unusually favorable thermodynamic values for producing a series of intermediate implicated in the catalytic hydrogenation of CO. Observations of metalloformyl complexes produced by reactions of H{sub 2} and CO, and reductive coupling of CO to form… more
Date: December 1, 1992
Creator: Wayland, B.B.
Partner: UNT Libraries Government Documents Department
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Recovery of anaerobic digestion after exposure to toxicants. Final report

Description: The concept that methane fermentation cannot tolerate chronic or slug doses of toxicants has almost totally precluded methane fermentation as a viable contender for the treatment of industrial wastewaters. This study assayed a wide variety of toxicants, heavy metals, inorganic salts, organic chemicals, solvents, and antibiotics which are used in industrial processes and, therefore, appear in the industrial wastewaters therefrom. Toxicity was related to the reduction in methane production of a c… more
Date: December 1, 1979
Creator: Yang, J.; Parkin, G. F. & Speece, R. E.
Partner: UNT Libraries Government Documents Department
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Ozone mass transfer and kinetics experiments

Description: Experiments were conducted at the Hanford Site to determine the most efficient pH and temperature levels for the destruction of complexants in Hanford high-level defense waste. These complexants enhance migration of radionuclides in the soil and inhibit the growth of crystals in the evaporator-crystallizer. Ozone mass transfer and kinetics tests have been outlined for the determination of critical mass transfer and kinetics parameters of the ozone-complexant reaction.
Date: December 1981
Creator: Bollyky, L. Joseph & Beary, M. M.
Partner: UNT Libraries Government Documents Department
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Lanthanide extraction with 2,5-dimethyl-2-hydroxyhexanoic acid

Description: This research is concerned with the solvent extraction into chloroform of the lanthanides, using 2,5-dimethyl-2-hydroxyhexanoic acid (DMHHA). This acid is the first ..cap alpha..-hydroxy aliphatic acid to be studied as an extracting agent for the lanthanides. The chloroform-water DMHHA partition constant was determined to be 1.0 (at 0.1 M ionic strength and 25/sup 0/C). The acid dimerizes in chloroform with a constant of 56. The light lanthanides can be extracted into chloroform by forming comp… more
Date: December 1, 1977
Creator: Miller, J. H.
Partner: UNT Libraries Government Documents Department
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Selective paint and black chrome coatings development. Semiannual report, June 5-December 5, 1978

Description: Solar selective black chrome and paint coatings were investigated to improve their performance and to develop techniques for large-scale applications. Formulations and processing conditions for thickness sensitive paint coatings were defined which consistently provide solar absorptance (..cap alpha..) of 0.90 and emittance (epsilon) of 0.10 on low emittance substrates. A significant improvement in abrasion resistance was achieved by decreasing the pigment volume concentration. Addition of alumi… more
Date: December 1, 1978
Creator: Lin, R J.H. & Zimmer, P B
Partner: UNT Libraries Government Documents Department
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Comparison of techniques for preserving dissolved nutrients in open-ocean seawater samples

Description: A survey of recent literature on methods for preserving nutrients indicates that the major factors which have been considered are: filtration and type of filter, material and history of storage containers, the influence of light, storage temperature and how it is achieved, the effectiveness of various acids, poisons, and preservatives, and the source of the sample. No comprehensive studies of open ocean seawater were found. A comprehensive study of nutrient preservation techniques was conducted… more
Date: December 1, 1981
Creator: Morse, J. W.; Hunt, M.; Zullig, J.; Mucci, A. & Mendez, T.
Partner: UNT Libraries Government Documents Department
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Magnetic resonance studies of photo-induced electron transfer reactions

Description: During the period covered by this report research has been concerned with the application of Fourier Transform Electron Paramagnetic Resonance (FT EPR) in the study of photo-induced electron transfer reactions. Donor molecules used in this investigation have been various porphyrins, whereas quinones were used as acceptor molecules.
Date: December 1, 1990
Creator: van Willigen, H.
Partner: UNT Libraries Government Documents Department
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Roles of Additives and Surface Control in Slurry Atomization

Description: This quarterly report describes the effects of anionic dispersant and nonionic surfactant on the rheology of micronized (Mass Median Diameters of 4 {mu}m and 10 {mu}m) coal water slurries (CWSs). We found that the micronized CWS is pseudoplastic (shear thinning) at a low additive concentration of either anionic dispersant or nonionic surfactant because coal particles aggregate under the influence of the interparticle van der Waals attraction. At a high additive concentration, the micronized CWS… more
Date: December 1, 1990
Creator: Tsai, S. C.
Partner: UNT Libraries Government Documents Department
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Polymers as advanced materials for desiccant applications

Description: This research is concerned with solid materials used as desiccants for desiccant cooling systems (DCSs) that process water vapor in an atmosphere to produce cooling. Background information includes an introduction to DCSs and the role of the desiccant as a system component. The water vapor sorption performance criteria used for screening the modified polymers prepared include the water sorption capacity from 5% to 80% relative humidity (R.H.), isotherm shape, and rate of adsorption and desorpti… more
Date: December 1, 1990
Creator: Czanderna, A.W.
Partner: UNT Libraries Government Documents Department
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Excited state electron transfer in systems with a well-defined geometry. Progress report, May 1, 1979-April 30, 1980

Description: To determine what are the important criteria governing efficient light-induced electron transfer, we have been studying cyclophanes formed by joining two chlorophyll macrocycles together with two covalent linkages. The properties of the cofacial dimer can be altered by adding one or two magnesium atoms. When a cyclophane containing only one metal atom is excited electron transfer takes place in under ten picoseconds. Evidence for the formation of a state having a great deal of charge transfer i… more
Date: December 1, 1979
Creator: Kaufmann, K.J.
Partner: UNT Libraries Government Documents Department
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Photoinduced Electron Transfer in Ordered Polymers

Description: Long range photoinduced electron transfer between electron donor and acceptor groups is of considerable current interest in terms of strategies for artificial photosynthesis and studies regarding the redox properties of proteins. As part of an extensive study of long range electron transfer involving biopolymers, we have carried out this year investigations of the assembly of electron transfer agents in a system of model short peptides. Also studied is a polyelectrolyte that can adopt a helical… more
Date: December 1, 1991
Creator: Jones, G., II
Partner: UNT Libraries Government Documents Department
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Recovery of americium-241 from aged plutonium metal

Description: About 5 kg of ingrown /sup 241/Am was recovered from 850 kg of aged plutonium using a process developed specifically for Savannah River Plant application. The aged plutonium metal was first dissolved in sulfamic acid. Sodium nitrite was added to oxidize the plutonium to Pu(IV) and the residual sulfamate ion was oxidized to nitrogen gas and sulfate. The plutonium and americium were separated by one cycle of solvent extraction. The recovered products were subsequently purified by cation exchange … more
Date: December 1, 1980
Creator: Gray, L. W.; Burney, G. A.; Reilly, T. A.; Wilson, T. W. & McKibben, J. M.
Partner: UNT Libraries Government Documents Department
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Radiation chemistry of amino acids, peptides and proteins in relation to the radiation sterilization of high-protein foods

Description: An important source of information on the question of whether or not toxic or other deleterious substances are formed in the radiation sterilization of foods is the chemical study of reaction products and reaction mechanisms in the radiolysis of individual food components. The present evaluation of the radiation chemistry of amino acids, peptides, and proteins outlines the various radiation-induced processes which lead to amino acid degradation and to the synthesis of amino acid derivatives of … more
Date: December 1, 1981
Creator: Garrison, W. M.
Partner: UNT Libraries Government Documents Department
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[Report of Foreign Travel: International Workshop on Radioiodinated Free Fatty Acids, Amsterdam]

Description: The traveler participated in the Second International Workshop on Radioiodinated Free Fatty Acids in Amsterdam, The Netherlands where he presented an invited paper describing the pioneering work at the Oak Ridge National Laboratory (ORNL) involving the design, development and testing of new radioiodinated methyl-branched fatty acids for evaluation of heart disease. He also chaired a technical session on the testing of new agents in various in vitro and in vivo systems. He also visited the Insti… more
Date: December 11, 1987
Creator: Knapp, Furn F., Jr.
Partner: UNT Libraries Government Documents Department
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Investigation of the Triplet State of Chlorophylls. Progress Report, May 1, 1980-April 30, 1981

Description: The triplet state of chlorophyll has been utilized as a nondestructive probe into the structural and dynamical nature of the photosynthetic apparatus. During the past year, using zero-field triplet state optically detected magnetic resonance spectroscopy, chlorophyll aggregates were examined in both their natural environment in vivo and in model complexes in vitro. Research efforts have focused on subchloroplast particles extracted from green plants, on chlorophyll monolayers, and on isolated c… more
Date: December 22, 1980
Creator: Clarke, R. H.
Partner: UNT Libraries Government Documents Department
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Production of high-energy chemicals using solar energy heat. Project 8999, final report for the period September 1, 1977--May 31, 1978

Description: The first phase of a study to identify candidate processes and products suitable for future exploitation using high-temperature solar energy is presented. This phase has been principally analytical, consisting of techno-economic studies, thermodynamic assessments of chemical reactions and processes, and the determination of market potentials for major chemical commodities that use significant amounts of fossil resources today. The objective was to identify energy-intensive processes that would … more
Date: December 1, 1978
Creator: Dafler, J. R.; Sinnott, J.; Novil, M.; Yudow, B. D. & Rackoff, M. G.
Partner: UNT Libraries Government Documents Department
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Water Resources Research Program: Pollution of Coastal Waters Off Chicago by Sinking Plumes From the Indiana Harbor Canal

Description: On March 2, 1977, during sinking-plume conditions, a portion of the water of the Indiana Harbor Canal (IHC) was injected with samarium and rhodamine-dye tags and a section of the IHC's surface was covered with simulated oily waste tagged with dysprosium. Water samples were taken downcurrent, over a 54-hr period, from a vessel and from the raw-water streams from the intakes at Chicago's South Water Filtration Plant (SWFP). Bottom currents and water temperatures were measured almost continuously … more
Date: December 1, 1977
Creator: Harrison, W.; McCown, D. L.; Raphaelian, L. A. & Saunders, K. D.
Partner: UNT Libraries Government Documents Department
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Direct probing of chromatography columns by laser-induced fluorescence

Description: This report summarizes the progress and accomplishments of this research project from September 1, 1989 to February 28, 1993. During this period, we have accomplished all of the primary scientific objectives of the research proposal: (1) constructed and evaluated a laser-induced fluorescence detection system that allows direct examination of the chromatographic column, (2) examined nonequilibrium processes that occur upon solute injection and elution, (3) examined solute retention in liquid chr… more
Date: December 7, 1992
Creator: McGuffin, V.L.
Partner: UNT Libraries Government Documents Department
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[Carbon isotope fractionation inplants]. Final report

Description: The objectives of this research are: To develop a theoretical and experimental framework for understanding isotope fractionations in plants; and to develop methods for using this isotope fractionation for understanding the dynamics of CO{sub 2} fixation in plants. Progress is described.
Date: December 31, 1990
Creator: O`Leary, M. H.
Partner: UNT Libraries Government Documents Department
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Materials Research and Evaluation for Geothermal Corrosion Environments. Progress Report, December 15, 1974--December 15, 1975. [Ni Co Cr Mo Alloy]

Description: Bent beam and self-stressed specimens have been employed and shown to give results consistent with other types of specimens as reported in the literature. All tests have been conducted in the standard NACE, H/sub 2/S environment for initial screening and then in a 20 percent NaCl modified NACE solution. Among the higher strength corrosion resistant alloys, K Monel at 135 ksi yield strength did not fail in either environment at temperatures up to 425/sup 0/F stressed at the yield strength. Age h… more
Date: December 1, 1975
Creator: Troiano, A. R. & Hehemann, R. F.
Partner: UNT Libraries Government Documents Department
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In vivo metabolism of I-123 labeled semisynthetic low density lipoproteins

Description: We previously observed that small model beta-strand peptides (MBPs) selectively bind to human low density lipoprotein (hLDL) in vitro, and that some MBPs can be labeled with I-123-tyramine cellobiose (I-123-TyC). We hypothesized that metabolism of semisynthetic hLDL should mimic that of covalently labeled native hLDL, and planned to evaluate the biodistribution in rabbits of semisynthetic hLDL; to determine effects of prior oxidation and acetylation of the adsorbing hLDL on binding of MBPs and … more
Date: December 1, 1990
Creator: Harper, Paul V.
Partner: UNT Libraries Government Documents Department
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The genome sequence of Geobacter metallireducens: features of metabolism, physiology and regulation common and dissimilar to Geobacter sulfurreducens

Description: Background: The genome sequence of Geobacter metallireducens is the second to be completed from the metal-respiring genus Geobacter, and is compared in this report to that of Geobacter sulfurreducens in order to understand their metabolic, physiological and regulatory similarities and differences. Results: The experimentally observed greater metabolic versatility of G. metallireducens versus G. sulfurreducens is borne out by the presence of more numerous genes for metabolism of organic acids in… more
Date: December 1, 2008
Creator: Aklujkar, Muktak; Krushkal, Julia; DiBartolo, Genevieve; Lapidus, Alla; Land, Miriam L. & Lovley, Derek R.
Partner: UNT Libraries Government Documents Department
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