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Energy dependence of metallic-encapsulated thermoluminescent dosimeters. Annual report

Description: The gamma-ray energy responses of encapsulated /sup 7/LiF and CaF/sub 2/:Mn thermoluminescent dosimeters were measured and compred to calculated values. This study was performed in order to improve the accuracy of gamma-ray heating measurements made in polyenergetic gamma-ray fields such as Argonne National Laboratory's Zero Power Reactors. Equations used in the development of the TERC/III computer code and code input parameters are specified. A section on TLD precision is also included. Compar… more
Date: June 1980
Creator: Simons, G. G.
Partner: UNT Libraries Government Documents Department
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Enhancing the use of coals by gas reburning-sorbent injection

Description: The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices; tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed tech… more
Date: December 22, 1988
Partner: UNT Libraries Government Documents Department
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Oxidation/gasification of carbon residue on retorted oil shale. Final report

Description: Studies of the oxidation and gasification of oil shale char were extended to an investigation of the effects of mineral catalysis. Six shales with differing mineral compositions were studied, including samples from the saline zone in the Western Colorado and from the Antrim shales of Michigan. Oxidation kinetics data, corrected for mass transfer effects, were compared for all six samples. A high assay shale from Utah and a sample from the saline zone were found to have the highest oxidation rat… more
Date: January 16, 1984
Creator: Thomson, W. J.
Partner: UNT Libraries Government Documents Department
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Proof of concept testing of an integrated dry injection system for SO sub x /NO sub x control

Description: The objectives of the subscale test program were designed to provide sorbent and additive selection guidance, and, in so doing, supply answers to the questions posed in the preceding section. The objectives are: Identify the best commercial hydrate sorbent and the best enhanced hydrate sorbent from a list of nine types, based upon S0{sub 2} removal at Ca/S=2. Determine the relative effectiveness of sodium sesquicarbonate versus sodium bicarbonate for S0{sub 2} and NO{sub x} control over the tem… more
Date: January 1, 1989
Creator: Helfritch, D.J.; Bortz, S.J. (Research-Cottrell, Inc., Somerville, NJ (United States). Environmental Services and Technologies Div.) & Beittel, R. (Riley Stoker Corp., Worcester, MA (United States))
Partner: UNT Libraries Government Documents Department
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RIMS diagnostics for laser desorption/laser ablation

Description: Laser desorption mass spectrometry is a useful method for interrogating materials and events at or near surfaces. Laser desorption/ablation combined with Resonance Ionization Mass Spectrometry (RIMS) provides a powerful tool to obtain information on chemical composition and speciation and, in some cases, internal and translational energy distributions. The application of this technique to the interrogation of materials and interfaces is discussed for several systems, including the analysis of c… more
Date: January 1, 1986
Creator: Apel, E. C.; Nogar, N. S.; Miller, C. M. & Estler, R. C.
Partner: UNT Libraries Government Documents Department
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The GALLEX Project

Description: The GALLEX collaboration aims at the detection of solar neutrinos in a radiochemical experiment employing 30 tons of Gallium in form of concentrated aqueous Gallium-chloride solution. The detector is primarily sensitive to the otherwise inaccessible pp-neutrinos. Details of the experiment have been repeatedly described before. Here we report the present status of implementation in the Laboratori Nazionali del Gran Sasso (Italy). So far, 12.2 tons of Gallium are at hand. The present status of de… more
Date: January 1, 1989
Creator: Kirsten, T. (Max-Planck-Institut fuer Kernphysik, Heidelberg (Germany, F.R.))
Partner: UNT Libraries Government Documents Department
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The use of BaF sub 2 buffer layers for the sputter-deposition of TlCaBaCuO thin-film superconductors

Description: Thin films of the Tl-based superconductors often have relatively poor properties because of film/substrate interdiffusion which occurs during the anneal. We have therefore investigated the use of BaF{sub 2} as a diffusion barrier. TlCaBaCuO thin films were deposited by dc magnetron sputtering onto MgO <100> substrates, both with and without an evaporation-deposited BaF{sub 2} buffer layer, and post-annealed in a Tl over-pressure. Electrical properties of the films were determined by four-point … more
Date: January 1, 1989
Creator: Hubbard, K. M.; Arendt, P. N.; Brown, D. R.; Cooke, D. W.; Elliott, N. E.; Farr, J. D. et al.
Partner: UNT Libraries Government Documents Department
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Physicochemical basis of the Na-K-Ca geothermometer

Description: Regular changes in solution composition were observed experimentally during granite reaction with dilute NaCl (+CaCl/sub 2/) solutions; these changes closely follow the empirical Na-K-Ca geothermometer relationship. Initial minerals forming the granite (quartz, plagioclase, K-feldspar, and biotite) were etched by the reactions. Alteration phases formed include calcium-zeolite at <300/sup 0/C, feldspar overgrowths at >300/sup 0/C, and minor amounts of clay and calcsilicate at all temperatures. A… more
Date: August 1, 1986
Creator: Janecky, D. R.; Charles, R. W.; Bayhurst, Gregory K. & Benjamin, T. M.
Partner: UNT Libraries Government Documents Department
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Design analysis and optimization of self-cooled lithium blankets and shields

Description: A study of self-cooled lithium blankets was carried out to define the performance of these blankets and to determine the potential to operate at the maximum possible values of the performance parameters. The main design parameters considered during the course of the study were the tritium breeding ratio, the blanket energy multiplication factor, the energy fraction lost to the shield, the total blanket thickness, the reflector material selection, and the compositions of the different blanket zo… more
Date: February 1, 1988
Creator: Gohar, Y.
Partner: UNT Libraries Government Documents Department
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High temperature fuel cell research and development. Final technical status report, 1 March 1979-31 March 1980. [Molten carbonate fuel cells]

Description: The objective of the program has been to evaluate potential materials for their chemical and physical stability in molten carbonate fuel cell electrolyte. Eleven powdered candidate materials were selected based on previous physical and chemical stability tests at elevated temperatures on solid materials and/or their thermodynamic stability with respect to proposed degradation reactions. The eleven candidate materials, plus gamma lithium aluminate, were characterized prior to corrosion testing u… more
Date: May 1, 1980
Creator: Lessing, P.A.
Partner: UNT Libraries Government Documents Department
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Cycle-life improvement of Zn/NiOOH cells by the addition of Ca(OH) sub 2 to the zinc electrode

Description: The addition of Ca(OH){sub 2} to the zinc electrode of Zn/NiOOH cells was investigated in order to determine its effect on reducing the rate of Zinc redistribution. Cells containing 0, 10, 25, and 40 mol% Ca(OH){sub 2} in the zinc electrode were constructed and tested. Ca(OH){sub 2} was found to form a calcium zincate complex with the zincate-supersaturated KOH solution created during the discharge half-cycle. As Ca(OH){sub 2} is insoluble in the electrolyte, the formation of this complex (cont… more
Date: August 1, 1989
Creator: Jain, R.; McLarnon, F. R. & Cairns, E. J.
Partner: UNT Libraries Government Documents Department
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Advances in materials science, Metals and Ceramics Division. Triannual progress report, October 1979-January 1980

Description: Progress is summarized concerning magnetic fusion energy materials, laser fusion energy, aluminium-air battery and vehicle, geothermal research, oil-shale research, nuclear waste management, office of basic energy sciences research, and materials research notes. (FS)
Date: March 31, 1980
Partner: UNT Libraries Government Documents Department
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CsAlSi/sub 5/O/sub 12/: a possible host for /sup 137/Cs immobilization

Description: CsAlSi/sub 5/O/sub 12/ exhibits more acid resistance than pollucite (CsAlSi/sub 2/O/sub 6/). At pH values of 1.02 and 1.40, the extraction of Cs from CsAlSi/sub 5/O/sub 12/ at 25/sup 0/C was approximately proportional to the square root of leach time. The Cs extraction at 25/sup 0/C varied as (H/sup +/)/sup 0/ /sup 36/ over the pH range of 1 to 6. Also, the Cs extraction in various brines at 300/sup 0/C/30 MPa was comparable with that for pollucite. CsAlSi/sub 5/O/sub 12/ can be crystallized at… more
Date: March 31, 1982
Creator: Adl, T. & Vance, E.R.
Partner: UNT Libraries Government Documents Department
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Chemical Engineering Division Fuel Cycle Programs. Quarterly progress report, January-March 1979

Description: In the program on pyrochemical and dry processing methods (PDPM) for nuclear fuel, corrosion testing of refractory metals and alloys, graphite, and SiC in PDPM environments was done. A tungsten-metallized Al/sub 2/O/sub 3/-3% Y/sub 2/O/sub 3/ crucible was successfully fabricated. Tungsten microstructure of a plasma-sprayed tungsten crucible was stabilized by nickel infiltration and heat treatment. Solubility measurements of Th in Cd and Cd-Mg alloys were continued, as were experiments to study … more
Date: January 1, 1980
Creator: Steindler, M J; Ader, M & Barletta, R E
Partner: UNT Libraries Government Documents Department
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CaO interaction in the staged combustion of coal

Description: The LIMB (limestone injection multi-stage burner) process offers special potential for reducing NO/sub x/ and SO/sub x/ by at least 50 percent in coal combustion. This is to be accomplished by adding limestone with fuel and/or air in a low NO/sub x/ burner. This program has been directed to defining the chemistry and kinetics necessary to optimize sulfur capture in LIMB combustion. More specifically, this program has attempted to clarify the role of calcium sulfide in LIMB chemistry. When limes… more
Date: December 19, 1983
Creator: Levy, Arthur; Merryman, Earl L. & Rising, Bruce W.
Partner: UNT Libraries Government Documents Department
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Light stable isotope study of the Roosevelt Hot Springs thermal area, Southwestern Utah

Description: The isotopic composition of hydrogen, oxygen, and carbon has been determined for regional cold springs, thermal fluids, and rocks and minerals from the Roosevelt Hot Springs thermal area. The geothermal system has developed within plutonic granitic rocks and amphibolite facies gneiss, relying upon fracture-controlled permeability for the migration of the thermal fluids. Probably originating as meteoric waters in the upper elevations of the Mineral Mountains, the thermal waters sampled in the pr… more
Date: May 1, 1980
Creator: D.T., Rohrs & Bowman, J.R.
Partner: UNT Libraries Government Documents Department
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Auger decay mechanism in photon-stimulated desorption of ions from surfaces

Description: Photon-stimulated desorption (PSD) of positive ions was studied with synchrotron radiation using an angle-integrating time-of-flight mass spectrometer. Ion yields as functions of photon energy near core levels were measured from condensed gases, alkali fluorides, and other alkali and alkaline earth halides. These results are compared to bulk photoabsorption measurements with emphasis on understanding fundamental desorption mechanisms. The applicability of the Auger decay mechanism, in which ion… more
Date: November 1, 1983
Creator: Parks, C.C.
Partner: UNT Libraries Government Documents Department
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Improvement of the mechanical reliability of monolithic refractory linings for coal gasification process vessels. Final report

Description: Eighteen heat-up tests were run on nine standard and experimental dual component monolithic refractory concrete linings. These tests were run with a five foot diameter by 14-ft high Pressure Vessel/Test Furnace designed to accommodate a 12-inch thick by 5-ft high refractory lining, heat the hot face to 2000/sup 0/F and expose the lining to air or steam pressures up to 150 psig. Results obtained from standard type linings in the test facility indicated that lining degradation duplicated that obs… more
Date: September 1, 1981
Creator: Potter, R.A. (comp.)
Partner: UNT Libraries Government Documents Department
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Comparison of phosgene, chlorine, and hydrogen chloride as reagents for converting molten CaO. CaCl/sub 2/ to CaCl/sub 2/

Description: One method at Los Alamos for preparing impure plutonium metal from the impure oxide is by batch reduction with calcium metal at 850/sup 0/C in a CaCl/sub 2/ solvent. The solvent salt from this reduction is currently discarded as low-level radioactivity waste only because it is saturated with the CaO byproduct. We have demonstrated a pyrochemical technique for converting the CaO to CaCl/sub 2/ thereby incorporating solvent recycling into the batch reduction process. We will discuss the effective… more
Date: January 1, 1985
Creator: Fife, K. W.
Partner: UNT Libraries Government Documents Department
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Development of an Effective Transport Media for Juvenile Spring Chinook Salmon to Mitigate Stress and Improve Smolt Survival During Columbia River Fish Hauling Operations, 1985 Final Report.

Description: Selected transport media consisting of mineral salt additions (Na/sup +/, Cl/sup -/, Ca/sup + +/, PO/sub 4//sup -3/, HCO/sub 3//sup -/, and Mg/sup + +/), mineral salts plus tranquilizing concentrations of tricaine methane sulfonate (MS-222), or MS-222 alone were tested for their ability to mitigate stress and increase smolt survival during single and mixed species hauling of Columbia River spring chinook salmon (Oncorhynchus tshawytscha) and steelhead trout (Salmo gairdneri). Successful stress … more
Date: February 1, 1985
Creator: Wedemeyer, Gary A.
Partner: UNT Libraries Government Documents Department
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Radiation damage studies related to nuclear waste forms

Description: Much of the previously reported work on alpha radiation effects on crystalline phases of importance to nuclear waste forms has been derived from radiation effects studies of composite waste forms. In the present work, two single-phase crystalline materials, Gd/sub 2/Ti/sub 2/O/sub 7/ (pyrochlore) and CaZrTi/sub 2/O/sub 7/ (zirconolite), of relative importance to current waste forms were studied independently by doping with /sup 244/Cm at the 3 wt % level. Changes in the crystalline structure me… more
Date: December 1, 1981
Creator: Gray, W.J.; Wald, J.W. & Turcotte, R.P.
Partner: UNT Libraries Government Documents Department
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Flexibility in formulating and processing SYNROC D: a current assessment

Description: In a recent series of papers, the authors have addressed the formulation, preparation, characterization and performance testing of SYNROC containing SRP defense wastes. They have also recently published a brief description of the SYNROC process flow sheets and a schematic layout of an associate processing facility. In this brief paper they summarize current data and discuss the implications of: (1) the flexibility of the SYNROC formulation to accommodate unanticipated changes in feed compositio… more
Date: March 1, 1982
Creator: Campbell, J. H.; Ryerson, F. J.; Rozsa, R. B. & Hoenig, C. L.
Partner: UNT Libraries Government Documents Department
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Workshop on sulfur chemistry in flue gas desulfurization

Description: The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)
Date: May 1, 1980
Creator: Wallace, W.E. Jr.
Partner: UNT Libraries Government Documents Department
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MAP3S precipitation chemistry network: fourth periodic summary report (1980)

Description: This, the fourth in a series of summary reports, contains complete field and chemical data from the MAP3S/RAINE (Multistate Atmospheric Power Production Pollution Studies) Precipitation Chemistry Network for the year 1980. The 1980 data were added to the previous data base, and an update of the previous statistical summary completed. Included are basic statistics, time trend analyses, and monthly averages.
Date: December 1, 1981
Partner: UNT Libraries Government Documents Department
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