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Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly progress report, October 1, 1979-December 31, 1979. [Pt/Rh, Ni/Rh, Ni/Pt/Rh, Ni, Ni/Ru, Ni/Pt, Ni/Co]

Description: Twelve steam reforming catalysts were evaluated using an autothermal reforming screening unit. Duplicate tests were run with two samples to determine test variability. The samples tested contained either base metals, precious metals, or combinations of base and precious metals. The test was capable of distinguishing among samples where gross variations in composition are the main factor; for example, catalysts containing 2% by weight precious metals are more active than catalysts containing 15%… more
Date: January 1, 1980
Creator: Yarrington, R M; Feins, I R; Hwang, H S & Mayer, C P
Partner: UNT Libraries Government Documents Department
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Organic components of nuclear wastes and their potential for altering radionuclide distribution when released to soil

Description: Normal waste processing at the Hanford operations requires the use of many organic materials, chiefly in the form of complexing agents and diluents. These organic materials and their chemical and radiolytic degradation products, have potential for complexing fission products and transuranium elements, both in the waste streams and upon infiltration into soil, perhaps influencing future sorption or migration of the nuclides. Particular complexation characteristics of various nuclides which const… more
Date: August 1, 1980
Creator: McFadden, K.M.
Partner: UNT Libraries Government Documents Department
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TCT hybrid preconceptual blanket design studies

Description: The conceptual design of a tokamak fusion-fission (hybrid) reactor, which produces electric power and fissile material, has been performed in a cooperative effort between Princeton's Plasma Physics Laboratory (PPPL) and Battelle's Pacific Northwest Laboratories (PNL). PPPL, who had overall project lead responsibility, designed the fusion driver system. Its core consists of a tokamak plasma maintained in the two-component torus (TCT) mode by both D and T beams and having a single null poloidal d… more
Date: January 1, 1978
Creator: Aase, D. T.; Bampton, M. C. C.; Doherty, T. J.; Leonard, B. R.; McCann, R. A.; Newman, D. F. et al.
Partner: UNT Libraries Government Documents Department
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Pacific Northwest Laboratory Report on Fusion Energy Research, April 1977 - June 1977

Description: The development of economic data for fusion power plants continued in a study estimating the potential impact of a shortage of materials important in fusion plant construction. In studies developing heat transfer and fluid flow design tools for fusion reactor blankets, preconceptual design studies were initiated to identify the potential design limits of water cooling in the first wall of Tokamak Next Step (TNS) concepts. In surface effects research clean gold samples were irradiated in the Uni… more
Date: July 1, 1977
Partner: UNT Libraries Government Documents Department
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Hydrogen bonding in asphaltenes and coal. Progress report, March 1, 1977--August 31, 1977

Description: A calorimetric method is presented for the simultaneous evaluation of equilibrium constant, K, and molar enthalpy, ..delta..H/sup 0/, for 1 : 1 adduct formation of quinoline (Qu) with asphaltene (A), together with its acid/neutral (AA) fraction and its base (BA) fraction, isolated from a centrifuged liquid product (CLP) sample prepared from Kentucky hvAb coal at 27.6 MPa hydrogen pressure and 723K, with reactor charged with glass pellets. The same procedure was used to determine K and ..delta..… more
Date: August 1, 1977
Creator: Li, N. C. & Tewari, K. C.
Partner: UNT Libraries Government Documents Department
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Price 1/sup 0/ x 2/sup 0/ NTMS area, Utah. Data report (abbreviated)

Description: Surface sediment samples were collected at 1444 sites, at a target sampling density of one site per 13 square kilometers. Ground water samples were collected at 137 sites. Neutron activation analysis results are given for uranium and 16 other elements in sediments, and for uranium and 9 other elements in ground water. Mass spectrometry results are given for helium in ground water. Field measurements and observations are reported for each site. Analytical data and field measurements are presente… more
Date: July 1, 1980
Creator: Cook, J. R.
Partner: UNT Libraries Government Documents Department
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Stream sediment detailed geochemical survey for Marysvale, Utah

Description: Results of the Marysvale detailed geochemical survey are reported. Field and laboratory data are presented for 397 stream sediment samples and 160 radiometric readings. Statistical and areal distributions of uranium and possible uranium-related variables are displayed. A generalized geologic map of the area is provided, and pertinent geologic factors which may be of significance in evaluating the potential for uranium mineralization are briefly discussed. Stream sediments containing significant… more
Date: July 31, 1980
Creator: Butz, T. R.; Vreeland, J. L.; Bard, C. S.; Helgerson, R. N.; Grimes, J. G. & Pritz, P. M.
Partner: UNT Libraries Government Documents Department
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SOME EXPERIENCES IN THE WELD FABRICATION OF REFRACTORY METALS

Description: Discussion is given on the welding fabrication of tungsten, molybdenum, niobium, and tantalum. Properties which make the four refractory metals important are tabulatcd along with titanium which is given for comparison. Extensive evaluation was conducted using the gas, tungsten arc welding process employing both manual and machine welding. Design data were obtained exclusively from machine welded sheet materials. Flash welding, resistance spot welding and brazing, electron beam welding, and high… more
Date: February 10, 1961
Creator: Thompson, E.G.
Partner: UNT Libraries Government Documents Department
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Development of passive electronic components for instrumentation of improved geothermal logging tools and components. Annual progress report

Description: Short term objectives for well-logging instrumentation are circuits which can operate at temperatures in the range 275/sup 0/C to 350/sup 0/C; the medium term goal is operation up to 500/sup 0/C, and the long term goal is to achieve operation at 1000/sup 0/C. It is apparent that useful electronic circuits will require the combination of both passive components and active devices. In order to meet the compatibility requirements, the basic technology which has been selected in this project is the… more
Date: October 20, 1977
Creator: Raymond, L.S.; Hamilton, D.J. & Kerwin, W.J.
Partner: UNT Libraries Government Documents Department
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Thermal and electrical conductivities of high purity tantalum

Description: The electrical resistivity and thermal conductivity of three high purity tantalum samples have been measured as functions of temperature over a temperature range of 5K to 65K. Sample purities ranged up to a resistivity ratio of 1714. The highest purity sample had a residual resistivity of .76 x 10/sup -10/OMEGA-m. The intrinsic resistivity varied as T/sup 3/./sup 9/ from 10K to 31K. The thermal conductivity of the purest sample had a maximum of 840 W/mK at 9.8K. The intrinsic thermal resistivit… more
Date: January 1, 1978
Creator: Archer, S. L.
Partner: UNT Libraries Government Documents Department
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Wells 1/sup 0/ x 2/sup 0/ NTMS area, Nevada. Data report (abbreviated)

Description: Surface sediment samples were collected at 1336 sites, at a target sampling density of one site per 13 square kilometers. Ground water samples were collected at 112 sites. Neutron activation analysis results are given for uranium and 16 other elements in sediments, and for uranium and 9 other elements in ground water and surface water. Mass spectrometry results are given for helium in ground water. Field measurements and observations are reported for each site. Data from ground water and surfac… more
Date: July 1, 1980
Creator: Cook, J. R.
Partner: UNT Libraries Government Documents Department
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Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly report, April 1-June 30, 1980. [Pt/Pd]

Description: Phase II of the contract, which involved catalyst preparation and evaluation, was nearly completed this quarter. Phase III, which calls for the design and construction of a fuel processor, was started. During the quarter, four types of tests were run on the small scale catalyst screening unit. The operating line for coke-free operations was found to be approximately between 0.41 to 0.44 O/sub 2//C level. Screening at lower O/sub 2//C levels led to problems with plugging. In other tests, increas… more
Date: July 1, 1980
Creator: Yarrington, R M; Feins, I R & Hwang, H S
Partner: UNT Libraries Government Documents Department
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Direct observations of the primary state of radiation damage of ion-irradiated tungsten and platinum

Description: A brief summary was presented of all the Cornell work on the primary state of radiation damage in ion-irradiated tungsten and platinum. The primary research tool for all this research was the field-ion microscope (FIM); the FIM was ideally suited for this research because of its excellent atomic resolution and the ability to examine the interior of the specimens, as a result of the field-evaporation effect. This paper summarized, in outline form, the following items: (1) the principal experimen… more
Date: July 1, 1980
Creator: Seidman, D. N.; Current, M. I.; Pramanik, D. & Wei, C. Y.
Partner: UNT Libraries Government Documents Department
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Surface damage of molybdenum and TZM alloy under D/sup +/ impact

Description: The surface damage of polycrystalline molybdenum and TZM alloy under 40-, 60-, and 120-keV D/sup +/ impact has been investigated for irradiation in both pulsed and continuous mode for total doses varying from 1.7 x 10/sup 17/ to 2.2 x 10/sup 19/ ions/cm/sup 2/ and for target temperatures verying from ambient temperature to 400/sup 0/C. Analysis by scanning electron microscopy of the MO samples held at ambient temperatures during D/sup +/ irradiations in both pulsed and continuous modes revealed… more
Date: January 1, 1977
Creator: Das, S.K.; Kaminsky, M. & Dusza, P.
Partner: UNT Libraries Government Documents Department
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Depth distributions of low energy deuterium implantations in (110) tungsten: a theoretical model

Description: The depth distributions of 80 eV D/sup +/ implants in (110) W have recently been measured by field desorption microscopy. Prominent structure, consisting of seven major and several minor peaks, is observed in the measured distributions. This contrasts with conventional implantation theory which predicts two peaks, one for the channeled D/sup +/ and one for the nonchanneled D/sup +/. The observed structure is explained in the present report by a model which ascribes the various peaks to D/sup +/… more
Date: March 1, 1978
Creator: Brice, D.K.
Partner: UNT Libraries Government Documents Department
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System model for analysis of the mirror fusion-fission reactor

Description: This report describes a system model for the mirror fusion-fission reactor. In this model we include a reactor description as well as analyses of capital cost and blanket fuel management. In addition, we provide an economic analysis evaluating the cost of producing the two hybrid products, fissile fuel and electricity. We also furnish the results of a limited parametric analysis of the modeled reactor, illustrating the technological and economic implications of varying some important reactor de… more
Date: October 12, 1977
Creator: Bender, D.J. & Carlson, G.A.
Partner: UNT Libraries Government Documents Department
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Hydrogenation of CO and CO/sub 2/ on clean rhodium and iron foils. Correlations of reactivities and surface compositions

Description: An experimental arrangement consisting of an ultrahigh vacuum bell jar equipped with an internal sample isolation cell was used to investigate the hydrogenation of CO over Fe and Rh surfaces. This apparatus permitted both UHV surface characterization (Auger electron spectroscopy, low-energy electron diffraction) and high pressure (1-20 atm) catalytic reactions to be carried out. Small surface area (approximately 1 cm/sup 2/) metal samples, both single crystals and polycrystalline foils, were us… more
Date: December 16, 1977
Creator: Dwyer, D.; Yoshida, K. & Somorjai, G.A.
Partner: UNT Libraries Government Documents Department
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Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly progress report, January 1, 1980-March 31, 1980. [Pt/Rh, Pd, Pt, Rh, Ni/Rh, Rh/Re, Ni]

Description: Catalysts are being screened to steam reform hydrocarbons in an autothermal reformer (STR). Twenty-one samples have been screened in a 1-in.-diam (ATR) reactor using No. 2 oil as the hydrocarbon feed. A series of platinum-rhodium catalysts were evaluated to study the effect of varying compositions. A sample containing 1.7% Pt/0.3% Rh was most active but the difference among the samples was within the range of test variability. Development of a more realistic test has been started. The effect of… more
Date: April 1, 1980
Creator: Yarrington, R M; Feins, I R & Hwang, H S
Partner: UNT Libraries Government Documents Department
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Chemical Vapor Deposition of Refractory Metal Reflectors for Spectrally Selective Solar Absorbers. Annual Report, May 1, 1978-April 30, 1979

Description: Three methods are described to fabricate by chemical vapor deposition (CVD) molybdenum films which rival conventional mirror materials in their infrared reflectance. With an absolute reflectance of 97.4% at 10 ..mu..m, these Super Molybdenum films reflect better than any other molybdenum film previously reported. When deposited in the presence of oxygen, films of a reduced reflectance over the solar emission range result. If passivated and antireflected by a Si/sub 3/N/sub 4/ layer, such Black … more
Date: May 1, 1979
Creator: Seraphin, B. O. & Carver, G. E.
Partner: UNT Libraries Government Documents Department
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Volatilities of ruthenium, iodine, and technetium on calcining fission product nitrate wastes

Description: Various high-level nitrate wastes were subjected to formic acid denitration. Formic acid reacts with the nitrate anion to yield noncondensable, inert gases according to the following equation: 4 HCOOH + 2 HNO/sub 3/ ..-->.. N/sub 2/O + 4 CO/sub 2/ + 5 H/sub 2/O. These gases can be scrubbed free of /sup 106/Ru, /sup 131/I, and /sup 99/Tc radioactivities prior to elimination from the plant by passage through HEPA filters. The formation of deleterious NO/sub x/ is avoided. Moreover, formic acid re… more
Date: January 1, 1980
Creator: Rimshaw, S. J. & Case, F. N.
Partner: UNT Libraries Government Documents Department
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Thermal transport properties of niobium and some niobium base alloys from 80 to 1600/sup 0/K

Description: The electrical resistivities and absolute Seebeck coefficients of 99.8 at. % niobium with a RRR of 36, Nb-4.8 at. % W, Nb-5 at. % Mo, Nb-10 at. % Mo, and Nb-2.4 at. % Mo-2.4 at. % Zr were measured from 80 to 1600/sup 0/K, and the thermal conductivities of the niobium and Nb-5 at. % W were measured from 80 to 1300/sup 0/K. A technique is described for measuring the electrical resistivity and Seebeck coefficient of a specimen during radial heat flow measurements of the thermal conductivity. The t… more
Date: January 1, 1980
Creator: Moore, J. P.; Graves, R. S. & Williams, R. K.
Partner: UNT Libraries Government Documents Department
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Combined shift and methanation in a fluidized-bed reactor. Quarterly progress report, 1 April-30 June 1980

Description: Only one bench-scale reactor test was completed. The Harshaw Ni/Cu/Mo and UCI (composition undisclosed) catalysts were evaluated over a 12-day period at 800 F and a feed gas H/sub 2//CO ratio of 2/1. Initial conversions with both catalysts were about 33 percent; and the activities of both samples declined steadily during the test, with final conversion values in the 15 to 20 percent range. During this test, problems were experienced with water carryover into the Drierite traps, necessitating so… more
Date: July 1, 1980
Creator: Streeter, R C
Partner: UNT Libraries Government Documents Department
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Liquid-metal embrittlement of refractory metals by molten plutonium

Description: Embrittlement by molten plutonium of the refractory metals and alloys W-25 wt % Re, tantalum, molybdenum, and Ta-10 wt % W was studied. At 900/sup 0/C and a strain rate of 10/sup -4/ s/sup -1/, the materials tested may be ranked in order of decreasing susceptibility to liquid-plutonium embrittlement as follows: molybdenum, W-25 wt % Re, Ta-10 wt % W, and tantalum. These materials exhibited a wide range in susceptibility. Embrittlement was found to exhibit a high degree of temperature and strain… more
Date: July 1, 1980
Creator: Lesuer, D. R.; Bergin, J. B.; McInturff, S. A. & Kuhn, B. A.
Partner: UNT Libraries Government Documents Department
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Elko 1/sup 0/ x 2/sup 0/ NTMS area: Nevada and Utah. Data report

Description: Results of ground water and surface sediment reconnaissance in the National Topographic Map Series (NTMS) Elko 1/sup 0/ x 2/sup 0/ quadrangle are presented. The target sampling density was one site per 12 square kilometers. This resulted in 1713 sediment samples being collected; however, dry conditions and sparce population contributed to the relatively small number of ground water (154) samples collected. Neutron activation analysis (NAA) results are given for uranium and 16 other elements in … more
Date: July 1, 1980
Creator: Fay, W.M.
Partner: UNT Libraries Government Documents Department
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