The DOE gaseous diffusion plant complex makes extensive use of CFC-114 as a primary coolant. As this material is scheduled for production curtailment within the next few years, a search for substitutes is underway, and apparently workable alternatives have been found and are under testing. The presently favored substitutes, FC-c3l8 and FC-3110, satisfy ozone depletion and operational chemical compatibility concerns, but will be long-lived greenhouse gases, and thus may be regulated on that basis in the future. A further search is therefore underway for compounds with shorter atmospheric lifetimes which could otherwise satisfy operational physical and chemical requirements. A number …
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The DOE gaseous diffusion plant complex makes extensive use of CFC-114 as a primary coolant. As this material is scheduled for production curtailment within the next few years, a search for substitutes is underway, and apparently workable alternatives have been found and are under testing. The presently favored substitutes, FC-c3l8 and FC-3110, satisfy ozone depletion and operational chemical compatibility concerns, but will be long-lived greenhouse gases, and thus may be regulated on that basis in the future. A further search is therefore underway for compounds with shorter atmospheric lifetimes which could otherwise satisfy operational physical and chemical requirements. A number of such candidates are in the process of being screened for chemical compatibility in a fluorinating environment. This document presents infrared spectral data developed and used in that study for candidates recently examined, and also for many of their fluorination reaction products. The data include gas-phase infrared spectra, quantitative peak intensities as a function of partial pressure, and integrated absorbance strength in the IR-transparent atmospheric window of interest to global warming modeling. Combining this last property with literature or estimated atmospheric lifetimes, rough estimates of global warming potential for these compounds are also presented.
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Trowbridge, L. D. & Angel, E. C.Infrared absorption strengths of potential gaseous diffusion plant coolants and related reaction products,
report,
May 1, 1993;
Tennessee.
(https://digital.library.unt.edu/ark:/67531/metadc1385819/:
accessed July 16, 2024),
University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu;
crediting UNT Libraries Government Documents Department.