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Actinide tetra-N-heterocyclic carbene ‘sandwiches’

Description: Article preparing highly-symmetrical, thorium and uranium octakis-carbene ‘sandwich’ complexes by ‘sandwiching’ the An(IV) cations between two anionic macrocyclic tetra-NHC ligands. The complexes are characterized by a range of experimental methods and DFT calculations.
Date: May 10, 2021
Creator: DeJesus, Joseph F.; Kerr, Ryan W. F.; Penchoff, Deborah A.; Carroll, Xian B.; Peterson, Charles C.; Arnold, Polly L. et al.
Partner: University of North Texas
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