Southwest Retort, Volume 10, Number 8, April 1958 Page: 9
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cinium ions and stannous ion in the pres-
ence of chloride have been studied. In addi-
tion, data is now available concerning the
formation of complexes of chloride with
ferricinium ions. These tie together to aid
in elucidating further the mechanism of
the electronic transfer.
Studies have also been made of the re-
action of ferrocene in water-alcohol solu-
tion with ferric ion to yield ferrous and
ferricinium ions. This is a very rapid re-
action studied by flow techniques. The
mechanism of electron transfer appears to
be quite different here from the reduction
of ferricinium ion by stannous ion.
Complex Ions
In Fused Salts
A number of methods have been used
to study complex ions in fused salts.
Direct measurements of equilibrium con-
stants are made using solubility and po-
tentiometric techniques. The influence of
complex ions on surface free energies of so-
lutions and on ion mobilities is considered.
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REFERENCES
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Page 9
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American Chemical Society. Dallas/Fort Worth Section. Southwest Retort, Volume 10, Number 8, April 1958, periodical, April 1958; [Dallas, Texas]. (https://digital.library.unt.edu/ark:/67531/metadc111053/m1/9/: accessed May 3, 2024), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; .