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Organic components of nuclear wastes and their potential for altering radionuclide distribution when released to soil

Description: Normal waste processing at the Hanford operations requires the use of many organic materials, chiefly in the form of complexing agents and diluents. These organic materials and their chemical and radiolytic degradation products, have potential for complexing fission products and transuranium elements, both in the waste streams and upon infiltration into soil, perhaps influencing future sorption or migration of the nuclides. Particular complexation characteristics of various nuclides which const… more
Date: August 1, 1980
Creator: McFadden, K.M.
Partner: UNT Libraries Government Documents Department
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Bodcau In Situ Combustion Project. Third annual report, July 1, 1978-August 31, 1979

Description: This project is a cooperative venture between Cities Service Company and the US Department of Energy. The main objective is to demonstrate the operation and economics of a successful commercial scale In Situ Combustion Project in a heavy oil reservoir. This Third Annual Report deals primarily with performance, development and economics of the project in the third year of operation, with pertinent information from the First and Second Annual Report included for background information. The five e… more
Date: August 1, 1980
Creator: Garvey, J.; Pusch, W. H. & Fulford, R. S.
Partner: UNT Libraries Government Documents Department
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Physicochemical Studies of the Carbamate-CO/sub 2/-Solvent System

Description: The formation of carbamate from CO/sub 2/ and the various amine solutions has been investigated for the purpose of elucidating the structure of the species generated in the reaction. The amine solutions used were 1 and 2 molar solutions of di-n-butylamine (DNBA) in triethylamine (TEA), pure DNBA and pure TEA. It has been found that the nonaqueous solvent participates in the formation of carbamate in 1 and 2M-DNBA/TEA solutions as a proton acceptor in DNBA-carbamate formation. However, due to th… more
Date: August 1, 1977
Creator: Prencipe, M. & Ishida, T.
Partner: UNT Libraries Government Documents Department
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Georgetown University atmospheric fluidized bed boiler cogeneration system

Description: This report presents the results of one year of operation of the cogeneration system capability of the Georgetown University coal- fired, atmospheric fluidized-bed (AFB) boiler. The AFB was designed and installed under a separate contract with the US Department of Energy. The AFB project funded by DOE to demonstrate that high sulfur coal could be burned in an environmentally acceptable manner in a urban environment such as Georgetown. In addition, operational data from the unit would assist the… more
Date: August 1, 1991
Creator: Podbielski, V. & Shaff, D.P.
Partner: UNT Libraries Government Documents Department
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Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

Description: AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-… more
Date: August 28, 1987
Creator: Jha, Mahesh C.; Baltich, Linda K. & Berggren, Mark H.
Partner: UNT Libraries Government Documents Department
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Advances in materials science, Metals and Ceramics Division. Triannual progress report, February-May 1980

Description: Research is reported in the magnetic fusion energy and laser fusion energy programs, aluminium-air battery and vehicle research, geothermal research, nuclear waste management, basic energy science, and chemistry and materials science. (FS)
Date: August 1, 1980
Creator: Truhan, J.J. & Gordon, K.M. (eds.)
Partner: UNT Libraries Government Documents Department
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Expected environments in high-level nuclear waste and spent fuel repositories in salt

Description: The purpose of this report is to describe the expected environments associated with high-level waste (HLW) and spent fuel (SF) repositories in salt formations. These environments include the thermal, fluid, pressure, brine chemistry, and radiation fields predicted for the repository conceptual designs. In this study, it is assumed that the repository will be a room and pillar mine in a rock-salt formation, with the disposal horizon located approx. 2000 ft (610 m) below the surface of the earth.… more
Date: August 1, 1980
Creator: Claiborne, H.C. & Rickertsen, L.D., Graham, R.F.
Partner: UNT Libraries Government Documents Department
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Study of aluminum corrosion in aluminum solar heat collectors using aqueous glycol solution for heat transfer. Annual technical progress report, July 30, 1979-July 31, 1980

Description: The effects of glycol aging at elevated temperatures over long periods of time were studied and the zinc powder protective technique was optimized. Glycols are known to gradually decompose into organic acids at high temperatures. These product species may be aggressive to aluminum in the long run. In addition, corrosion inhibitors may also breakdown due to continuous exposure to high temperatures. As for the zinc powder protective technique, efforts have been made to determine the optimal condi… more
Date: August 1, 1980
Creator: Wong, D. & Cocks, F.H.
Partner: UNT Libraries Government Documents Department
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Experimental results of direct containment heating by high-pressure melt ejection into the Surtsey vessel: The DCH-3 and DCH-4 tests

Description: Two experiments, DCH-3 and DCH-4, were performed at the Surtsey test facility to investigate phenomena associated with a high-pressure melt ejection (HPME) reactor accident sequence resulting in direct containment heating (DCH). These experiments were performed using the same experimental apparatus with identical initial conditions, except that the Surtsey test vessel contained air in DCH-3 and argon in DCH-4. Inerting the vessel with argon eliminated chemical reactions between metallic debris … more
Date: August 1, 1991
Creator: Allen, M.D.; Pilch, M.; Brockmann, J.E.; Tarbell, W.W. (Sandia National Labs., Albuquerque, NM (United States)); Nichols, R.T. (Ktech Corp., Albuquerque, NM (United States)) & Sweet, D.W. (AEA Technology, Winfrith (United Kingdom))
Partner: UNT Libraries Government Documents Department
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Fire protection countermeasures for containment ventilation systems

Description: The goal of this project is to find countermeasures to protect High Efficiency Particulate Air (HEPA) filters, in exit ventilation ducts, from the heat and smoke generated by fire. Initially, methods were developed to cool fire-heated air by fine water spray upstream of the filters. It was recognized that smoke aerosol exposure to HEPA filters could also cause disruption of the containment system. Through testing and analysis, several methods to partially mitigate the smoke exposure to the HEPA… more
Date: August 25, 1980
Creator: Alvares, N.; Beason, D.; Bergman, V.; Creighton, J.; Ford, H. & Lipska, A.
Partner: UNT Libraries Government Documents Department
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High-Temperature Reactions of Type 304 Stainless Steel in Low Concentrations of Carbon Dioxide and Carbon Monoxide

Description: Compatibility studies of type 304 stainless steel in helium containing low concentrations of CO and CO/sub 2/ were conducted. The oxidation rates were insensitive to impurity concentrations between 0.0006--0.3 vol% in the temperature range 400--1000 deg C when P/sub co2/P/sub co/ was less than 0.66. Ratios above this value resulted initially in a slow oxidation rate, but was followed by an accelerated attack. The incubation period for the break-away varied with the P/sub co2//P/sub co/ ratio an… more
Date: August 29, 1962
Creator: Inouye, H.
Partner: UNT Libraries Government Documents Department
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METALLURGY DIVISION ANNUAL PROGRESS REPORT FOR PERIOD ENDING MAY 31, 1961

Description: >Fundamental Alloying. Studies of crystal structures, reactions at metal surfaces, spectroscopy of molten salts, mechanical deformation, and alloy theory are reported. Long-Range Applied Metallurgy. A thermal comparator is described and the characteristic temperature of U0/sub 2/ determined. Sintering studies were carried out on ThO/sub 2/. The diffusion of fission products in fuel and of Al/sup 26/ and Mn/sup 54/ in Al and the reaction of Be with UC were studied. Transformation and oxidation d… more
Date: August 17, 1961
Partner: UNT Libraries Government Documents Department
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Synthesis of high specific activity (1- sup 3 H) farnesyl pyrophosphate

Description: The synthesis of tritiated farnesyl pyrophosphate with high specific activity is reported. trans-trans Farnesol was oxidized to the corresponding aldehyde followed by reduction with lithium aluminium tritide (5%-{sup 3}H) to give trans-trans (1-{sup 3}H)farnesol. The specific radioactivity of the alcohol was determined from its triphenylsilane derivative, prepared under very mild conditions. The tritiated alcohol was phosphorylated by initial conversion to an allylic halide, and subsequent trea… more
Date: August 1, 1991
Creator: Saljoughian, M.; Morimoto, H. & Williams, P. G.
Partner: UNT Libraries Government Documents Department
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Three year progress report and renewal request

Description: A review of research accomplisments during the contract period is presented. Reported projects include: (1) metals as radiation sensitizers of spores; (2) studies on transforming and calf thymus DNA; (3) pulse radiolysis studies on DNA components; (4) studies of metal complexes of DNA compounds; and (5) dosimetry of the pulsed electron beam. (ACR)
Date: August 1, 1980
Creator: Powers, E. L.
Partner: UNT Libraries Government Documents Department
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Design, microstructure, and high-temperature behavior of silicon nitride sintered with rate-earth oxides

Description: The processing-microstructure-property relations of silicon nitride ceramics sintered with rare-earth oxide additives have been investigated with the aim of improving their high-temperature behavior. The additions of the oxides of Y, Sm, Gd, Dy, Er, or Yb were compositionally controlled to tailor the intergranular phase. The resulting microstructure consisted of {beta}-Si{sub 3}N{sub 4} grains and a crystalline secondary phase of RE{sub 2}Si{sub 2}O{sub 7}, with a thin residual amorphous phase … more
Date: August 1, 1991
Creator: Ciniculk, M.K. (California Univ., Berkeley, CA (United States). Dept. of Materials Science and Mineral Engineering)
Partner: UNT Libraries Government Documents Department
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Innovative Clean Coal Technology (ICCT): Demonstration of innovative applications of technology for cost reductions to the CT-121 FGD process

Description: The objective of this project is to demonstrate on a commercial scale several innovative applications of cost-reducing technology to the Chiyoda Thoroughbred-121 (CT-121) process. CT-121 is a second generation flue gas desulfurization (FGD) process which is considered by the Electric Power Research Institute (EPRI) and Southern Company Services (SCS) to be one of the most reliable and lowest cost FGD options for high-sulfur coal-fired utility boiler applications. Demonstrations of the innovativ… more
Date: August 6, 1990
Partner: UNT Libraries Government Documents Department
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Ocean Thermal Energy Conservation (OTEC) power system development (PDS) II. Preliminary design report

Description: This report documents the results and conclusions of the PDS II, Phase I, preliminary design of a 10 MWe OTEC power system, using enhanced plate type heat exchangers, and of representative 0.2 MWe test articles. It further provides the documentation (specifications, drawings, trade studies, etc.) resulting from the design activities. The data and discussions of the technical concepts are organized to respond to the PDS II, Phase II proposal evaluation criteria. This volume, which specifically a… more
Date: August 10, 1979
Partner: UNT Libraries Government Documents Department
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Ancillary effects of selected acid deposition control policies

Description: NAPAP is examining a number of potential ways to reduce the precursors (sulfur dioxide and nitrogen oxides) to acid deposition. However, the policies to reduce acid deposition will have other physical, biological and economic effects unrelated to acid deposition. For example, control policies that reduce sulfur dioxide emissions may also increase visibility. The effects of an acid deposition policy that are unrelated to acid deposition are referred to as ''ancillary'' effects. This reserch iden… more
Date: August 1, 1986
Creator: Moe, R.J.; Lyke, A. J. & Nesse, R. J.
Partner: UNT Libraries Government Documents Department
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High voltage research (breakdown strengths of gaseous and liquid insulators) and environmental effects of dielectric gases. Semiannual report, October 1, 1979-March 31, 1980

Description: Topics covered include basic studies of gaseous dielectrics, direct current breakdown strengths of gases/mixtures, environmental effects studies and decomposition analyses, impulse studies, breakdown strengths of binary mixtures with concentric cylinder geometry, and a discussion of the experimental apparatus. (GHT)
Date: August 1, 1980
Creator: Christophorou, L.G.; James, D.R. & Pai, R.Y.
Partner: UNT Libraries Government Documents Department
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Photoassisted oxidation of oil films on water

Description: The objective of the project is to develop TiO{sub 2}-based photocatalysts for the solar assisted oxidative dissolution of oil slicks. In a TiO{sub 2} crystal, absorption of a photon generates an electron-hole pair. The electron reacts with surface-adsorbed oxygen, reducing it to hydrogen peroxide; the hole directly oxidizes adsorbed organic compounds, usually via an intermediate OH radical. Since the density of TiO{sub 2} (3.8g/cc for anatase, 4.3 g/cc for rutile) is greater than that of eithe… more
Date: August 1, 1991
Creator: Heller, A. & Brock, J. R.
Partner: UNT Libraries Government Documents Department
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Ammonia as a hydrogen energy-storage medium. [LH/sub 2/, MeOH, and NH/sub 3/]

Description: Liquid Hydrogen (LH/sub 2/), Methanol (MeOH), and Ammonia (NH/sub 3/) are compared as hydrogen energy-storage media on the basis of reforming the MeOH to produce H/sub 2/ and dissociating (cracking) the NH/sub 3/ to release H/sub 2/. The factors important in this storage concept are briefly discussed. Results of the comparison show that, in terms of energy input for media manufacture from natural gas, hydrogen energy content of the medium, and energy cost ($/10/sup 6/ Btu), NH/sub 3/ has a wide… more
Date: August 1, 1980
Creator: Strickland, G
Partner: UNT Libraries Government Documents Department
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