Investigation of Copper-Natural Ligand Complexes by RP-HPLC Photodiode Array UV-VIS and Fluorescence Detection

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Description

In this study, reversed phase HPLC with dual UV photodiode (PDA) and fluorescence (FL) detection were used to investigate copper complexes with fulvic, caffeic, vanillic, salicylic, and adipic acids. Application of the RE method provided valuable information on the retention behavior and spectral characteristics of FA and model compounds. Even though the method was only applicable to VA, the use of the PDA detector allowed the UV-V is scanning of the separated peaks. This allowed the comparison between the UV-Vis spectra of uncomplexed species. The overall results provide an experimental framework for validation of the proposed Cu-humate interaction models.

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ix, 171 leaves : ill.

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Liao, Jing-Piin August 1992.

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  • Liao, Jing-Piin

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In this study, reversed phase HPLC with dual UV photodiode (PDA) and fluorescence (FL) detection were used to investigate copper complexes with fulvic, caffeic, vanillic, salicylic, and adipic acids. Application of the RE method provided valuable information on the retention behavior and spectral characteristics of FA and model compounds. Even though the method was only applicable to VA, the use of the PDA detector allowed the UV-V is scanning of the separated peaks. This allowed the comparison between the UV-Vis spectra of uncomplexed species. The overall results provide an experimental framework for validation of the proposed Cu-humate interaction models.

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ix, 171 leaves : ill.

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  • August 1992

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  • Aug. 27, 2014, 7:42 a.m.

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  • March 30, 2020, 1:39 p.m.

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Liao, Jing-Piin. Investigation of Copper-Natural Ligand Complexes by RP-HPLC Photodiode Array UV-VIS and Fluorescence Detection, dissertation, August 1992; Denton, Texas. (https://digital.library.unt.edu/ark:/67531/metadc332502/: accessed April 28, 2024), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; .

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