Kinetics and Mechanism of Reactions of Disubstituted Octahedral Metal Carbonyls with Phosphorus Donor Ligands and Germanium Tetraiodide
Description:
The kinetics and mechanism of the reactions of (tmpa)W-(CO)^ and (tmen)W(CO)^ (tmpa = N,N,N',N'-tetramethy1-1,3-diaminopropane and tmen = N,N,N1,N1-tetramethylethylenediamine) with four phosphorus donor ligands (triisopropyl phosphite, triphenyl phosphite, triphenylphosphine and "constrained phosphite", 4-methyl-2,6,7-trioxa-l-phosphabicylo[2.2.2]octane) in xylene have been investigated in detail. These reactions were found to take place by the ring-opening of the bidentate ligand in a reversib…
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Date:
August 1976
Creator:
Moradi-Araghi, Ahmad
Partner:
UNT Libraries