The catalytic efficiency of 2-pyridone and 4-pyridone (tautomers of 2-hydroxy and 4-hydroxypyridine) for transfer hydrogenolysis of dinaphthyl ether in tetralin at 450 C was investigated. The effectiveness of 2-pyridone dropped when the reaction time was increased, suggesting that the catalyst is destroyed. Reaction of a compound with bromine in CCl[sub 4] yielded a rearrangement product with a minor amount of the cyclization product; in acetonitrile, only the rearrangement product is obtained.
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The catalytic efficiency of 2-pyridone and 4-pyridone (tautomers of 2-hydroxy and 4-hydroxypyridine) for transfer hydrogenolysis of dinaphthyl ether in tetralin at 450 C was investigated. The effectiveness of 2-pyridone dropped when the reaction time was increased, suggesting that the catalyst is destroyed. Reaction of a compound with bromine in CCl[sub 4] yielded a rearrangement product with a minor amount of the cyclization product; in acetonitrile, only the rearrangement product is obtained.
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Miller, B.Catalysis and co-catalysis of bond cleavages in coal and coal analogs,
report,
January 1, 1992;
United States.
(https://digital.library.unt.edu/ark:/67531/metadc1193186/:
accessed July 16, 2024),
University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu;
crediting UNT Libraries Government Documents Department.