Determination of Solute Descriptors for Illicit Drugs Using Gas Chromatographic Retention Data and Abraham Solvation Model Page: VIII
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LIST OF FIGURES
Page
Figure 1.1. Hydrogen-bond complexation reaction. Adapted from ref. 41.................... 7
Figure 1.2. Schematic diagram of the components of a typical gas chromatograph. Adapted from
http://en.wikipedia.org/wiki/gas-chromatography ....................................................................11
Figure 1.3. Picture of GC column oven and column from our la.b ...........................................13
Figure 1.4. Column efficiency. clu-in.org/characterization/technologies/images/theoreticalz.gifl3
Figure 1.5. Split/splitless injector............................................................................................. 16
Figure 1.6. Flame ionization detector.........................................................................................18
Figure 3.1. Correlation of LogtR (calculated) and LogtR (experimentally) observed for the six
columns......................................................................................................................................... 65
Figure 3.2. Correlation of LogtR (calculated) and LogtR (experimentally) observed for the six
columns ZB wax plus (a), ZB 35(b), TR- 1MS(c), TR-5(d), TG-5MS (e), TG1301 MS (f) for just
active compounds.......................................................................................................................... 69
Figure 3.3. Structure of nicotine ............................................................................................... 76
Figure 3.4. Structure of oxycodone............................................................................................77
Figure 3.5. Structure of methamphetamine................................................................................79
Figure 3.6. Structure of heroin (left) and morphine(right).........................................................80
Figure 3.7. Structure of ketamine ............................................................................................. 81viii
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Mitheo, Yannick K. Determination of Solute Descriptors for Illicit Drugs Using Gas Chromatographic Retention Data and Abraham Solvation Model, thesis, August 2015; Denton, Texas. (https://digital.library.unt.edu/ark:/67531/metadc804935/m1/9/?rotate=90: accessed July 17, 2024), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; .