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Development and Validation of a One-Dimensional Co-Electrolysis Model for Use in Large-Scale Process Modeling Analysis

Description: A one-dimensional chemical equilibrium model has been developed for analysis of simultaneous high-temperature electrolysis of steam and carbon dioxide (coelectrolysis) for the direct production of syngas, a mixture of hydrogen and carbon monoxide. The model assumes local chemical equilibrium among the four process-gas species via the shift reaction. For adiabatic or specified-heat-transfer conditions, the electrolyzer model allows for the determination of coelectrolysis outlet temperature, comp… more
Date: July 1, 2007
Creator: O'Brien, J. E.; McKellar, M. G.; Hawkes, G. L. & Stoots, C. M.
Partner: UNT Libraries Government Documents Department
open access

PROCESS MODEL FOR THE PRODUCTION OF SYNGAS VIA HIGH TEMPERATURE CO-ELECTROLYSIS

Description: A process model has been developed to evaluate the potential performance of a large-scale high-temperature coelectrolysis plant for the production of syngas from steam and carbon dioxide. The coelectrolysis process allows for direct electrochemical reduction of the steam – carbon dioxide gas mixture, yielding hydrogen and carbon monoxide, or syngas. The process model has been developed using the HYSYS systems analysis code. Using this code, a detailed process flowsheet has been defined that inc… more
Date: November 1, 2007
Creator: McKellar, M. G.; O'Brien, J. E.; Stoots, C. M. & Hawkes, G. L.
Partner: UNT Libraries Government Documents Department
open access

Results Of Recent High Temperature Co-Electrolysis Studies At The Idaho National Laboratory

Description: For the past several years, the Idaho National Laboratory and Ceramatec, Inc. have been studying the feasibility of high temperature solid oxide electrolysis for large-scale, nuclear-powered hydrogen production. Parallel to this effort, the INL and Ceramatec have been researching high temperature solid oxide co-electrolysis of steam/CO2 mixtures to produce syngas, the raw material for synthetic fuels production. When powered by nuclear energy, high temperature co-electrolysis offers a carbon-ne… more
Date: November 1, 2007
Creator: Stoots, C. M.; O'Brien, James E. & Hartvigsen, Joseph J.
Partner: UNT Libraries Government Documents Department
open access

Parametric Study Of Large-Scale Production Of Syngas Via High Temperature Co-Electrolysis

Description: A process model has been developed to evaluate the potential performance of a largescale high-temperature co-electrolysis plant for the production of syngas from steam and carbon dioxide. The co-electrolysis process allows for direct electrochemical reduction of the steam – carbon dioxide gas mixture, yielding hydrogen and carbon monoxide, or syngas. The process model has been developed using the Honeywell UniSim systems analysis code. Using this code, a detailed process flow sheet has been def… more
Date: November 1, 2007
Creator: O'Brien, J. E.; McKellar, M. G.; Stoots, C. M.; Herring, J. S. & Hawkes, G. L.
Partner: UNT Libraries Government Documents Department
open access

Tiger Teams Technical Assistance: Reliable, Universal Open Architecture for Card Access to Dispense Alternative Fuels

Description: Report discusses the dilemma of incorporating consistent, convenient, universal card access (or ''pay-at-the-pump'') systems into alternative fueling stations across the country. The state of California continues to be in the forefront of implementing alternative fuels for transportation applications. Aggressive efforts to deploy alternative fuel vehicles (AFVs) in California have highlighted the need to provide adequate fueling stations and develop appropriate, user-friendly means to purchase … more
Date: March 1, 2002
Partner: UNT Libraries Government Documents Department
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Clean Cities Fact Sheet

Description: This fact sheet explains the Clean Cities Program and provides contact information for all coalitions and regional offices. It answers key questions such as: What is the Clean Cities Program? What are alternative fuels? How does the Clean Cities Program work? What sort of assistance does Clean Cities offer? What has Clean Cities accomplished? What is Clean Cities International? and Where can I find more information?
Date: January 1, 2004
Partner: UNT Libraries Government Documents Department
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From Minnesota to New Mexico, E85 Expands beyond the Corn Belt; State Energy Program (SEP) Case Studies

Description: DOE's State Energy Program published this case study in conjunction with the New Mexico Division of Energy Conservation and Management. It describes an emerging corridor of service stations selling a specific alternative fuel-E85 ethanol-along highways in New Mexico.
Date: April 1, 2004
Partner: UNT Libraries Government Documents Department
open access

Capture of Heat Energy from Diesel Engine Exhaust

Description: Diesel generators produce waste heat as well as electrical power. About one-third of the fuel energy is released from the exhaust manifolds of the diesel engines and normally is not captured for useful applications. This project studied different waste heat applications that may effectively use the heat released from exhaust of Alaskan village diesel generators, selected the most desirable application, designed and fabricated a prototype for performance measurements, and evaluated the feasibili… more
Date: December 31, 2008
Creator: Lin, Chuen-Sen
Partner: UNT Libraries Government Documents Department
open access

Studies of Scale Formation and Kinetics of Crofer 22 APU and Haynes 230 in Carbon Oxide-Containing Environment for SOFC Applications

Description: Significant progress in reducing the operating temperature of SOFCs below 800oC may allow the use of chromia-forming metallic interconnects at a substantial cost savings. Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). Carbon oxides present in the hydrogen fuel can cause significant perfo… more
Date: January 1, 2006
Creator: Ziomek-Moroz, M.; Covino, B. S., Jr.; Holcomb, G. R.; Bullard, S. J. & Penner, L. R.
Partner: UNT Libraries Government Documents Department
open access

HIGH-TEMPERATURE CO-ELECTROLYSIS OF H2O AND CO2 FOR SYNGAS PRODUCTION

Description: Worldwide, the demand for light hydrocarbon fuels like gasoline and diesel oil is increasing. To satisfy this demand, oil companies have begun to utilize oil deposits of lower hydrogen content (an example is the Athabasca Oil Sands). Additionally, the higher contents of sulfur and nitrogen of these resources requires processes such as hydrotreating to meet environmental requirements. In the mean time, with the price of oil currently over $50 / barrel, synthetically-derived hydrocarbon fuels (sy… more
Date: November 1, 2006
Creator: Stoots, C.M.
Partner: UNT Libraries Government Documents Department
open access

HYBRID HETEROGENEOUS CATALYSTS FOR HYDROGENATION OF CARBON DIOXIDE

Description: HYBRID HETEROGENEOUS CATALYSTS FOR HYDROGENATION OF CARBON DIOXIDE Lucia M. Petkovic, Harry W. Rollins, Daniel M. Ginosar, and Kyle C. Burch Idaho National Laboratory P.O. Box 1625 Idaho Falls, ID 83415-2208 Introduction Anthropogenic emissions of carbon dioxide, a gas often associated with global warming, have increased considerably since the beginning of the industrial age.1 In the U.S., stationary CO2 sources, such as electricity generation plants, produce about one-third of the anthropogeni… more
Date: September 1, 2006
Creator: Petkovic, Licia M.; Rollins, Harry W.; Ginosar, Daniel M. & Burch, Kyle C.
Partner: UNT Libraries Government Documents Department
open access

Summary report : direct approaches for recycling carbon dioxide into synthetic fuel.

Description: The consumption of petroleum by the transportation sector in the United States is roughly equivalent to petroleum imports into the country, which have totaled over 12 million barrels a day every year since 2004. This reliance on foreign oil is a strategic vulnerability for the economy and national security. Further, the effect of unmitigated CO{sub 2} releases on the global climate is a growing concern both here and abroad. Independence from problematic oil producers can be achieved to a great … more
Date: January 1, 2009
Creator: Allendorf, Mark D. (Sandia National Laboratories, Livermore, CA); Ambrosini, Andrea; Diver, Richard B., Jr.; Siegel, Nathan Phillip; Miller, James Edward; Gelbard, Fred et al.
Partner: UNT Libraries Government Documents Department
open access

Engineered Particulates for Co-Firing of Diverse Feedstocks: Final Report

Description: The goal of this project is to develop a novel methodology for the formation of engineered particulates of energy-relevant material. Specifically, we aim to control interparticle cohesion in such a way as to generate macro-particles or agglomerates of several differing types of primary particles in specific proportions such that they would be of utility for co-firing applications. In Phase I of this project, we used a combination of experimentation and simulation to validate theoretically deriv… more
Date: March 1, 2004
Creator: McCarthy, Joseph J.; Jain, Kunal; Li, Hongming & Shi, Deliang
Partner: UNT Libraries Government Documents Department
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Alternative Fuels and Chemicals From Synthesis Gas Technical Progress Report: Number 31

Description: The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated … more
Date: July 1, 2002
Partner: UNT Libraries Government Documents Department
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Las Vegas Serves up Biodiesel for Local Schools

Description: This 2-page Clean Cities fact sheet describes the use of biodiesel as a fuel source in buses by the Clark County School District, located in Las Vegas, NV. It includes information on the history of the program, along with contact information for the local Clean Cities Coordinator and Clark County School District.
Date: April 1, 2004
Partner: UNT Libraries Government Documents Department
open access

CNG a Natural for Tulsa Public Schools

Description: This 2-page Clean Cities fact sheet describes the use of natural gas power for Tulsa Public Schools' fleet of buses and cars. It includes information on the history of the program, along with contact information for the local Clean Cities Coordinator and Tulsa Public Schools.
Date: April 1, 2004
Partner: UNT Libraries Government Documents Department
open access

Fuel and Fuel Additive Registration Testing of Ethanol-Diesel Blend for O2Diesel, Inc.

Description: O2 Diesel Inc. (formerly AAE Technologies Inc.) tested a heavy duty engine with O2Diesel (diesel fuel with 7.7% ethanol and additives) for regulated emissions and speciation of vapor-phase and semi-volatile hydrocarbon compounds. This testing was performed in support of EPA requirements for registering designated fuels and fuel additives as stipulated by sections 211(b) and 211(e) of the Clean Air Act.
Date: February 1, 2004
Creator: Fanick, E. R.
Partner: UNT Libraries Government Documents Department
open access

Interactions of Jet Fuels with Nitrile O-Rings: Petroleum-Derived versus Synthetic Fuels

Description: A transition from petroleum-derived jet fuels to blends with Fischer-Tropsch (F-T) fuels, and ultimately fully synthetic hydro-isomerized F-T fuels has raised concern about the fate of plasticizers in nitrile-butadiene rubber o-rings that are contacted by the fuels as this transition occurs. The partitioning of plasticizers and fuel molecules between nitrile o-rings and petroleum-derived, synthetic, and additized-synthetic jet fuels has been measured. Thermal desorption of o-rings soaked in the… more
Date: January 1, 2008
Creator: Gormley, R. J.; Link, D. D.; Baltrus, J. P. & Zandhuis, P. H.
Partner: UNT Libraries Government Documents Department
open access

What's New: Fall 2003 Update

Description: Articles focus on changes in Ford and Chrysler's MY 2004 AFV offerings, funding availability for E85 infrastructure, upcoming AFV training opportunities, growth in biodiesel, and efforts to find fleets to comply with EPAct.
Date: November 1, 2003
Partner: UNT Libraries Government Documents Department
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