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A Novel Coal Feeder for Production of Low Sulfur Fuel

Description: During the past three months, the coal feeding system has been tested and currently undergoing evaluation at the University of Cincinnati. The system consists primarily of an auger feed tube which is used to both convey and provide desulfurization of a high sulfur coal feedstock. The coal is conveyed at temperatures ranging from 350 to 550{degrees}C and under normal atmospheric pressure. Under these mild processing conditions, the coal partially pyrolizes and emits sulfur in the form of hydroge… more
Date: January 1, 1990
Creator: Khang, S. J. & Keener, T. C.
Partner: UNT Libraries Government Documents Department
open access

Phosphate-bonded glass cements for geothermal wells. Final report

Description: Calcium aluminosilicate glasses were found to react with phosphoric acid in three ways depending upon silica content. Above 55% SiO/sub 2/ they are insoluble while below 50% they dissolve readily. The transition compositions release calcium and aluminum ions and a silica gel phase replaces the glass. Activation energies in the order of 10 kcal/mole are associated with the dissolution. Equilibrium studies in the systems CaO-P/sub 2/O/sub 5/-H/sub 2/O, Al/sub 2/O/sub 3/-P/sub 2/O/sub 5/-H/sub 2/O… more
Date: September 1, 1979
Creator: Rockett, T.J.
Partner: UNT Libraries Government Documents Department
open access

Energy dependence of metallic-encapsulated thermoluminescent dosimeters. Annual report

Description: The gamma-ray energy responses of encapsulated /sup 7/LiF and CaF/sub 2/:Mn thermoluminescent dosimeters were measured and compred to calculated values. This study was performed in order to improve the accuracy of gamma-ray heating measurements made in polyenergetic gamma-ray fields such as Argonne National Laboratory's Zero Power Reactors. Equations used in the development of the TERC/III computer code and code input parameters are specified. A section on TLD precision is also included. Compar… more
Date: June 1980
Creator: Simons, G. G.
Partner: UNT Libraries Government Documents Department
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Enhancing the use of coals by gas reburning-sorbent injection

Description: The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices; tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed tech… more
Date: December 22, 1988
Partner: UNT Libraries Government Documents Department
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Long-term leaching of irradiated spent fuel

Description: Spent Light Water Reactor (LWR) fuel with burnups of 9, 28 and 54 MWd/kg U were leach tested at 25/sup 0/C in deionized water in a Paige apparatus. No discernible differences in leach rates were observed due to burnup. Additionally, the 28 MWd/kg U fuel was IAEA leach tested in five different leachants using the IAEA method. Deionized water gave the highest leach rates and a calcium chloride solution gave the lowest leach rates. An accelerated leaching period was observed during the Paige leach… more
Date: January 1, 1979
Creator: Katayama, Y. B. & Bradley, D. J.
Partner: UNT Libraries Government Documents Department
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Oxidation/gasification of carbon residue on retorted oil shale. Final report

Description: Studies of the oxidation and gasification of oil shale char were extended to an investigation of the effects of mineral catalysis. Six shales with differing mineral compositions were studied, including samples from the saline zone in the Western Colorado and from the Antrim shales of Michigan. Oxidation kinetics data, corrected for mass transfer effects, were compared for all six samples. A high assay shale from Utah and a sample from the saline zone were found to have the highest oxidation rat… more
Date: January 16, 1984
Creator: Thomson, W. J.
Partner: UNT Libraries Government Documents Department
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Proof of concept testing of an integrated dry injection system for SO sub x /NO sub x control

Description: The objectives of the subscale test program were designed to provide sorbent and additive selection guidance, and, in so doing, supply answers to the questions posed in the preceding section. The objectives are: Identify the best commercial hydrate sorbent and the best enhanced hydrate sorbent from a list of nine types, based upon S0{sub 2} removal at Ca/S=2. Determine the relative effectiveness of sodium sesquicarbonate versus sodium bicarbonate for S0{sub 2} and NO{sub x} control over the tem… more
Date: January 1, 1989
Creator: Helfritch, D.J.; Bortz, S.J. (Research-Cottrell, Inc., Somerville, NJ (United States). Environmental Services and Technologies Div.) & Beittel, R. (Riley Stoker Corp., Worcester, MA (United States))
Partner: UNT Libraries Government Documents Department
open access

RIMS diagnostics for laser desorption/laser ablation

Description: Laser desorption mass spectrometry is a useful method for interrogating materials and events at or near surfaces. Laser desorption/ablation combined with Resonance Ionization Mass Spectrometry (RIMS) provides a powerful tool to obtain information on chemical composition and speciation and, in some cases, internal and translational energy distributions. The application of this technique to the interrogation of materials and interfaces is discussed for several systems, including the analysis of c… more
Date: January 1, 1986
Creator: Apel, E. C.; Nogar, N. S.; Miller, C. M. & Estler, R. C.
Partner: UNT Libraries Government Documents Department
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Alternate materials of construction for geothermal applications. Progress report No. 14, July--September 1977

Description: A program to determine if non-metallic materials such as polymers, concrete polymer composites, and refractory cements can be utilized as materials of construction in geothermal processes is in progress. To date, several high temperature polymer concrete systems have been formulated, laboratory and field tests performed in brine, flashing brine, and steam at temperatures up to 260/sup 0/C (500/sup 0/F), and economic studies started. Laboratory data for exposure times > 2 years are available. Re… more
Date: September 1, 1977
Creator: Kukacka, L. E.; Fontana, J.; Zeldin, A.; Sugama, T.; Horn, W.; Carciello, N. et al.
Partner: UNT Libraries Government Documents Department
open access

The GALLEX Project

Description: The GALLEX collaboration aims at the detection of solar neutrinos in a radiochemical experiment employing 30 tons of Gallium in form of concentrated aqueous Gallium-chloride solution. The detector is primarily sensitive to the otherwise inaccessible pp-neutrinos. Details of the experiment have been repeatedly described before. Here we report the present status of implementation in the Laboratori Nazionali del Gran Sasso (Italy). So far, 12.2 tons of Gallium are at hand. The present status of de… more
Date: January 1, 1989
Creator: Kirsten, T. (Max-Planck-Institut fuer Kernphysik, Heidelberg (Germany, F.R.))
Partner: UNT Libraries Government Documents Department
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Experiments with a lime slurry in a stirred tank for the fixation of carbon-14-contaminated CO/sub 2/ from simulated HTGR fuel reprocessing off-gas

Description: The fixation of CO/sub 2/ with a lime slurry in a stirred tank reactor appears to be feasible. The rate of reaction is fast, and virtually complete removal of CO/sub 2/ can be attained. At a gas residence time of <1 min, the decontamination factor (DF) is >100 in a single stage reactor for CO/sub 2/ concentrations ranging from 5 to 100%. It has been determined that two-stage contacting sequences which result in a cumulative DF > 10/sup 4/ are feasible. The reaction rate is constant up … more
Date: March 1, 1978
Creator: Holladay, D. W.
Partner: UNT Libraries Government Documents Department
open access

Development of improved cathodes for solid oxide fuel cells

Description: The University of Missouri-Rolla conducted a 17 month research program focused on the development and evaluation of improved cathode materials for solid oxide fuel cells (SOFC). The objectives of this program were: (1) the development of cathode materials of improved stability in reducing environments; and (2) the development of cathode materials with improved electrical conductivity. The program was successful in identifying some potential candidate materials: Air sinterable (La,Ca)(Cr,Co)O{su… more
Date: March 1, 1991
Creator: Anderson, H.U.
Partner: UNT Libraries Government Documents Department
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Excited state absorption measurements of Sm sup 2+ in CaF sub 2 , SrF sub 2 , and SrCl sub 2

Description: We measured the pump-probe spectrum of the Sm{sup 2+} ion in three materials: CaF{sub 2}, SrF{sub 2}, and SrCl{sub 2}. The onset of the observed prominent excited-state absorption band is consistent with an electrostatic model for impurity levels in a solid-state material. 15 refs., 4 figs., 1 tab.
Date: April 1, 1991
Creator: Lawson, J. K.; Lee, H. W. H.; Payne, S. A. (Lawrence Livermore National Lab., CA (United States)) & Boatner, L. A. (Oak Ridge National Lab., TN (United States))
Partner: UNT Libraries Government Documents Department
open access

The use of BaF sub 2 buffer layers for the sputter-deposition of TlCaBaCuO thin-film superconductors

Description: Thin films of the Tl-based superconductors often have relatively poor properties because of film/substrate interdiffusion which occurs during the anneal. We have therefore investigated the use of BaF{sub 2} as a diffusion barrier. TlCaBaCuO thin films were deposited by dc magnetron sputtering onto MgO <100> substrates, both with and without an evaporation-deposited BaF{sub 2} buffer layer, and post-annealed in a Tl over-pressure. Electrical properties of the films were determined by four-point … more
Date: January 1, 1989
Creator: Hubbard, K. M.; Arendt, P. N.; Brown, D. R.; Cooke, D. W.; Elliott, N. E.; Farr, J. D. et al.
Partner: UNT Libraries Government Documents Department
open access

Physicochemical basis of the Na-K-Ca geothermometer

Description: Regular changes in solution composition were observed experimentally during granite reaction with dilute NaCl (+CaCl/sub 2/) solutions; these changes closely follow the empirical Na-K-Ca geothermometer relationship. Initial minerals forming the granite (quartz, plagioclase, K-feldspar, and biotite) were etched by the reactions. Alteration phases formed include calcium-zeolite at <300/sup 0/C, feldspar overgrowths at >300/sup 0/C, and minor amounts of clay and calcsilicate at all temperatures. A… more
Date: August 1, 1986
Creator: Janecky, D. R.; Charles, R. W.; Bayhurst, Gregory K. & Benjamin, T. M.
Partner: UNT Libraries Government Documents Department
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Spectral weight changes at the superconducting transition of Bi sub 2 Sr sub 2 CaCu sub 2 O sub 8+. delta

Description: An overview of our gap studies in high-{Tc} superconductors is presented for the workshop on Fermiology of high-{Tc}'s. The work is centered on the study of single crystal Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8+{delta}}. In a conventional BCS superconductor, a superconducting gap {Delta} is formed when the near Fermi edge electrons condense to form Cooper pairs at low temperatures. As the material goes superconducting the density of states is modified such that the spectral intensity in the regio… more
Date: January 1, 1991
Creator: Dessau, D. S.; Shen, Z. X.; Wells, B. O.; Spicer, W. E. (Stanford Univ., CA (United States). Stanford Electronics Labs.) & Arko, A. J. (Los Alamos National Lab., NM (United States))
Partner: UNT Libraries Government Documents Department
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A novel approach to highly dispersing catalytic materials in coal for gasification

Description: This project seeks to develop a technique, based on coal surface properties, for highly dispersing catalysts in coal for gasification and to investigate the potential of using potassium carbonate and calcium acetate mixtures as catalysts for coal gasification. The lower cost and higher catalytic activity of the latter compound will produce economic benefits by reducing the amount of K{sub 2}CO{sub 3} required for high coal char reactivities.
Date: January 1, 1992
Creator: Abotsi, G.M.K. & Bota, K.B.
Partner: UNT Libraries Government Documents Department
open access

Literature review of the saturation state of seawater with respect to calcium carbonate and its possible significance for scale formation on OTEC heat exchangers

Description: An investigation of available data on the saturation state of seawater with respect to calcium carbonate and its possible significance for scale formation on Ocean Thermal Energy Conversion (OTEC) heat exchangers has been carried out. Pertinent oceanographic data is lacking at or near potential OTEC sites for the calculation of the degree of saturation of seawater with respect to calcium carbonate. Consequently, only ''extrapolated'' saturation values can be used. These indicate that near surfa… more
Date: April 5, 1978
Creator: Morse, J. W.; de Kanel, J. & Craig, Jr., H. L.
Partner: UNT Libraries Government Documents Department
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Design analysis and optimization of self-cooled lithium blankets and shields

Description: A study of self-cooled lithium blankets was carried out to define the performance of these blankets and to determine the potential to operate at the maximum possible values of the performance parameters. The main design parameters considered during the course of the study were the tritium breeding ratio, the blanket energy multiplication factor, the energy fraction lost to the shield, the total blanket thickness, the reflector material selection, and the compositions of the different blanket zo… more
Date: February 1, 1988
Creator: Gohar, Y.
Partner: UNT Libraries Government Documents Department
open access

Development of glass formulations containing high-level nuclear wastes

Description: The effects of Na/sub 2/O, K/sub 2/O, B/sub 2/O/sub 3/, TiO/sub 2/, CaO, and ZnO contents were determined on the leach rate and homogeneity of a potential high-level waste glass. It was found that the two characteristics are in competition, with variations of CaO having the greatest effect and TiO/sub 2/ having the least effect. Boron oxide content is important in control of Na/sub 2/MoO/sub 4/ formation and separation. Sodium molybdate formation can also be controlled by the use of reducing ag… more
Date: February 1, 1978
Creator: Ross, W.A.
Partner: UNT Libraries Government Documents Department
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Simulation experiments and solar wind sputtering

Description: In order to isolate the role played by solar wind sputtering from other lunar surface phenomena a number of simulation experiments were performed, including isotope abundance measurements of Ca sputtered from terrestrial fluorite and plagioclase by 50-keV and 130-keV /sup 14/N beams, measurement of the energy distribution of U atoms sputtered with 80-keV /sup 40/Ar, and measurement of the fraction of sputtered U atoms which stick on the surfaces used to collect these atoms. 10 references. (JFP)
Date: January 1, 1978
Creator: Griffith, J. E.; Papanastassiou, D. A.; Russell, W. A.; Tombrello, T. A. & Weller, R. A.
Partner: UNT Libraries Government Documents Department
open access

A Novel Coal Feeder for Production of Low Sulfur Fuel

Description: A novel coal feeding system is currently undergoing testing and evaluation at the University of Cincinnati. The system consists primarily of an auger feed tube which is used to both convey and provide desulfurization of a high sulfur coal feedstock. The coal is conveyed at temperatures ranging from 350 to 550 {degrees}C and under normal atmospheric pressure. Under these mild processing conditions, the coal partially pyrolizes and emits sulfur in the form of hydrogen sulfide while maintaining a … more
Date: January 1, 1990
Creator: Keener, T. C.; Khang, S. J. & Yu, X. L.
Partner: UNT Libraries Government Documents Department
open access

Proof of concept testing of an integrated dry injection system for SO sub x /NO sub x control

Description: The objective of the subscale test program were designed to provide sorbent and additive selection guidance, and, in so doing, supply answers to the questions posed in the preceding section. The objectives are: Identify the best commercial hydrate sorbent and the best enhanced hydrate sorbent from a list of nine types, based upon S0{sub 2} removal at Ca/S=2. Determine the relative effectiveness of sodium sesquicarbonate versus sodium bicarbonate for S0{sub 2} and NO{sub x} control over the temp… more
Date: January 1, 1990
Creator: Helfritch, D.J.; Bortz, S.J. (Research-Cottrell, Inc., Somerville, NJ (United States). Environmental Services and Technologies Div.) & Beittel, R. (Riley Stoker Corp., Worcester, MA (United States))
Partner: UNT Libraries Government Documents Department
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