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Magnetic ordering in a vanadium-organic coordination polymer using a pyrrolo[2,3-d:5,4-d0] bis(thiazole)-based ligand

Description: This article presents the synthesis and characterization of a hybrid vanadium-organic coordination polymer with robust magnetic order, a Curie temperature TC of ~110 K, a coercive field of ~5 Oe at 5 K, and a maximum mass magnetization of about half that of the benchmark ferrimagnetic vanadium(tetracyanoethylene)~₂ (V·(TCNE)~₂).
Date: October 11, 2018
Creator: Getmanenko, Yulia A.; Mullins, Christopher S.; Nesterov, Vladimir N.; Lake, Stephanie; Risko, Chad & Johnston-Halperin, Ezekiel
Item Type: Refine your search to only Article
Partner: UNT College of Science
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Oxovanadium(IV) Complexes of Substituted N-(2-Thiophenyl)Salicylideneimine

Description: In an effort to study the spectral, magnetic, and stereochemical properties of vanadyl complexes, both a new series of vanadyl complexes derived from type (VII) ligands with subnormal magnetic moment and from type (VIII) ligands with normal magnetic moment are synthesized and characterized.
Date: June 1970
Creator: Lee, Cheng Chang
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
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Experimental and Computational Studies of the Isomerization Reactions of Bidentate Phosphine Ligands in Triosmium Clusters: Kinetics of the Rearrangements from Bridged to Chelated Isomers and X-ray Structures of the Clusters Os3 (CO)10 (dppbz), 1,1-Os3 (CO)10 (dppbzF4), HOs3 (CO)9 [μ -1,2-PhP (C6H4-ɳ1) C6H4PPh2], and HOs3 (CO)9- [μ-1,2-PhP (C6H4-ɳ 1) C6F4PPh2]

Description: Article on experimental and computational studies of the isomerization reactions of bidentate phosphine ligands in triosmium clusters.
Date: February 22, 2011
Creator: Zhang, Xue; Kandala, Srikanth; Yang, Li; Watson, William H.; Wang, Xiaoping; Hrovat, David A. et al.
Item Type: Refine your search to only Article
Partner: UNT College of Arts and Sciences
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New Vistas for Functionalized Polyoxometalates

Description: Polyoxometalates (POMs) - the multimetallic oxoanions [MxOyXz]n? formed by Mo, W, and, to a lesser extent, V, Nb and Ta ? have been described as "a class of inorganic compounds that is unmatched in terms of molecular and electronic structural versatility, reactivity, and relevance". The remarkable breadth of POM chemistry, which extends to areas as diverse as catalysis, medicine, imaging, photo- and electrochromism, and magnetic materials, derives from the confluence of the species' attractive … more
Date: April 21, 2006
Creator: Maatta, Eric A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Unusual Electronic Features and Reactivity of the Dipyridylazaallyl Ligand: Characterizations of (smif)2M [M = Fe, Co, Co+, Ni; smif = {(2-py)CH}2N] and [(TMS)2NFe]2(smif)2

Description: Article discussing unusual electronic features and reactivity of the dipyridylazaallyl ligand and characterizations of (smif)2M [M = Fe, Co, Co+, Ni; smif = {(2-py)CH}2N and [(TMS)2NFe] 2(smif)2.
Date: February 19, 2009
Creator: Frazier, Brenda A.; Wolczanski, Peter T.; Lobkovsky, Emil B. & Cundari, Thomas R., 1964-
Item Type: Refine your search to only Article
Partner: UNT College of Arts and Sciences
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Heats of Solution of the Cobaltous Nitrate Hydrates in Water and in Certain Organic Solvents and Binding Energies of Molecular Ligands

Description: Abstract: "Heats of solution have been measured for the hexahydrate, tetrahydrate, trihydrate and dihydrate of cobaltus nitrate in water and in a series of organic solvents, including isobutyl alcohol, diethyland monoethyl ether of ethylene glycol, acetone, methyl ethyl ketone, tetrahydrofuran, tributyl phosphate and dimethyl formanide. For some solvents, where the solubility of the salt of its reaction product was insufficient, measurements were made in a mixture with acetone. Such solvents in… more
Date: February 1952
Creator: Katzin, Leonard I. & Ferraro, John R.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Actinide tetra-N-heterocyclic carbene ‘sandwiches’

Description: Article preparing highly-symmetrical, thorium and uranium octakis-carbene ‘sandwich’ complexes by ‘sandwiching’ the An(IV) cations between two anionic macrocyclic tetra-NHC ligands. The complexes are characterized by a range of experimental methods and DFT calculations.
Date: May 10, 2021
Creator: DeJesus, Joseph F.; Kerr, Ryan W. F.; Penchoff, Deborah A.; Carroll, Xian B.; Peterson, Charles C.; Arnold, Polly L. et al.
Item Type: Refine your search to only Article
Partner: University of North Texas
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NRPreTo: A Machine Learning-Based Nuclear Receptor and Subfamily Prediction Tool

Description: Article asserts that the nuclear receptor (NR) superfamily includes phylogenetically related ligand-activated proteins, which play a key role in various cellular activities. The authors developed Nuclear Receptor Prediction Tool (NRPreTo), a two-level NR prediction tool with a unique training approach where in addition to the sequence-based features used by existing NR prediction tools, six additional feature groups depicting various physiochemical, structural, and evolutionary features of prot… more
Date: May 30, 2023
Creator: Madugula, Sita Sirisha; Pandey, Suman; Amalapurapu, Shreya & Bozdag, Serdar
Item Type: Refine your search to only Article
Partner: UNT College of Engineering
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Synthesis and Screening of a Combinatorial Peptide Library for Ligands to Target Transferrin: Miniaturizing the Library

Description: Combinatorial libraries are used in the search for ligands that bind to target proteins. Fmoc solid-phase peptide synthesis is routinely used to generate such libraries. Microwave-assisted peptide synthesis was employed here to decrease reaction times by 80-90%. Two One-Bead-One-Compound combinatorial libraries were synthesized on 130μm beads (one containing 750 members and the other 16, 807). The use of smaller solid supports would have many important practical advantages including; increased … more
Date: August 2010
Creator: Brown, Jennifer Marie
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries

Diphosphine Ligand Substitution in H4Ru4(CO)12: X-ray Diffraction Structures and Reactivity Studies of the Diphosphine Substituted Cluster Products

Description: The tetraruthenium cluster H4Ru4(CO)12 has been studied for its reactivity with the unsaturated diphosphine ligands (Z)-Ph2PCH=CHPPh2, 4,5-bis (diphenylphosphino)-4-cyclopenten-1,3-dione, bis(diphenyphosphino)benzene and 1,8- bis(diphenyl phosphino)naphthalene under thermal, near-UV photolysis, and Me3NO-assisted activation. All three cluster activation methods promote loss of CO and furnish the anticipated substitution products that possess a chelating diphosphine ligand. Clusters 1, 2, 3 and … more
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Date: December 2006
Creator: Kandala, Srikanth
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
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Six-, Five-, and Four-Coordinate Ruthenium(II) Hydride Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis, Characterization, Fundamental Reactivity, and Catalytic Hydrogenation of Olefins, Aldehydes, and Ketones

Description: This article discusses six-, five-, and four-coordinate ruthenium(II) hydride complexes.
Date: February 20, 2009
Creator: Lee, John P.; Ke, Zhuofeng; Ramírez, Magaly A.; Gunnoe, T. Brent; Cundari, Thomas R., 1964-; Boyle, Paul D. et al.
Item Type: Refine your search to only Article
Partner: UNT College of Arts and Sciences
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Oxygen atom transfer catalysis by dioxidomolybdenum(VI) complexes of pyridyl aminophenolate ligands

Description: This article synthesizes and characterizes a series of new cationic dioxidomolybdenum(VI) complexes [MoO₂(Lⁿ)]PF₆ (2–5) with the tripodal tetradentate pyridyl aminophenolate ligands HL²-HL⁵.
Date: April 21, 2021
Creator: Hossain, Kamal; Schachner, Jörg A.; Haukka, Matti; Richmond, Michael G.; Mösch-Zanetti, Nadia C.; Lehtonen, Ari et al.
Item Type: Refine your search to only Article
Partner: UNT College of Science
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The Effects of Iron Complexing Ligands on the Long Term Ecosystem Response to Iron Enrichment of HNLC waters

Description: The central hypothesis of this project is that natural iron-complexing organic ligands in seawater differentially regulate iron availability to large (microplankton) and small (nano and picoplankton) class of phytoplankton and thereby strongly influence the potential carbon sequestration in High Nitrate Low Chlorophyll (HNLC) regions of the ocean. The primary project goals are to: 1) determine how different natural and synthetic Fe chelators affect Fe availability to phytoplankton species that … more
Date: November 18, 2006
Creator: Wells, Mark L.; Perry, Mary Jane; Cochlan, William P. & Trick, Charles G.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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The Nature of Intermediates Produced Through Ligand-Substitution Reactions of Octahedral Metal Carbonyls

Description: Pulsed laser time-resolved ligand-substitution photochemistry for (DTO)W(CO)4, (DTN)W(CO)4, and (NP)Mo(CO)4 (DTO = 2,2,7,7-tetramethyl-3,6-diathiaoctane; DTN = 2,2,8,8- tetramethyl-3,7-diathianonane; NP = l-diethylamino-2- diphenylphosphinoethane) proceeds via initial fission of the W-S and Mo-P bonds, affording Cs and C4v five-coordinate intermediates for DTN and NP but largely Cs for DTO. The rates of reaction of these intermediates, via chelate ring closure and competitive bimolecular intera… more
Date: May 1986
Creator: Mansour, Saber E. (Saber El-Sayed)
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
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