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in subjects: "Aromatic compounds."  
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Photophysical properties of pyrene, 2,7 diazapyrene and 1,3-bis(β-naphthyl)propane.

Description: The luminescence properties of Van Der Waals' dimers and clusters of pyrene and diazapyrene have been investigated. Excimers, dimeric species which are associative in an excited electronic state and dissociative in their ground state, have long been established and play an important role in many areas of photochemistry. My work here focuses on the luminescence and absorption properties of ground state dimers/aggregates, which are less understood, and allows further characterization of the groun… more
Date: August 2007
Creator: Boateng, Stephen
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
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Synthesis, characterization and properties of rigid macromolecules with extended conjugation, using palladium-catalyzed alkynylated polyhaloarenes.

Description: A synthetic approach to macromolecules of acetylenic arrays and luminescent properties is proposed and the execution of initial steps is described. Palladium-catalyzed coupling of 1,3,5-triiodobenzene with trimethylsilylbuta-1,3-diyne, trimethylsilylocta-1,3,5,7-tetrayne, and trimethylsilylhexadeca-1,3,5,7,9,11,13,15-octayne to yield the new 1,3,5-tris(trimethylsilylbuta-1,3-diynyl)benzene and the proposed 1,3,5-tris(8-(trimethylsilyl)octa-1,3,5,7-tetraynyl)benzene and 1,3,5-tris(trimethylsilyl… more
Date: December 2007
Creator: Akintomide, Temiloluwa
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
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Sensitization of Lanthanides and Organic-Based Phosphorescence via Energy Transfer and Heavy-Atom Effects

Description: The major topics discussed are the phosphorescence sensitization in the lanthanides via energy transfer and in the organics by heavy atom effects. The f-f transitions in lanthanides are parity forbidden and have weak molar extinction coefficients. Upon complexation with the ligand, ttrpy (4'-p-Tolyl-[2,2':6',2"]-terpyridine) the absorption takes place through the ligand and the excitation is transferred to the lanthanides, which in turn emit. This process is known as "sensitized luminescence." … more
Date: May 2010
Creator: Arvapally, Ravi K.
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
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Electronic Spectra of Catacondensed and Pericondensed Aromatic Hydrocarbons

Description: From abstract: "The electronic spectra arising from the excitations of pi-electrons in homo-nuclear conjugated bond systems are calculated for 37 aromatic hydrocarbons. The theoretical approach used takes into account overlap effects between different a atoms, correlation between different electrons, variations in internuclear distances, and the influence of non-conjugated neighbors, hydrogen and carbon. Four types of approximations are carried trough for the molecules in order to obtain an est… more
Date: June 21, 1962
Creator: Hummel, Richard L. & Ruedenberg, Klaus, 1920-
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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