Magnetic Properties of Metal(II) Schiff Base Complexes

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Ligands prepared from various combinations of aldehydes and ketones with the appropriate aminealcohol were complexed with cupric acetate monohydrate. The complexes with O,NO or N,N,O donor atoms were synthesized to study the influences of the ligand on molecular structure, spin-spin interaction, and on the value of the exchange integral. The magnetic data indicated that of the eight Cu(II) complexes discussed, two behaved differently from known analogous compounds. Cu (benzoylacetone :ethanolamine) was compared to Cu(acac:ethanolamine), and Cu(pyrr:oaminophenol) was compared to Cu(acac:o-aminophenol). Each pair of complexes was postulated to have the same molecular structure. The synthesis and characterization of Mn(pyrr:oaminophenol) 2H2 is ... continued below

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vii, 148 leaves: ill.

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Hines, Mary Katherine May 1976.

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  • Hines, Mary Katherine

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Ligands prepared from various combinations of aldehydes and ketones with the appropriate aminealcohol were complexed with cupric acetate monohydrate. The complexes with O,NO or N,N,O donor atoms were synthesized to study the influences of the ligand on molecular structure, spin-spin interaction, and on the value of the exchange integral. The magnetic data indicated that of the eight Cu(II) complexes discussed, two behaved differently from known analogous compounds. Cu (benzoylacetone :ethanolamine) was compared to Cu(acac:ethanolamine), and Cu(pyrr:oaminophenol) was compared to Cu(acac:o-aminophenol). Each pair of complexes was postulated to have the same molecular structure. The synthesis and characterization of Mn(pyrr:oaminophenol) 2H2 is also discussed. The following physical data were collected and discussed: elemental analysis, melting point, molecular weight, infrared spectra, electronic spectra, and magnetic susceptibility.

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vii, 148 leaves: ill.

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  • May 1976

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  • July 15, 2016, 12:16 p.m.

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Hines, Mary Katherine. Magnetic Properties of Metal(II) Schiff Base Complexes, thesis, May 1976; Denton, Texas. (digital.library.unt.edu/ark:/67531/metadc663278/: accessed September 19, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; .