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Biological Production of Ethanol From Coal

Description: Research is continuing in an attempt to increase both the ethanol concentration and product ratio using C. ljungdahlii. The purpose of this report is to present data utilizing a medium prepared especially for C. ljungdahlii. Medium development studies are presented, as well as reactor studies with the new medium in batch reactors. CSTRs and CSTRs with cell recycle. The use of this new medium has resulted in significant improvements in cell concentration, ethanol concentration and product ratio.
Date: January 1, 1992
Partner: UNT Libraries Government Documents Department
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Waste Treatment and Disposal Progress Report for June and July 1961

Description: 7 7 6 4 : 9 8 9 6 5 : 9 aluminum nitrate waste was calcined in the close-coupled continuous evaporator-pot calciner unit. Waste oxides from TBP-25 waste were incorporated into glassy materials after the addition of phosphate and borate fluxing agents. Melts formed at 850 to 950 deg C were glassy solids when cooled and had densities from 2.41 to 2.47 g/ml. Waste volurne reduction factors were from 7.6 to 9.3. Low-Level Waste Treatment. A demonstration run was completed in the 60 liters/hr scaven… more
Date: October 24, 1961
Creator: Blanco, R. E. & Struxness, E. G.
Partner: UNT Libraries Government Documents Department
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Investigation on the damage threshold of films coated on various silicate, fluorophosphate and phosphate laser glasses. Final report, January 1, 1979-August 29, 1980

Description: Effects of substrate laser glass on the damage threshold and adhesion of dielectric films has been studied in order to improve the damage threshold. The study is divided into two parts: the first part dealing with four types of laser glass, LSG-91H silicate, LHG-8 phosphate, P-1 phosphate and LHG-10 fluorophosphate; the second part dealing with twenty-six glasses with systematically modified compositions in three glass systems, silicate, phosphate and fluorophosphate.
Date: January 1, 1980
Creator: Nakajima, Y & Izumitani, T
Partner: UNT Libraries Government Documents Department
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Analytical Chemistry of the Polyphosphates

Description: Additional data were obtained on the separation of linear polymers from cyclic polymers by precipitation with barium chloride. An unexpected peak was observed in the anion-exchange chromatography of a sodium poly-phosphate of n-bar average degree of polymerization) = 6, and the compound represented by this peak was isolated. An end-group titration of this compound by microtechnique proved unequivocally that it is a cyclic phosphate. Although the identification (number of phosphorus atoms per mo… more
Date: October 17, 1961
Creator: Rieman, W., III & Rothbart, H. L.
Partner: UNT Libraries Government Documents Department
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Nonlinear optical properties of new KTiOPO sub 4 isostructures

Description: The atomic structures of the nonlinear optical materials potassium titanyl phosphate (KTiOPO{sub 4}, or KTP) and potassium titanyl arsenate (KTiOAsO{sub 4}) feature one-dimensional channels through which the potassium ions are relatively free to migrate. Ion exchange results when these materials are immersed in molten salts containing alkali metal ions. Sodium, lithium and silver all exchange readily for K{sup +} single crystals of both KTP and KTA to yield the exchanged derivatives Na{sub .95}… more
Date: January 1, 1991
Creator: Phillips, M. L. F.; Harrison, W. T. A. & Stucky, G. D.
Partner: UNT Libraries Government Documents Department
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MAP3S precipitation chemistry network. Third periodic summary report, July 1978-December 1979

Description: The MAP3S Precipitation Chemistry Network consists of eight collection sites in the northeastern United States. Precipitation event samples are collected by cooperating site operators, using specially developed sampling equipment. In this, the third periodic summary report, are listed field and concentration data for the period July 1, 1978 to December 31, 1979. Over three years' samples have been collected at most of the sites, which went into operation between September 1976 and October 1978.… more
Date: May 1, 1980
Partner: UNT Libraries Government Documents Department
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Investigation of strain birefringence and wavefront distortion in 001 plates of KD sub 2 PO sub 4

Description: When 001 plates of KD{sub 2}PO{sub 4} (KD*P) are used in Pockels cells, strain induced refractive index variations result in beam depolarization and transmitted wavefront distortion. The depolarization is determined by the induced birefringence while the wavefront distortion is controlled by the average index shift. Here we show that the birefringence is determined by the shear stress in the xy-plane of the crystal while the average index shift depends only on the normal stresses. Furthermore, … more
Date: August 26, 1991
Creator: De Yoreo, J. J. & Woods, B. W.
Partner: UNT Libraries Government Documents Department
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Chemical Processing Technology Quarterly Progress Report, January-March 1961

Description: Studies are reported on aqueous zirconium processing, dissolution of BeO- UO/sub 2/ ceramic fuel, the aqueous stainless steel process, the behavior of dibutyl phosphates, use of boron (boric acid) solution to assure critical safety, fluidized bed calcination, conversion of amorphous alumina to alpha alumina, the Demonstrational Waste Calcining Facility, removal of long-lived radioisotopes from waste solutions, separation of iron, nickel, and chromiun from stainless steel waste solutions, electr… more
Date: October 31, 1962
Creator: Bower, J. R.
Partner: UNT Libraries Government Documents Department
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Biological Production of Ethanol From Coal

Description: A batch kinetic study involving Clostridium lungdahlii in a mineral medium was carried out in order to provide baseline data for the effects of nutrients on product ratio and kinetics. The use of this minimal medium containing vitamins, minerals, select amino acids and salts showed both a lower maximum specific growth rate and a lower maximum specific uptake rate than found when using a complex medium supplemented with 0.01% yeast extract. At the same time, the product ratio was improved slight… more
Date: January 1, 1990
Partner: UNT Libraries Government Documents Department
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Requirements and new materials for fusion laser systems

Description: Higher focusable power in neodymium glass fusion lasers can be obtained through the use of new materials with lower nonlinear index (n/sub 2/) and better energy storage capabilities than the presently employed silicate glass. Silicate, phosphate, fluorophosphate, and beryllium fluoride glasses are discussed in terms of fusion laser requirements, particularly those for the proposed Nova laser. Examples of the variation in spectroscopic and optical properties obtainable with compositional changes… more
Date: October 1, 1977
Creator: Stokowski, S. E.; Weber, M. J.; Saroyan, R. A. & Hagen, W. F.
Partner: UNT Libraries Government Documents Department
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Assessment of U. S. domestic capacity for producing reactor-grade thorium dioxide and controlling associated wastes and effluents

Description: Demand for reactor-grade ThO/sub 2/ is likely to increase as a result of the growing interest in the application of the thorium-uranium fuel cycle to nuclear reactors. The wastes and effluents identified with the production of ThO/sub 2/ from monazite sand are waste water, tailings, dust, smoke and gas, and radionuclides (primarily, /sup 232/Th and /sup 226/Ra). There are currently an estimated 1,500 short tons of crude thorium hydroxide byproduct that can be readily converted to reactor-grade … more
Date: February 1, 1978
Creator: Enderlin, W.I.
Partner: UNT Libraries Government Documents Department
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Ferrocyanide-containing waste tanks: Ferrocyanide chemistry and reactivity

Description: The complexing constant for hexacyano-iron complexes, both Fe(2) and Fe(3), are exceptionally large. The derived transition metal salts or double salts containing alkali metal ions are only slightly soluble. The various nickel compounds examined in this study, i.e., those predicted to have been formed in the Hanford waste scavenging program, are typical examples. In spite of their relative stability towards most reagents under ambient conditions, they are all thermodynamically unstable towards … more
Date: September 1, 1991
Creator: Scheele, R. D.; Burger, L. L.; Tingey, J. M.; Bryan, S. A.; Borsheim, G. L.; Simpson, B. C. et al.
Partner: UNT Libraries Government Documents Department
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Phase Transformations in Alumina. Technical Report, May to December 1961

Description: e transformation studies showed that synthetic aluminas produced in the laboratory were not transformed to alpha alumina at 400 to 700' deg n the presence of nitric acid and water vapor. Amorphous aluminn produced in the pilot plant was transformed to alpha alumina. This indicated that the amorphous alumina produced in the pilot plant is structurally predisposed to form alpha alumina. Most additives did not appear to have any special effects. Lithium formed zeta alumina, LiAl/sub 5/O/sub 8/. Ph… more
Date: December 1, 1961
Creator: Eding, H J; Huggins, M L & Brown, A G
Partner: UNT Libraries Government Documents Department
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Development of ultrafiltration and inorganic adsorbents for reducing volumes of low-level and intermediate-level liquid waste: July--September 1977

Description: The ultrafiltration (UF) pilot system is being evaluated at Mound Facility. The effect of pressure drop, temperature, and pH of the feed on system performance has been studied. The system has been run through a number of cleaning cycles including tap water flush, enzyme soak, detergent wash, and citric acid/oxalic acid wash. A continuous run was started on waste from the Waste Processing Facility; about 11,500 gal has been processed. Studies to determine the effect of (..cap alpha.., ..beta.., … more
Date: February 9, 1978
Creator: Koenst, J. W.; Herald, W. R. & Roberts, R. C.
Partner: UNT Libraries Government Documents Department
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Biological Production of Ethanol From Coal

Description: The effects of temperature on the growth and uptake of CO by C. ljundahlii were studied in batch culture. A maximum specific growth rate of 0.095h{sup {minus}1} was found at 37{degrees}C, a normal optimum temperature for the growth of anaerobic bacteria. A maximum specific uptake rate of 0.0095 mmol/mg{center dot}h was found at a slightly higher temperature of 40{degrees}C. CSTR studies were carried out measuring the effects of agitation rate on culture performance. As expected, growth was best… more
Date: January 1, 1991
Partner: UNT Libraries Government Documents Department
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Structural study of the high-pressure antiferroelectric phase of CsH/sub 2/PO/sub 4/

Description: A three-dimensional neutron diffraction study has been carried out on the pressure-induced antiferroelectric phase of CsH/sub 2/PO/sub 4/. At 100.7/sup 0/K and a hydrostatic pressure of 3.6 kbar, the unit cell parameters are a = 15.625(9), b = 6.254(2), c = 4.886(1) A, ..beta.. = 108.08(3)/sup 0/ and Z = 4. Atomic parameters were determined using full-matrix least-squares methods which yield final agreement indices: R(F/sup 2/) = 0.0715, R/sub w/(F/sup 2/) = 0.0807 and S = 2.13. The structure i… more
Date: January 1, 1985
Creator: Schuele, P.J. & Thomas, R.
Partner: UNT Libraries Government Documents Department
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Development of an Effective Transport Media for Juvenile Spring Chinook Salmon to Mitigate Stress and Improve Smolt Survival During Columbia River Fish Hauling Operations, 1985 Final Report.

Description: Selected transport media consisting of mineral salt additions (Na/sup +/, Cl/sup -/, Ca/sup + +/, PO/sub 4//sup -3/, HCO/sub 3//sup -/, and Mg/sup + +/), mineral salts plus tranquilizing concentrations of tricaine methane sulfonate (MS-222), or MS-222 alone were tested for their ability to mitigate stress and increase smolt survival during single and mixed species hauling of Columbia River spring chinook salmon (Oncorhynchus tshawytscha) and steelhead trout (Salmo gairdneri). Successful stress … more
Date: February 1, 1985
Creator: Wedemeyer, Gary A.
Partner: UNT Libraries Government Documents Department
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Development of tailored ceramics for geologic storage of nuclear wastes. Quarterly progress report, January 1-March 31, 1980

Description: In the second quarter of activities on developing Tailored Ceramic waste forms for SRP waste compositions, emphasis was on the chemistry controlling the incorporation of the waste elements into the crystalline phases of the high-alumina content ceramic and the major factors affecting the consolidation process. Research on the design and synthesis of oxide and phosphate ceramic waste forms has continued with emphasis on fluorite-structure oxides and on rare earth phosphates with the monazite str… more
Date: May 15, 1980
Partner: UNT Libraries Government Documents Department
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Investigations of several interference effects in high frequency plasmas of analytical importance

Description: Investigations of the extent to which certain inter-element or interference effects occur in a radiofrequency-excited inductively coupled plasma (ICP) are reported. Under conditions normally employed for analytical purposes, it is shown that: (a) two solute vaporization interferences often observed in flames are eliminated or reduced to negligible proportions in the plasma; (b) increasing concentrations of an easily ionizable element (Na) up to concentrations of 6900 ..mu..g/ml exerted an unusu… more
Date: February 1, 1977
Creator: Larson, G.F.
Partner: UNT Libraries Government Documents Department
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