Experimental evidence of a dynamic Jahn-Teller effect in C-60(+)
Description:
Detailed analysis of the HOMO bandshape in the photoelectron spectrum of gaseous C60 reveals a dynamic Jahn-Teller effect in the ground state of C60+. The direct observation of three tunneling states asserts a D3d geometry for the isolated cation, originating from a strong vibronic coupling. These results show that the ionic motion of the ions plays an important role in the electron-phonon interaction.
Date:
May 20, 2002
Creator:
Canton, S.E.; Yencha, A.J.; Kukk, E.; Bozek, J.D.; Lopes, M.C.A.; Snell, G. et al.
Item Type:
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