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Analysis of Paraho oil shale products and effluents: an example of the multi-technique approach

Description: Inorganic analysis of solid, liquid and gaseous samples from the Paraho Semiworks Retort was completed using a multitechnique approach. The data were statistically analyzed to determine both the precision of each method and to see how closely the various techniques compared. The data were also used to determine the redistribution of 31 trace and major elements in the various effluents, including the offgas for the Paraho Retort operating in the direct mode. The computed mass balances show that … more
Date: June 10, 1979
Creator: Fruchter, J. S.; Wilkerson, C. L.; Evans, J. C. & Sanders, R. W.
Partner: UNT Libraries Government Documents Department
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Lawrence Livermore National Laboratory DIII-D cooperation: 1987 annual report

Description: This report summarizes the Lawrence Livermore National Laboratory (LLNL) DIII-D cooperation during FY87. The LLNL participation in DIII-D concentrated on three principal areas: ECH and current-drive physics, divertor and edge physics, and tokamak operations. These topics are dicussed in this report. 27 refs., 11 figs.
Date: February 24, 1988
Creator: Allen, S. L.; Calderon, M. O.; Ellis, R. M.; Evans, J. C.; Ferguson, S. W.; Hill, D. N. et al.
Partner: UNT Libraries Government Documents Department
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Characterization of mercury, arsenic, and selenium in the product streams of the Pacific Northwest Laboratory 6-kg retort

Description: The objective of this program is to determine how retorting process parameters affect the partitioning of Hg, As, Se, and Cd from raw oil shale to spent shale, shale oil, retort water, and offgas. For each of the elements, the objective of this study is to (1) determine the distribution coefficients for each product stream; (2) identify the chemical forms in water, gas, and oil streams, with particular emphasis on inorganic or organometallic species known to be or suspected of being carcinogeni… more
Date: December 1, 1985
Creator: Olsen, K. B.; Evans, J. C.; Sklarew, D. S.; Girvin, D. C.; Nelson, C. L.; Lepel, E. A. et al.
Partner: UNT Libraries Government Documents Department
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Long-lived activation products in reactor materials

Description: The purpose of this program was to assess the problems posed to reactor decommissioning by long-lived activation products in reactor construction materials. Samples of stainless steel, vessel steel, concrete, and concrete ingredients were analyzed for up to 52 elements in order to develop a data base of activatable major, minor, and trace elements. Large compositional variations were noted for some elements. Cobalt and niobium concentrations in stainless steel, for example, were found to vary b… more
Date: August 1, 1984
Creator: Evans, J. C.; Lepel, E. L.; Sanders, R. W.; Wilkerson, C. L.; Silker, W.; Thomas, C. W. et al.
Partner: UNT Libraries Government Documents Department
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Hanford Site ground-water monitoring for July through December 1987

Description: The Pacific Northwest Laboratory monitors ground-water quality at the Hanford Site for the US Department of Energy to assess the impact of Site operations on the environment. Work undertaken between July and December 1987 included monitoring ground-water elevations across the Site, monitoring hazardous chemicals and radionuclides in ground water, geochemical evaluations of unconfined ground-water data, and calibration of ground-water flow and transport models. Water levels continued to rise in … more
Date: December 1, 1988
Creator: Evans, J. C.; Dennison, D. I.; Bryce, R. W.; Mitchell, P. J.; Sherwood, D. R.; Krupka, K. M. et al.
Partner: UNT Libraries Government Documents Department
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Field investigation source area ST58 old Quartermaster service station, Eielson Air Force Base, Alaska

Description: Source area ST58 is the site of the old Quartermaster service station at Eielson Air Force Base, Alaska. The source area is one of several Source Evaluation Report sites being investigated by Pacific Northwest Laboratory for the US Air Force as candidates for no further remedial action, interim removal action, or a remedial investigation/feasibility study under a Federal Facilities Agreement. The purpose of this work was to characterize source area ST58 and excavate the most contaminated soils … more
Date: January 1995
Creator: Liikala, T. L. & Evans, J. C.
Partner: UNT Libraries Government Documents Department
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Hanford Site ground-water monitoring for 1990

Description: The Pacific Northwest Laboratory monitors ground-water quality across the Hanford Site for the US Department of Energy (DOE) to assess the impact of Site operations on the environment. Monitoring activities were conducted to determine the distribution of mobile radionuclides and identify chemicals present in ground water as a result of Site operations and whenever possible, relate the distribution of these constituents to Site operations. To comply with the Resource Conservation and Recovery Ac… more
Date: June 1, 1992
Creator: Evans, J. C.; Bryce, R. W. & Bates, D. J.
Partner: UNT Libraries Government Documents Department
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Hanford Site ground-water monitoring for 1990

Description: The Pacific Northwest Laboratory monitors ground-water quality across the Hanford Site for the US Department of Energy (DOE) to assess the impact of Site operations on the environment. Monitoring activities were conducted to determine the distribution of mobile radionuclides and identify chemicals present in ground water as a result of Site operations and whenever possible, relate the distribution of these constituents to Site operations. To comply with the Resource Conservation and Recovery Ac… more
Date: June 1, 1992
Creator: Evans, J. C.; Bryce, R. W. & Bates, D. J.
Partner: UNT Libraries Government Documents Department
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Tank Vapor Characterization Project: Headspace vapor characterization of Hanford Waste Tank U-204, Results from samples collected on August 8, 1995

Description: This report describes the analytical results of vapor samples taken from the headspace of the waste storage tank 241-U-204 (Tank U-204) at the Hanford Site in Washington State. The results described in this report were obtained to characterize the vapors present in the tank headspace and to support safety evaluations and tank-farm operations. The results include air concentrations of selected inorganic and organic analytes and grouped compounds from samples obtained by Westinghouse Hanford Comp… more
Date: November 1, 1995
Creator: Clauss, T. W.; Evans, J. C.; McVeety, B. D.; Pool, K. H.; Thomas, B. L.; Olsen, K. B. et al.
Partner: UNT Libraries Government Documents Department
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Multielement detector for gas chromatography

Description: This report describes the results of a study to improve the capabilities of a gas chromatography-microwave-induced plasma (GC- MIP) detector system, determine the feasibility of empirical formula determination for simple mixtures containing elements of interest to fossil fuel analysis and, subsequently, explore applications for analysis of the complex mixtures associated with fossil fuels. The results of this study indicate that the GC-MIP system is useful as a specific-element detector that pr… more
Date: November 1, 1988
Creator: Sklarew, D. S.; Evans, J. C. & Olsen, K. B.
Partner: UNT Libraries Government Documents Department
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Ground-water sample collection and analysis plan for the ground-water surveillance project

Description: The Pacific Northwest Laboratory performs ground-water sampling activities at the US Department of Energy`s (DOE`s) Hanford Site in support of DOE`s environmental surveillance responsibilities. The purpose of this document is to translate DOE`s General Environmental Protection Program (DOE Order 5400.1) into a comprehensive ground-water sample collection and analysis plan for the Hanford Site. This sample collection and analysis plan sets forth the environmental surveillance objectives applicab… more
Date: December 1, 1991
Creator: Bryce, R. W.; Evans, J. C. & Olsen, K. B.
Partner: UNT Libraries Government Documents Department
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Use of mass spectrometric methods for field screening of VOC`s

Description: While mass spectrometric (MS) methods of chemical analysis, particularly gas chromatography-mass spectrometry (GC/MS), have been the mainstay of environmental organic analytical techniques in the laboratory through the use of EPA and other standard methods, field implementation is relatively rare. Instrumentation and methods now exist for utilizing MS and GC/MS techniques in the field for analysis of VOC`s in gas phase, aqueous, and soil media. Examples of field investigations utilizing HP 5971… more
Date: November 1, 1994
Creator: Evans, J. C.
Partner: UNT Libraries Government Documents Department
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Hanford Site ground-water monitoring for 1991

Description: The Pacific Northwest Laboratory (PNL) monitors the distribution of radionuclides and other hazardous materials in ground water at the Hanford Site for the US Department of Energy (DOE). This work is performed through the Ground-Water Surveillance Project and is designed to meet the requirements of DOE Order 5400.1 that apply to environmental surveillance and ground-water monitoring (DOE 1988). This annual report discusses results of ground-water monitoring at the Hanford Site during 1991. In a… more
Date: October 1, 1992
Creator: Evans, J. C.; Bryce, R. W. & Bates, D. J.
Partner: UNT Libraries Government Documents Department
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Hanford Site ground-water monitoring for 1993

Description: This report presents the results of the Ground-Water Surveillance Project monitoring for calendar year 1993 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiological and chemical waste that have impacted ground-water quality on the Site. Monitoring of water levels and ground-water chemistry is performed to track the extent of contamination and trends in contaminant concentrations. The 1993 monitoring was also designed to identify emergin… more
Date: September 1, 1994
Creator: Dresel, P. E.; Luttrell, S. P. & Evans, J. C.
Partner: UNT Libraries Government Documents Department
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Characterization and monitoring of 300 Area Facility liquid waste streams: Status report

Description: This report summarizes the results of characterizing and monitoring the following sources during a portion of this year: liquid waste streams from Buildings 331, 320, and 3720; treated and untreated Columbia River water; and water at the confluence of the waste streams (that is, end-of-pipe). Characterization and monitoring data were evaluated for samples collected between March 22 and June 21, 1994, and subsequently analyzed for hazardous chemicals, radioactivity, and general parameters. Excep… more
Date: September 1, 1994
Creator: Manke, K. L.; Riley, R. G.; Ballinger, M. Y.; Damberg, E. G.; Evans, J. C.; Ikenberry, A. S. et al.
Partner: UNT Libraries Government Documents Department
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Characteristics of the volatile organic compounds -- Arid Integrated Demonstration Site

Description: The Volatile Organic Compounds -- Arid Integrated Demonstration Program (VOC-Arid ID) is targeted at demonstration and testing of technologies for the evaluation and cleanup of volatile organic compounds and associated contaminants at arid DOE sites. The initial demonstration site is an area of carbon tetrachloride (CCl{sub 4}) contamination located near the center of the Hanford Site. The movement of CCl{sub 4} and other volatile organic contaminants in the subsurface is very complex. The prob… more
Date: October 1, 1991
Creator: Last, G. V.; Lenhard, R. J.; Bjornstad, B. N.; Evans, J. C.; Roberson, K. R.; Spane, F. A. et al.
Partner: UNT Libraries Government Documents Department
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Tank vapor characterization project - Tank 241-U-112 headspace gas and vapor characterization: Results for homogeneity samples collected on December 6, 1996

Description: This report presents the results of analyses of samples taken from the headspace of waste storage tank 241-U-112 (Tank U-112) at the Hanford Site in Washington State. Samples were collected to determine the homogeneity of selected inorganic and organic headspace constitutents. Two risers (Riser 3 and Riser 6) were sampled at three different elevations (Bottom, Middle, and Top) within the tank. Tank headspace samples were collected by SGN Eurisys Service Corporation (SESC) and were analyzed by P… more
Date: September 1, 1997
Creator: Sklarew, D. S.; Pool, K. H.; Evans, J. C. & Hayes, J. C.
Partner: UNT Libraries Government Documents Department
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Tank vapor characterization report headspace vapor characterization of Hanford tank 241-S-105: results from samples collected on 12/07/95

Description: This document presents the details of the inorganic and organic analysis that was performed on samples from the headspace of Hanford waste tank 241-S-105. The results described were obtained to support the safety evaluations and tank operations. A summary of the results for the inorganic and organic analytes is included, as well as, a detailed description of the results.
Date: June 1, 1996
Creator: Pool, K. H.; Thomas, B. L.; Evans, J. C.; McVeety, B. D.; Olsen, K. B.; Fruchter, J. S. et al.
Partner: UNT Libraries Government Documents Department
open access

Headspace vapor characterization of Hanford waste Tank 241-BX-110: Results from samples collected on 04/30/96

Description: This report describes the analytical results of vapor samples taken from the headspace of the waste storage tank 241-BX-110 (Tank BX-110) at the Hanford Site in Washington State. The results described in this report were obtained to characterize the vapors present in the tank headspace and to support safety evaluations and tank farm operations. The results include air concentrations of selected inorganic and organic analytes and grouped compounds from samples obtained by Westinghouse Hanford Co… more
Date: January 1, 1997
Creator: Evans, J. C.; Pool, K. H.; Thomas, B. L.; Olsen, K. B.; Fruchter, J. S. & Silvers, K. L.
Partner: UNT Libraries Government Documents Department
open access

Headspace vapor characterization at Hanford Waste Tank 241-A-102: Results from samples collected on November 10, 1995. Tank Vapor Characterization Project

Description: This report describes the results of vapor samples taken from the headspace of waste storage tank 241-A-102 (Tank A-102) at the Hanford Site in Washington State. Pacific Northwest National Laboratory (PNNL) (a) contracted with Westinghouse Hanford Company (WHC) to provide sampling devices and analyze samples for inorganic and organic analytes collected from the tank headspace and ambient air near the tank. The analytical work was performed by the PNNL Vapor Analytical Laboratory (VAL) by the Ta… more
Date: June 1996
Creator: Evans, J. C.; Pool, K. H.; Thomas, B. L.; Olsen, K. B.; Fruchter, J. S. & Silvers, K. L.
Partner: UNT Libraries Government Documents Department
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Comparison of vapor sampling system (VSS) and in situ vapor sampling (ISVS) methods on Tanks C-107, BY-108, and S-102. Revision 1

Description: This report discusses comparison tests for two methods of collecting vapor samples from the Hanford Site high-level radioactive waste tank headspaces. The two sampling methods compared are the truck-mounted vapor sampling system (VSS) and the cart-mounted in-situ vapor sampling (ISVS). Three tanks were sampled by both the VSS and ISVS methods from the same access risers within the same 8-hour period. These tanks have diverse headspace compositions and they represent the highest known level of s… more
Date: August 1, 1996
Creator: Huckaby, J. L.; Edwards, J. A. & Evans, J. C.
Partner: UNT Libraries Government Documents Department
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Headspace vapor characterization of Hanford waste tank 241-U-109: Results from samples collected on 8/10/95

Description: This report describes the analytical results of vapor samples taken from the headspace of the waste storage tank 241-U-109 (Tank U-109) At the Hanford Site in Washington State. The results described in this report were obtained to characterize the vapors present in the tank headspace and to support safety evaluations and tank farm operations. This tank is on the Hydrogen Waste List. The results include air concentrations of selected inorganic and organic analytes and grouped compounds from samp… more
Date: May 1, 1996
Creator: Evans, J. C.; Thomas, B. L.; Pool, K. H.; Olsen, K. B.; Fruchter, J. S. & Silvers, K. L.
Partner: UNT Libraries Government Documents Department
open access

Headspace vapor characterization of Hanford waste tank 241-S-106: Results from samples collected on 06/13/96

Description: This report describes the analytical results of vapor samples taken from the headspace of the waste storage tank 241-S-106 (Tank S-106) at the Hanford Site in Washington State. The results described in this report were obtained to characterize the vapors present in the tank headspace and to support safety evaluations and tank farm operations. The results include air concentrations of selected inorganic and organic analytes and grouped compounds from samples obtained by Westinghouse Hanford Comp… more
Date: January 1, 1997
Creator: Evans, J. C.; Pool, K. H.; Thomas, B. L.; Olsen, K. B.; Fruchter, J. S. & Silvers, K. L.
Partner: UNT Libraries Government Documents Department
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