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Assessment of research and development (R and D) needs in ammonia safety and environmental control

Description: This report characterizes the ammonia industry operations, reviews current knowledge of ammonia release and subsequent impacts, summarizes the status of release prevention and control methods and identify research and development needs for safety and environmental control. Appendices include: accidental spills and human exposure; adiabatic mixing of liquid nitrogen and air; fire and explosion hazards; and environmental impact rating tables. (PSB)
Date: September 1, 1981
Creator: Brenchley, D.L.; Athey, G.F. & Bomelburg, H.J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Sintering of polycrystalline ionic conductors:. beta. ''-Al/sub 2/O/sub 3/ and NASICON

Description: The densification kinetics for both ..beta..''-alumina and NASICON are dramatically different. ..beta..''-Alumina sinters by a reactive liquid process whereas NASICON densifies by a solid state method. More importantly, a qualitative examination of particle and agglomerate distributions, phase composition, linear shrinkage analysis, and heating rate effects can result in a concise determination of sintering processes without recourse to more quantitative techniques. Such a s… more
Date: January 1, 1979
Creator: McEntire, B. J.; Miller, G. R. & Gordon, R. S.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Alkali sorber (RABSAM), September 1, 1990--August 30, 1991

Description: The objective of this work is to develop a regenerable activated-bauxite sorber alkali monitor that requires no high-temperature/high-pressure sampling line for the reliable in situ measurement of alkali-vapor concentration in the exhaust from the pressurized fluidized-bed combustion of coal. 11 refs., 2 figs., 1 tab.
Date: January 1, 1991
Creator: Lee, S. H. D. & Swift, M. W.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Tumor production in Syrian hamsters following inhalation of PuO/sub 2/--ZrO/sub 2/ aerosol

Description: Syrian golden hamsters of both sexes were exposed to aerosols of ZrO/sub 2/ containing PuO/sub 2/. The starting material in the aerosol generator also had a small amount of /sup 57/Co added as a tracer. The mixture of all three constituents was nebulized and the droplets passed through a heating column at 1000/sup 0/C. Aerosol sampling was accomplished with a cascade impactor and electrostatic precipitator. The median aerodynamic diameters in all inhalation runs were approximately 2 ..mu..m wit… more
Date: January 1, 1978
Creator: Thomas, R. G. & Smith, D. M.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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A Novel Coal Feeder for Production of Low Sulfur Fuel

Description: During the past three months, the coal feeding system has been tested and currently undergoing evaluation at the University of Cincinnati. The system consists primarily of an auger feed tube which is used to both convey and provide desulfurization of a high sulfur coal feedstock. The coal is conveyed at temperatures ranging from 350 to 550{degrees}C and under normal atmospheric pressure. Under these mild processing conditions, the coal partially pyrolizes and emits sulfur in the form of hydroge… more
Date: January 1, 1990
Creator: Khang, S. J. & Keener, T. C.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Redox reactions involving chromium, plutonium, and manganese in soils

Description: Plutonium speciation in soils is discussed. Chromium was selected as a model for studying soil Pu. Similarities between Cr and Pu are pointed out, and a hypotheses concerning Pu speciation in soils is presented. Findings from Cr oxidation studies that may be relevant to the problem of Pu oxidation in soils are discussed. (JGB)
Date: January 1, 1979
Creator: Amacher, M.C. & Baker, D.E.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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BRAZING OF CERAMICS. Progress Report

Description: Brazing alloys such as 48 Ti-48 Zr-4 Be (wt%) and 49 Ti-49 Cu-2 Be (wt%) have been found to readily flow on oxide and graphite ceramics. Two demonstrati on fuel element assemblies were fabricated to illustrate the usefulness of these procedures for nuclear applications. One of these assemblies contained graphite tubes and end caps which were brazed to a molybdenum hanger. The second demonstration fuel element was composed of a compartmented aluminum oxide plate to which aluminum oxide cover pla… more
Date: November 1, 1962
Creator: Fox, C.W.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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NQR-NMR studies of higher alcohol synthesis Cu-Co catalysts

Description: Copper and cobalt are the key elements in syngas conversion catalyst systems used for higher alcohol synthesis. Their proximity and synergy sensitively control the selectivity and efficiency of the process. It is believed that their outer electronic charge distribution which is responsible for their electrical and magnetic properties might be governing their catalytic properties also. To examine the correlation between catalytic and magnetic properties, a series of copper cobalt catalysts (Co/C… more
Date: January 14, 1991
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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High temperature ceramic membrane reactors for coal liquid upgrading

Description: In this project we intend to study a novel process concept, i.e, the use of ceramic membranes reactors in upgrading of coal derived liquids. Membrane reactors have been used in a number of catalytic reaction processes in order to overcome the limitations on conversion imposed by thermodynamic equilibrium. They have, furthermore, the inherent capability for combining reaction and separation in a single step. Thus they offer promise for improving and optimizing yield, selectivity and performance … more
Date: January 1, 1992
Creator: Tsotsis, T.T.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Measurements of the dependence of damage thresholds on laser wavelength, pulse duration and film thickness

Description: Results of three experiments will be described. We used 351-nm and 355-nm pulses with durations of 0.6, 1, 5 and 9 ns measure thresholds for a variety of anti-reflectance and high reflectance coatings. The functional form t/sup m/, with t the pulse duration, was used to scale fluence thresholds measured at 0.6 ns to those measured at 9.0 ns. Values of the coefficient m ranged from 0.10 to 0.51. The average value was 0.30. In the second experiment, we measured thresholds at 1064 nm, 527 nm and 3… more
Date: March 1, 1984
Creator: Rainer, F.; Vercimak, C.L.; Milam, D.; Carniglia, C.K. & Tuttle Hart, T.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Irradiation experiment for lithium ceramics

Description: Solid breeder materials are required in D-T fusion reactor blankets to convert fusion neutrons to tritium and thermal energy while providing some neutron shielding for the magnets. Lithium compounds such as Li/sub 2/O, LiAlO/sub 2/, Li/sub 4/SiO/sub 4/ and Li/sub 2/ZrO/sub 3/ have been proposed as solid breeder materials. Tritium is necessary to maintain the fuel supply for the D-T fusion reaction. No high burnup irradiation performance data is available for these materials in a neutron environ… more
Date: March 1, 1982
Creator: Hollenberg, G.W.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Phosphate-bonded glass cements for geothermal wells. Final report

Description: Calcium aluminosilicate glasses were found to react with phosphoric acid in three ways depending upon silica content. Above 55% SiO/sub 2/ they are insoluble while below 50% they dissolve readily. The transition compositions release calcium and aluminum ions and a silica gel phase replaces the glass. Activation energies in the order of 10 kcal/mole are associated with the dissolution. Equilibrium studies in the systems CaO-P/sub 2/O/sub 5/-H/sub 2/O, Al/sub 2/O/sub 3/-P/sub 2/O/sub 5/-H/sub 2/O… more
Date: September 1, 1979
Creator: Rockett, T.J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Evidence of former higher temperatures from alteration minerals, Bostic 1-A well, Mountain Home, Idaho

Description: Cuttings from the silicic volcanics in the Bostic 1-A well near Mountain Home, Idaho have been examined petrographically with the assistance of x-ray diffraction and electron microprobe analyses. Results indicate that these rocks have been subjected to much higher temperatures than were observed in the well in 1974, when a static temperature log was run. It is not known to what extent the alternation may be due to greater depth of burial in the past, or whether it resulted from an early hydroth… more
Date: January 1, 1982
Creator: Arney, B.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Pacific Northwest Laboratory Report on Fusion Energy Research, April 1977 - June 1977

Description: The development of economic data for fusion power plants continued in a study estimating the potential impact of a shortage of materials important in fusion plant construction. In studies developing heat transfer and fluid flow design tools for fusion reactor blankets, preconceptual design studies were initiated to identify the potential design limits of water cooling in the first wall of Tokamak Next Step (TNS) concepts. In surface effects research clean gold samples were irradiated in the Uni… more
Date: July 1, 1977
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Progress report on the development of the General Atomic thermochemical water-splitting process

Description: The major accomplishments of the DOE funded part of the GA thermochemical water-splitting program are reported. They include: completion of installation of all bench-scale equipment; operation and preliminary data acquisition for bench-scale subunits I and II; design, installation and operation of a system for iodine removal from the low phase; review and modification of Section III of the engineering flowsheet resulting in an increase in process efficiency and decrease in capital cost; and com… more
Date: August 1, 1980
Creator: Besenbruch, G.E.; Allen, C.L.; Brown, L.C.; McCorkle, K.; Rode, J.S.; Norman, J.H. et al.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Interaction of noble-metal fission products with pyrolytic silicon carbide

Description: Fuel particles for the High-Temperature Gas-Cooled Reactor (HTGR) contain layers of pyrolytic carbon and silicon carbide, which act as a miniature pressure vessel and form the primary fission product barrier. Of the many fission products formed during irradiation, the noble metals are of particular interest because they interact significantly with the SiC layer and their concentrations are somewhat higher in the low-enriched uranium fuels currently under consideration. To study fission product-… more
Date: January 1, 1982
Creator: Lauf, R. J. & Braski, D. N.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Preliminary study of the favorability for uranium in the Madera Limestone, and Cutler and Chinle Formations of the Sierra Nacimiento-Jemez Mountains area, New Mexico

Description: Small, surficial, secondary uranium deposits are present in several formations in the Sierra Nacimiento-Jemez Mountains region, but none of significant size are known. Field surveys indicate that the deposits are laterally discontinuous and are, in most cases, associated with carbonaceous debris. Mineral contents of as much as 0.18 percent U/sub 3/O/sub 8/ are recorded. There are 2 known deposits in the Pennsylvanian Madera Limestone, 18 in the Permian Cutler Formation, and 3 in the Triassic Ch… more
Date: January 1, 1978
Creator: Vizcaino, H. P.; O'Neill, A. J. & Dotterer, F. E.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Gas chromatographic studies of the relative retention of the sulfur isotopes in carbonyl sulfide, carbon disulfide, and sulfur dioxide

Description: A precision gas chromatograph, coupled to a quadrupole mass spectrometer and an on-line computer, was used to study the fractionation on Porasil A of the /sup 32/S//sup 34/S isotopic pair in a variety of sulfur-containing molecules. Carbonyl sulfide (COS) yielded an average ..cap alpha.. value of 1.00074 +- 0.00017 (standard deviation) for the temperature range 25/sup 0/C to 75/sup 0/C. The carbon disulfide (CS/sub 2/) value was 1.00069 +- 0.00023 for the range 53/sup 0/C to 103/sup 0/C, and th… more
Date: January 18, 1980
Creator: Fetzer, J.C. & Rogers, L.B.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Enhancing the use of coals by gas reburning-sorbent injection

Description: The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices; tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed tech… more
Date: December 22, 1988
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Efficiencies of gas neutralizers for multi-MeV beams of light negative ions

Description: Measurements are reported of the neutral and charged particle fractions produced by running beams of Li/sup -/, C/sup -/, O/sup -/, and Si/sup -/ at energies up to 7 MeV through gas cells of N/sub 2/, Ar, or CO/sub 2/. We discuss the implications of these measurements for the design of neutralizers to produce high energy light atom beams for heating or current drive in tokamaks.
Date: November 1, 1981
Creator: Grisham, L. R.; Post, D. E.; Johnson, B. M.; Jones, K. W.; Barette, J.; Kruse, T. H. et al.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Organic iodine removal from simulated dissolver off-gas streams using silver-exchanged mordenite

Description: The removal of methyl iodide by absorption onto silver mordenite was studied using a simulated off-gas from the fuel dissolution step of a nuclear fuel reprocessing plant. The methyl iodide absorption of silver mordenite was examined for the effects of NO/sub x/, humidity, iodine concentration, filter temperature, and filter pretreatment. The highest iodine loading achieved in these tests has been 34 mg CH/sub 3/I per g of substrate, approximately five times less than the elemental iodine loadi… more
Date: January 1, 1980
Creator: Jubin, R. T.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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High temperature ceramic membrane reactors for coal liquid upgrading

Description: In this project we will study a novel process concept, i.e., the use of ceramic membrane reactors in upgrading of coal model compounds and coal derived liquids. In general terms, the USC research team is responsible for constructing and operating the membrane reactor apparatus and for testing various inorganic membranes for the upgrading of coal derived asphaltenes and coal model compounds. The USC effort will involve the principal investigator of this project and two graduate research assistan… more
Date: January 1, 1992
Creator: Tsotsis, T.T.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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