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Proof of concept testing of an integrated dry injection system for SO sub x /NO sub x control

Description: The objectives of the subscale test program were designed to provide sorbent and additive selection guidance, and, in so doing, supply answers to the questions posed in the preceding section. The objectives are: Identify the best commercial hydrate sorbent and the best enhanced hydrate sorbent from a list of nine types, based upon S0{sub 2} removal at Ca/S=2. Determine the relative effectiveness of sodium sesquicarbonate versus sodium bicarbonate for S0{sub 2} and NO{sub x} control over the tem… more
Date: January 1, 1989
Creator: Helfritch, D.J.; Bortz, S.J. (Research-Cottrell, Inc., Somerville, NJ (United States). Environmental Services and Technologies Div.) & Beittel, R. (Riley Stoker Corp., Worcester, MA (United States))
Partner: UNT Libraries Government Documents Department
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700, 100, and 20 hp combustion test facility yearly activity report for the period April 1, 1979 to April 1, 1980

Description: Management and Technical Services Co./ General Electric was awarded the contract to operate, modify and maintain the DOE/PETC 700 hp, 100 hp, and 20 hp Combustion Test Facility. These facilities were designed and built by the Department of Energy at Pittsburgh Energy Technology Center and its ultimate success is the responsibility of DOE/PETC. MATSCO/GE will provide support to assist in the goal of successful operation of this pilot plant facility. The primary objective of the DOE/PETC 700 hp a… more
Date: January 1, 1980
Partner: UNT Libraries Government Documents Department
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Modeling of Integrated Environmental Control Systems for Coal-Fired Power Plants Quarterly Report: November-December 1987

Description: This is the first quarterly report of DOE/PETC Contract No. DE-AC22-87PC79864, entitled, Modeling of Integrated Environmental Control Systems for Coal-Fired Power Plants.'' Refining, creating, and documenting of computer models concerning coal/flue gas cleaning and desulfurization are discussed. (VC)
Date: January 1, 1988
Creator: Rubin, E. S.
Partner: UNT Libraries Government Documents Department
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Interactive Chemistry of Coal-Petroleum Processing

Description: The objective of this program is to investigate the interactive thermal and catalytic chemistry of coal and petroleum processing using model compounds and actual petroleum-coal materials. This quarter the interactive catalytic chemistry of model coal and petroleum systems was investigated using combined catalysts of molybdenum naphthenate and vanadyl acetylacetonate. This combination was performed in order to evaluate the effect of the presence of an indigenous residuum metal, vanadium, on mode… more
Date: January 1, 1989
Creator: Curtis, C. W.; Guin, J. A. & Tarrer, A. R.
Partner: UNT Libraries Government Documents Department
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Development of significantly improved catalysts for coal liquefaction and upgrading of coal extracts. Quarterly progress report No. 7, April 1-June 30, 1983

Description: A series of twenty-five experimental bead catalysts were tested for coal liquefaction activity in batch screening trials. Six factors relating to support preparation and composition, molybdenum, nickel, and cobalt levels, and additives, were varied according to a statistical design. Molybdenum (MoO/sub 3/) and NiO/CoO promotor levels were found to correlate most closely with coal conversion and sulfur removal. Support composition and additive variables had detrimental effects only at particular… more
Date: January 1, 1983
Creator: Sinha, V. T.; Wolfson, S. L.; Kutzenco, P. D.; Preston, W. J.; Graham, S. W.; Brinen, J. S. et al.
Partner: UNT Libraries Government Documents Department
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Cost of meeting geothermal hydrogen sulfide emission regulations. [DOW, EIC, Stretford, and iron catalyst processes]

Description: H{sub 2}S emission abatement processes considered feasible for control of airborne emissions included two upstream and two downstream treatment techniques. From literature describing the technical aspects of the processes, individual treatment cost functions were developed. These functions were then used to estimate the range of costs that may be encountered when controlling H{sub 2}S emissions to meet given standards. Treatment costs include estimates of certain fixed charges and overheads tha… more
Date: January 1, 1980
Creator: Wells, K.D.; Currie, J.W.; Weakley, S.A. & Ballinger, M.Y.
Partner: UNT Libraries Government Documents Department
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SALT (System Analysis Language Translater): A steady state and dynamic systems code

Description: SALT (System Analysis Language Translater) is a lumped parameter approach to system analysis which is totally modular. The modules are all precompiled and only the main program, which is generated by SALT, needs to be compiled for each unique system configuration. This is a departure from other lumped parameter codes where all models are written by MACROS and then compiled for each unique configuration, usually after all of the models are lumped together and sorted to eliminate undetermined var… more
Date: January 1, 1983
Creator: Berry, G. & Geyer, H.
Partner: UNT Libraries Government Documents Department
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Effects of calcium magnesium acetate on the combustion of coal-water slurries

Description: The general objectives of the project is to investigate the combustion behavior of single Coal-Winter Slurry particles burning at high temperature environments. Both uncatalyzed as well as catalyzed CWS drops with Calcium Magnesium Acetate (CMA) catalyst will be investigated. Emphasis will also be given in the effects of CMA on the sulfur capture during combustion.
Date: January 1, 1989
Partner: UNT Libraries Government Documents Department
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Project for laboratory study for removal of organic sulfur from coal

Description: Major accomplishments are listed: 1. It was found that molten sodium hydroxide (in place of mixed sodium and potassium hydroxides) followed by dilute sulfuric acid wash gave Gravimelt coal with the usual amount of sulfur and mineral matter removal but there was no MAF heat content loss over the small amount required for replacement of sulfur atoms by oxygen atoms in the coal structure - e.g., these samples had both measured heat content and MAF heat content in excess of 1400 Btu/lb. Therefore, … more
Date: January 15, 1981
Partner: UNT Libraries Government Documents Department
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Studies in Coal Liquefaction With Application to the SRC and Related Processes. Quarterly Report, August 1981-October 1981. [Using Model Compounds]

Description: Model compound reactions were studied to evaluate the effects of mass transfer, solvent type, solvent blending, hydrogen partial pressure, temperature, reactant concentration, additive loading and its preparation, etc. Naphthalene hydrogenation and benzothiophene hydrodesulfurization were investigated under the conditions comparable to commercial coal liquefaction and related processes. Both of these reaction systems were observed to be surface reaction controlled under the reaction conditions … more
Date: January 1, 1981
Creator: Tarrer, A. R.; Guin, J. A. & Curtis, C. W.
Partner: UNT Libraries Government Documents Department
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SRC-1 Quarterly technical report, April-June 1980

Description: The SRC-1 quarterly report has chapters on: an evaluation of current technologies for deashing coal liquids; domestic vendors of thick-wall pressure vessels; a comparative evaluation of GKT, Texaco and Shell-Koppers gasification processes (GKT is a modification of Koppers-Totzek and is recommended for reasons given); disposal or gasification of residues; evaluation of one or two slurry feed tanks; evaluation of one or two critical solvent deashing trains; analysis of causes of corrosion in the … more
Date: January 1, 1980
Partner: UNT Libraries Government Documents Department
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Coal desulfurization by a microwave process. Technical progress report, February 1981-May 1981

Description: Desulfurization experiments were carried out using the 6KW, 2450 MHz Flow Reactor System. The program has been directed toward the combination of physical separation and microwave exposure with NaOH to increase sulfur removal. The following treatment sequence has been used with good results: (1) expose 1/4 to 1 in. raw coal to microwaves; (2) crush the treated coal and separate the sample into float/sink fractions; (3) add NaOH to the float fraction and re-expose the sample to microwaves; and (… more
Date: January 1, 1981
Creator: Zavitsanos, P. D.; Golden, J. A. & Bleiler, K. W.
Partner: UNT Libraries Government Documents Department
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Development of new catalysts for coal liquids refining. Fourth quarterly report, October 1-December 31, 1979

Description: Base-line catalyst testing conditions for hydrotreating SRC-II fuel Oil Blend have been determined: temperature, 750/sup 0/F; pressure, 1000 psig; LHSV, 1 ml/ml-hr; and H/sub 2/ flow rate, 5000 SCF/bbl. At these conditions the average values for HDN and HDS after 24 hours on stream are approx. = 85% and 90% respectively with the best series of Ni-Mo on ..gamma..-alumina. Nickel and cobalt tungstate are significantly poorer catalysts. They afford 60-40% HDN and 85-75% HDS respectively. Nickel mo… more
Date: January 1, 1980
Partner: UNT Libraries Government Documents Department
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Modeling of Integrated Environmental Control Systems for Coal-Fired Power Plants. Technical Progress Report, [Period Ending December 31, 1987]

Description: This is the first quarterly report of DOE/PETC Contract No. DE-AC22-87PC79864, entitled, ``Modeling of Integrated Environmental Control Systems for Coal-Fired Power Plants.`` Refining, creating, and documenting of computer models concerning coal/flue gas cleaning and desulfurization are discussed. (VC)
Date: January 1, 1988
Creator: Rubin, E. S.
Partner: UNT Libraries Government Documents Department
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Application of the SULF-X process to coal conversion and utilization. Phase II final report

Description: Pittsburgh Environmental and Energy Systems, Inc. contracted with the Department of Energy to demonstrate the efficacy of an iron sulfide flue gas treatment system (FGT) for removing sulfur dioxide (SO/sub 2/) and nitrogen oxides (NO/sub x/) and to correlate process variables to system performance. Laboratory and bench-scale testing was conducted with the SULF-X process, using both synthesized gas and actual flue gas from a coal-fired furnace. Laboratory tests resulted in 95% SO/sub 2/ removal … more
Date: January 1, 1984
Creator: Shapiro, E.; Bramer, H.C. & New, R.A.
Partner: UNT Libraries Government Documents Department
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Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes]

Description: This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulate… more
Date: January 1, 1982
Creator: Jablonski, G.; Hamm, J. R.; Alvin, M. A.; Wenglarz, R. A. & Patel, P.
Partner: UNT Libraries Government Documents Department
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KVB coal desulfurization process development. Quarterly technical progress report, October-December 1980

Description: This is the second technical progress report for the KVB Coal Desulfurization Process Development. The project is a joint venture between Research-Cottrell, Inc. and the College of Engineering of Rutgers University. The process involves oxidation of the sulfur in coal (both organic and pyritic) to soluble forms using nitrogen oxide gas mixtures and subsequent extractive removal. Key features of the process are mild reaction conditions and the use of a regenerable oxidant. Construction of a benc… more
Date: January 1, 1980
Partner: UNT Libraries Government Documents Department
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Studies in Coal Liquefaction With Application to the SRC and Related Processes. Quarterly Report, May-July 1981

Description: This report discusses a kinetic investigation of the Fe-S-H/sub 2/ system conducted as an outgrowth of current research in the SRC-I (solvent refined coal) process to better understand the effects of naturally occurring iron sulfides in coal hydrogenation and hydrodesulfurization. A total of twelve closed system reactions were carried out in which 48 to 60 mesh pyrite, in the presence of hydrogen gas, underwent transformation to 1C hexagonal pyrrhotite. Reaction temperatures were 350/sup 0/C an… more
Date: January 1, 1981
Creator: Guin, J. A.; Curtis, C. W. & Tarrer, A. R.
Partner: UNT Libraries Government Documents Department
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[Surface studies of absorbents for the removal of SO[sub x] and NO[sub x]]

Description: During this quarter, we studied the x-ray absorption spectra of CaO and CaSO[sub 4] at high temperatures and used standard models to determine the calcium environment during coal combustion. The theoretical effort during this quarter was directed toward modeling the electronic structure of CuO supported on alumina; this is necessary for understanding the chemisorption processes for surface oxide and nitrogen oxide components of flue gas. 8 figs.
Date: January 1, 1988
Creator: Cooper, B. R. & Montano, P. A.
Partner: UNT Libraries Government Documents Department
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Surface magnetic enhancement for coal cleaning

Description: Phase I study, which investigates the fundamental chemistry and properties of magnetizing reagents, is completed in this reporting period. Phase II study is initiated to apply the results of Phase I study for coal cleaning. Coal samples for Phase II work have been selected, ordered, and received. Processing and characterization of coal samples are in progress. Preliminary tests show that significant ash and sulfur reduction can be obtained with the magnetizing reagent method. The work is slight… more
Date: January 1, 1989
Creator: Hwang, J. Y.
Partner: UNT Libraries Government Documents Department
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Surface magnetic enhancement for coal cleaning

Description: The fundamental chemistry for selective adsorption of magnetizing reagent on coal-associated minerals to enhance the magnetic susceptibility of minerals have been established in Phase I study. The application of the results on coal cleaning is in progress in the Phase II study. The task in Phase II study for coal selection, preparation, and characterization is completed in this reporting period. The optimization of adsorption conditions for {minus}48 mesh ROM coals and flotation concentrates is… more
Date: January 1, 1989
Creator: Hwang, J. Y.
Partner: UNT Libraries Government Documents Department
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Surface magnetic enhancement for coal cleaning

Description: The fundamental chemistry for selective adsorption of magnetizing reagent on coal-associated minerals to enhance the magnetic susceptibilities of minerals have been established in Phase I study. The application of the results on coal cleaning is in progress in the Phase II study. Illinois No. 6, Ohio Lower Kittanning, and West Virginia Pocahontas coals have been prepared(simulating the industrial operations) and characterized. The adsorption conditions for {minus}48 mesh ROM coals and flotation… more
Date: January 1, 1989
Creator: Hwang, J. Y.
Partner: UNT Libraries Government Documents Department
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Combined Treatment of SO/sub 2/ and High Resistivity Fly Ash Using a Pulse Energized Electron Reactor

Description: The combined removal of SO/sub 2/ and high resistivity fly ash has been demonstrated in a pulse energized electron reactor (PEER). The PEER system which was originally developed for the removal of SO/sub 2/ utilizes a positive pulse streamer corona discharge in a non-uniform field geometry. In performance tests on SO/sub 2/, more than 90% was removed with an advantageously small power requirement. Combined treatment performance was demonstrated by introducing high resistivity fly ash into the t… more
Date: January 1, 1984
Creator: Mizuno, A.; Clements, J.S. & Davis, R.H.
Partner: UNT Libraries Government Documents Department
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Aerosol Particle Charger and an SO/sub 2/ Reactor Using Energetic Electrons

Description: Two properties of energetic electrons in gas, their high specific ionization and their production of radicals and other chemically active specie, have promising applications to the cleanup of flue gas from coal combustion. The copious ionization has been used in a test particle charger to electrically charge 1 and 3 ..mu..m particles for subsequent removal by electrostatic precipitation. Particle charge greater than 5 times the theoretical ionic charging value for 1 ..mu..m particles have been … more
Date: January 1, 1984
Creator: Davis, R.H.
Partner: UNT Libraries Government Documents Department
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