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TANKS 18 AND 19-F STRUCTURAL FLOWABLE GROUT FILL MATERIAL EVALUATION AND RECOMMENDATIONS

Description: Cementitious grout will be used to close Tanks 18-F and 19-F. The functions of the grout are to: (1) physically stabilize the final landfill by filling the empty volume in the tanks with a non compressible material; (2) provide a barrier for inadvertent intrusion into the tank; (3) reduce contaminant mobility by (a) limiting the hydraulic conductivity of the closed tank and (b) reducing contact between the residual waste and infiltrating water; and (4) providing an alkaline, chemically reducing… more
Date: November 1, 2011
Creator: Stefanko, D. & Langton, C.
Partner: UNT Libraries Government Documents Department
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CEMENTITIOUS GROUT FOR CLOSING SRS HIGH LEVEL WASTE TANKS - #12315

Description: In 1997, the first two United States Department of Energy (US DOE) high level waste tanks (Tanks 17-F and 20-F: Type IV, single shell tanks) were taken out of service (permanently closed) at the Savannah River Site (SRS). In 2012, the DOE plans to remove from service two additional Savannah River Site (SRS) Type IV high-level waste tanks, Tanks 18-F and 19-F. These tanks were constructed in the late 1950's and received low-heat waste and do not contain cooling coils. Operational closure of Tank… more
Date: January 10, 2012
Creator: Langton, C.; Burns, H. & Stefanko, D.
Partner: UNT Libraries Government Documents Department
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TANK 18-F AND 19-F TANK FILL GROUT SCALE UP TEST SUMMARY

Description: High-level waste (HLW) tanks 18-F and 19-F have been isolated from FTF facilities. To complete operational closure the tanks will be filled with grout for the purpose of: (1) physically stabilizing the tanks, (2) limiting/eliminating vertical pathways to residual waste, (3) entombing waste removal equipment, (4) discouraging future intrusion, and (5) providing an alkaline, chemical reducing environment within the closure boundary to control speciation and solubility of select radionuclides. Thi… more
Date: January 3, 2012
Creator: Stefanko, D. & Langton, C.
Partner: UNT Libraries Government Documents Department
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MAGNESIUM MONO POTASSIUM PHOSPHATE GROUT FOR P-REACTOR VESSEL IN-SITU DECOMISSIONING

Description: The objective of this report is to document laboratory testing of magnesium mono potassium phosphate grouts for P-Reactor vessel in-situ decommissioning. Magnesium mono potassium phosphate cement-based grout was identified as candidate material for filling (physically stabilizing) the 105-P Reactor vessel (RV) because it is less alkaline than portland cement-based grout (pH of about 12.4). A less alkaline material ({<=} 10.5) was desired to address a potential materials compatibility issue c… more
Date: January 5, 2011
Creator: Langton, C. & Stefanko, D.
Partner: UNT Libraries Government Documents Department
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USE OF CEMENTITIOUS MATERIALS FOR SRS REACTOR FACILITY IN-SITU DECOMMISSIONING - 11620

Description: The United States Department of Energy (US DOE) concept for facility in-situ decommissioning (ISD) is to physically stabilize and isolate in tact, structurally sound facilities that are no longer needed for their original purpose of, i.e., producing (reactor facilities), processing (isotope separation facilities) or storing radioactive materials. The Savannah River Site 105-P and 105-R Reactor Facility ISD requires about 250,000 cubic yards of grout to fill the below grade structure. The fills … more
Date: December 7, 2010
Creator: Langton, C.; Stefanko, D.; Serrato, M.; Blankenship, J.; Griffin, W.; Waymer, J. et al.
Partner: UNT Libraries Government Documents Department
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SAVANNAH RIVER SITE R REACTOR DISASSEMBLY BASIN IN SITU DECOMMISSIONING

Description: The US DOE concept for facility in-situ decommissioning (ISD) is to physically stabilize and isolate in tact, structurally sound facilities that are no longer needed for their original purpose of, i.e., generating (reactor facilities), processing(isotope separation facilities) or storing radioactive materials. The 105-R Disassembly Basin is the first SRS reactor facility to undergo the in-situ decommissioning (ISD) process. This ISD process complies with the105-R Disassembly Basin project strat… more
Date: December 3, 2009
Creator: Langton, C.; Blankenship, J.; Griffin, W. & Serrato, M.
Partner: UNT Libraries Government Documents Department
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REVIEW OF MECHANISTIC UNDERSTANDING AND MODELING AND UNCERTAINTY ANALYSIS METHODS FOR PREDICTING CEMENTITIOUS BARRIER PERFORMANCE

Description: Cementitious barriers for nuclear applications are one of the primary controls for preventing or limiting radionuclide release into the environment. At the present time, performance and risk assessments do not fully incorporate the effectiveness of engineered barriers because the processes that influence performance are coupled and complicated. Better understanding the behavior of cementitious barriers is necessary to evaluate and improve the design of materials and structures used for radioact… more
Date: November 30, 2009
Creator: Langton, C. & Kosson, D.
Partner: UNT Libraries Government Documents Department
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TECHNOLOGY REQUIREMENTS FOR IN SITU DECOMMISSIONING WORKSHOP REPORT

Description: In recognition of the increasing attention being focused on In Situ Decommissioning (ISD or entombment) as an acceptable and beneficial decommissioning end state, the Department of Energy's (DOE) Office of Environmental Management (EM) is developing guidance for the implementation of ISD of excess facilities within the DOE complex. Consistent with the overarching DOE goals for increased personnel and environmental safety, reduced technical uncertainties and risks, and overall gains in efficienc… more
Date: June 30, 2009
Creator: Jannik, T.; Lee, P.; Gladden, J.; Langton, C.; Serrato, M.; Urland, C. et al.
Partner: UNT Libraries Government Documents Department
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OVERVIEW OF THE U.S. DEPARTMENT OF ENERGY AND NUCLEAR REGULATORY COMMISSION PERFORMANCE ASSESSMENT APPROACHES: CEMENTITIOUS BARRIERS PARTNERSHIP

Description: Engineered barriers including cementitious barriers are used at sites disposing or contaminated with low-level radioactive waste to enhance performance of the natural environment with respect to controlling the potential spread of contaminants. Drivers for using cementitious barriers include: high radionuclide inventory, radionuclide characteristics (e.g., long half-live, high mobility due to chemical form/speciation, waste matrix properties, shallow water table, and humid climate that provides… more
Date: May 29, 2009
Creator: Langton, C. & Burns, H.
Partner: UNT Libraries Government Documents Department
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SALTSTONE MATRIX CHARACTERIZATION AND STADIUM SIMULATION RESULTS

Description: SIMCO Technologies, Inc. was contracted to evaluate the durability of the saltstone matrix material and to measure saltstone transport properties. This information will be used to: (1) Parameterize the STADIUM{reg_sign} service life code, (2) Predict the leach rate (degradation rate) for the saltstone matrix over 10,000 years using the STADIUM{reg_sign} concrete service life code, and (3) Validate the modeled results by conducting leaching (water immersion) tests. Saltstone durability for this … more
Date: July 30, 2009
Creator: Langton, C.
Partner: UNT Libraries Government Documents Department
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TANK 18 AND 19-F TIER 1A EQUIPMENT FILL MOCK UP TEST SUMMARY

Description: The United States Department of Energy (US DOE) has determined that Tanks 18-F and 19-F have met the F-Tank Farm (FTF) General Closure Plan Requirements and are ready to be permanently closed. The high-level waste (HLW) tanks have been isolated from FTF facilities. To complete operational closure they will be filled with grout for the purpose of: (1) physically stabilizing the tanks, (2) limiting/eliminating vertical pathways to residual waste, (3) discouraging future intrusion, and (4) providi… more
Date: November 4, 2011
Creator: Stefanko, D. & Langton, C.
Partner: UNT Libraries Government Documents Department
open access

BLENDED CALCIUM ALUMINATE-CALCIUM SULFATE CEMENT-BASED GROUT FOR P-REACTOR VESSEL IN-SITU DECOMMISSIONING

Description: The objective of this report is to document laboratory testing of blended calcium aluminate - calcium hemihydrate grouts for P-Reactor vessel in-situ decommissioning. Blended calcium aluminate - calcium hemihydrate cement-based grout was identified as candidate material for filling (physically stabilizing) the 105-P Reactor vessel (RV) because it is less alkaline than portland cement-based grout which has a pH greater than 12.4. In addition, blended calcium aluminate - calcium hemihydrate cemen… more
Date: March 10, 2011
Creator: Langton, C. & Stefanko, D.
Partner: UNT Libraries Government Documents Department
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NEW MATERIALS DEVELOPED TO MEET REGULATORY AND TECHNICAL REQUIREMENTS ASSOCIATED WITH IN-SITU DECOMMISSIONING OF NUCLEAR REACTORS AND ASSOCIATED FACILITIES

Description: For the 2010 ANS Embedded Topical Meeting on Decommissioning, Decontamination and Reutilization and Technology, Savannah River National Laboratory's Mike Serrato reported initial information on the newly developed specialty grout materials necessary to satisfy all requirements associated with in-situ decommissioning of P-Reactor and R-Reactor at the U.S. Department of Energy's Savannah River Site. Since that report, both projects have been successfully completed and extensive test data on both … more
Date: January 18, 2012
Creator: Blankenship, J.; Langton, C.; Musall, J. & Griffin, W.
Partner: UNT Libraries Government Documents Department
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Computation at the edge of chaos: Phase transition and emergent computation

Description: In order for computation to emerge spontaneously and become an important factor in the dynamics of a system, the material substrate must support the primitive functions required for computation: the transmission, storage, and modification of information. Under what conditions might we expect physical systems to support such computational primitives This paper presents research on Cellular Automata which suggests that the optimal conditions for the support of information transmission, storage, a… more
Date: January 25, 1990
Creator: Langton, C.
Partner: UNT Libraries Government Documents Department
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REFERENCE CASES FOR USE IN THE CEMENTITOUS PARTNERSHIP PROJECT

Description: The Cementitious Barriers Partnership Project (CBP) is a multi-disciplinary, multi-institution cross cutting collaborative effort supported by the US Department of Energy (DOE) to develop a reasonable and credible set of tools to improve understanding and prediction of the structural, hydraulic and chemical performance of cementitious barriers used in nuclear applications. The period of performance is >100 years for operating facilities and > 1000 years for waste management. The CBP has d… more
Date: August 31, 2010
Creator: Langton, C.; Kosson, D. & Garrabrants, A.
Partner: UNT Libraries Government Documents Department
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Assessment of the Potential for Hydrogen Generation During Deactivation and Decommissioning of Reactor Vessels at the Savannah River Site

Description: The R- and P-reactor vessels at the Savannah River Site (SRS) are being prepared for deactivation and decommissioning (D&D). D&D activities will consist primarily of physically isolating and stabilizing the reactor vessel by filling it with a grout material. The reactor vessels contain aluminum alloy materials, which pose a concern in that aluminum corrodes rapidly when it comes in contact with the alkaline grout. A product of the corrosion reaction is hydrogen gas and therefore potenti… more
Date: November 10, 2010
Creator: Wiersma, B.; Serrato, M. & Langton, C.
Partner: UNT Libraries Government Documents Department
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CEMENTITIOUS BARRIERS PARTNERSHIP ACCOMPLISHMENTS AND RELEVANCE TO THE DOE COMPLEX

Description: The Cementitious Barriers Partnership (CBP) was initiated to reduce risk and uncertainties in the performance assessments that directly impact U.S. Department of Energy (DOE) environmental cleanup and closure programs. The CBP is supported by the DOE Office of Environmental Management (DOE-EM) and has been specifically addressing the following critical EM program needs: (i) the long-term performance of cementitious barriers and materials in nuclear waste disposal facilities and (ii) increased u… more
Date: November 15, 2010
Creator: Burns, H.; Langton, C.; Flach, G. & Kosson, D.
Partner: UNT Libraries Government Documents Department
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CONSIDERATIONS FOR GROUT FORMULATIONS FOR FACILITY CLOSURES USING IN SITU STRATEGIES

Description: The U.S. Department of Energy (DOE) is conducting in situ closures (entombment) at a large number of facilities throughout the complex. Among the largest closure actions currently underway are the closures of the P and R Reactors at the Savannah River Site (SRS), near Aiken, South Carolina. In these facilities, subgrade open spaces are being stabilized with grout; this ensures the long term structural integrity of the facilities and permanently immobilizes and isolates residual contamination. T… more
Date: August 25, 2010
Creator: Gladden, J.; Serrato, M.; Langton, C.; Long, T.; Blankenship, J.; Hannah, G. et al.
Partner: UNT Libraries Government Documents Department
open access

DEMONSTRATION OF LEACHXS/ORCHESTRA CAPABILITIES BY SIMULATING CONSTITUENT RELEASE FROM A CEMENTITIOUS WASTE FORM IN A REINFORCED CONCRETE VAULT

Description: The objective of the work described in this report is to demonstrate the capabilities of the current version of LeachXS{trademark}/ORCHESTRA for simulating chemical behavior and constituent release processes in a range of applications that are relevant to the CBP. This report illustrates the use of LeachXS{trademark}/ORCHESTRA for the following applications: (1) Comparing model and experimental results for leaching tests for a range of cementitious materials including cement mortars, grout, sta… more
Date: March 31, 2010
Creator: Langton, C.; Meeussen, J. & Sloot, H.
Partner: UNT Libraries Government Documents Department
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Cementitious Barriers Partnership fy13 Mid-Year Report

Description: In FY2013, the Cementitious Barriers Partnership (CBP) is continuing in its effort to develop and enhance software tools demonstrating tangible progress toward fulfilling the objective of developing a set of tools to improve understanding and prediction of the long‐term structural, hydraulic and chemical performance of cementitious barriers used in nuclear applications. In FY2012, the CBP released the initial inhouse “Beta‐version” of the CBP Software Toolbox, a suite of software for simulating… more
Date: May 1, 2013
Creator: Burns, H.; Flach, G.; Langton, C.; Kosson, D.; Brown, K.; Samson, E. et al.
Partner: UNT Libraries Government Documents Department
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TRANSPORT THROUGH CRACKED CONCRETE: LITERATURE REVIEW

Description: Concrete containment structures and cement-based fills and waste forms are used at the Savannah River Site to enhance the performance of shallow land disposal systems designed for containment of low-level radioactive waste. Understanding and measuring transport through cracked concrete is important for describing the initial condition of radioactive waste containment structures at the Savannah River Site (SRS) and for predicting performance of these structures over time. This report transmits t… more
Date: May 11, 2012
Creator: Langton, C.
Partner: UNT Libraries Government Documents Department
open access

TANKS 18 AND 19-F EQUIPMENT GROUT FILL MATERIAL EVALUATION AND RECOMMENDATIONS

Description: The United States Department of Energy (US DOE) intends to remove Tanks 18-F and 19-F at the Savannah River Site (SRS) from service. The high-level waste (HLW) tanks have been isolated from the F-area Tank Farm (FTF) facilities and will be filled with cementitious grout for the purpose of: (1) physically stabilizing the empty volumes in the tanks, (2) limiting/eliminating vertical pathways from the surface to residual waste on the bottom of the tanks, (3) providing an intruder barrier, and (4) … more
Date: December 15, 2011
Creator: Stefanko, D. & Langton, C.
Partner: UNT Libraries Government Documents Department
open access

EVALUATION OF THE IMPACT OF THIN POURS ON SALTSTONE PROPERTIES

Description: The proposed Saltstone Disposal Unit 6 (SDU6) is a larger structure than the SDU4 cells and larger than the disposal units (SDU2, SDU3, and SDU5) currently in use or under construction. The additional capacity provided by SDU6 is desired to reduce life cycle costs and support site accelerated closure goals. The larger size of the planned SDU6 could result in saltstone being placed in thinner lifts as the unit is filled. This study was performed to determine whether thinner layers of saltstone n… more
Date: October 2, 2012
Creator: Cozzi, A.; Langton, C. & Fox, K.
Partner: UNT Libraries Government Documents Department
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TANK 50 BATCH 0 SALTSTONE FORMULATION CONFIRMATION

Description: Savannah River National Laboratory (SRNL) personnel were requested to confirm the Tank 50 Batch 0 grout formulation per Technical Task Request, SSF-TTR-2006-0001 (task 1 of 2) [1]. Earlier Batch 0 formulation testing used a Tank 50 sample collected in September 2005 and is described elsewhere [2]. The current testing was performed using a sample of Tank 50 waste collected in May 2006. This work was performed according to the Technical Task and Quality Assurance Plan (TT/QAP), WSRC-RP-2006-00594… more
Date: June 5, 2006
Creator: Langton, C.
Partner: UNT Libraries Government Documents Department
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