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in subjects: "Hydroxyl Radicals"

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High temperature reaction kinetics

During the last year the dependence of the apparent rate of OD + CO on water pressure was measured at 305, 570, 865 and 1223 K. An explanation was found and tested for the H/sub 2/O dependence of the apparent rate of OH(OD) + CO at high temperatures. The isotope effect for OH(D) with CO was determined over the temperature range 330 K to 1225 K. The reason for the water dependence of the rate of OH(OD) + CO near room temperatures has been investigated but no clear explanation has been found. 1 f… more

Date: January 1, 1985

Creator: Jonah, C. D.; Beno, M. F.; Mulac, W. A. & Bartels, D.

Item Type: Article

Partner: UNT Libraries Government Documents Department

open access

Energy transfer in reactive and non-reactive H/sub 2/ + OH collisions

We have used the methods of quasi-classical dynamics to compute energy transfer properties of non-reactive and reactive H/sub 2/ + OH collisions. Energy transfer has been investigated as function of translational temperature, reagent rotational energy, and reagent vibrational energy. The energy transfer mechanism is complex with ten types of energy transfer possible, and evidence was found for all types. There is much more exchange between the translational degree of freedom and the H/sub 2/ vi… more

Date: April 1, 1985

Creator: Rashed, O. & Brown, N.J.