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Photoinduced Charge Separation by Polymer-Bound Chromophores

Description: This project has examined the photodynamic behavior of water-soluble polymers that have covalently linked hydrophobic chromophores spaced along the chains. These polymeric systems have been examined for photoinduced charge separation with electron-accepting ions having different total charge. Focus has been on the excited singlet (S{sub 1}) state formed by laser flash absorption. The effects of pH and ionic strength -- factors that govern the conformational nature of the polymer in solution -- … more
Date: September 1, 1991
Creator: Rodgers, M. A. J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Alkali sorber (RABSAM), September 1, 1990--August 30, 1991

Description: The objective of this work is to develop a regenerable activated-bauxite sorber alkali monitor that requires no high-temperature/high-pressure sampling line for the reliable in situ measurement of alkali-vapor concentration in the exhaust from the pressurized fluidized-bed combustion of coal. 11 refs., 2 figs., 1 tab.
Date: January 1, 1991
Creator: Lee, S. H. D. & Swift, M. W.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Geothermal Materials Development, Annual Report FY 1991

Description: Advances in the development of new materials, the commercial availabilities of which are essential for the attainment of Hydrothermal Category Level I and II Objectives, continue to be made in the Geothermal Materials Development Project. Many successes have already been accrued and the results used commercially. In FY 1991, utility company sponsored full cost'' recovery programs based upon materials technology developed in this project were initiated on topics such as condensing heat exchanger… more
Date: December 1, 1991
Creator: Kukacka, L. E.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Sonic enhanced ash agglomeration and sulfur capture

Description: The major objective of the Phase 1 test program is to confirm the feasibility of the Manufacturing and Technology Conversion International, Inc. bimodal particle size approach to enhance particulate control by acoustic ash agglomeration. An ancillary objective of the Phase 1 effort is to demonstrate and confirm the feasibility of an acoustic field to enhance sulfur capture by increasing sorbent reactivity. Phase 1 tests are designed to cover the frequency range between 50 and 1400 Hz, establish… more
Date: January 1, 1991
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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NQR-NMR studies of higher alcohol synthesis Cu-Co catalysts

Description: Copper and cobalt are the key elements in syngas conversion catalyst systems used for higher alcohol synthesis. Their proximity and synergy sensitively control the selectivity and efficiency of the process. It is believed that their outer electronic charge distribution which is responsible for their electrical and magnetic properties might be governing their catalytic properties also. To examine the correlation between catalytic and magnetic properties, a series of copper cobalt catalysts (Co/C… more
Date: January 14, 1991
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Liquefaction of coals using ultra-fine particle, unsupported catalysts: In situ generation by rapid expansion of supercritical fluid solutions

Description: The program objective is to generate ultra-fine catalyst particles (20 to 400 {Angstrom} in size) and quantify their potential for improving coal dissolution in the solubilization stage of two-stage catalytic-catalytic liquefaction systems. In the first quarterly report for this program the concept behind our approach was detailed, the structure of the program was presented, key technical issues were identified, preliminary designs were outlined, and technical progress was discussed. All progre… more
Date: September 1, 1991
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Impact of Nonequilibrium Particle Temperature Considerations on Seeded Coal Combustion Plasma Properties

Description: This past quarter ending 12/30/91, the linear MHD channel simulation model has not only been completely specified but also fully modified to incorporate considerations for nonequilibrium particle temperatures. Testing of the modified model with the initial values from the first submodel (Richter's combustion zone model) and evaluation of the non-equilibrium particle temperature effect on the overall MHD performance is being held up. Reasons for the holdup is the lack of adequate response from D… more
Date: January 1, 1991
Creator: Oni, A. A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Inexpensive cross-flow hydropower turbine at Arbuckle Mountain Hydroelectric Project

Description: This report documents the first three and half years of operation and maintenance on the Arbuckle Mountain Hydroelectric Project. Located on a flashy mountain stream in northern California, the project was designed, built and tested through a Cooperative Agreement between the US DOE and OTT Engineering, Inc. (OTT). The purpose of the Agreement is to build and intensively test an inexpensive American-made cross-flow turbine and to provide information to the DOE on the cost, efficiency, operation… more
Date: July 1, 1991
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Thermodynamic model for calorimetric and phase coexistence properties of coal derived fluids

Description: On September 1, 1989 work was initiated on a project to extend the available vapor-liquid equilibrium (VLE) model for coal fluids to allow satisfactory predictions of excess enthalpies of coal liquids at high pressures. The available vapor liquid equilibrium model was developed with support from previous grant from DOE-PETC (Grant no. DE-FG22-89PC90541). The current project also involves measurement of some model compound VLE data and chromatographic characterization of coal liquids for distrib… more
Date: October 1, 1991
Creator: Kabadi, V. N.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Utilization of coal-water fuels in fire-tube boilers

Description: This project is a demonstration for firing coal-water slurry in a fire-tube boiler. It includes design, installation, and demonstration of the slurry firing equipment in a fire-tube boiler at the University of Alabama in Tuscaloosa. The project will be funded by the US Department of Energy with cost sharing from Jim Walter Resources and the University of Alabama. Energy and Environmental Research Corporation is the prime contractor responsible for all respects of the project. The specific objec… more
Date: January 1, 1991
Creator: Sommer, T. & Melick, T.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Application of optical fluctuation diagnostics to transport studies in high temperature tokamak plasmas

Description: First data was obtained from the TFTR BES system in May 1990, after the prototype 4-channel system with photomultiplier detectors from PBX-M was transferred to the TFTR Hot Cell. The system was expanded to 16 spatial channels during the Summer 1990 run period, and data of interest was obtained near the end of the run in October 1990. The most attention has been given to a radial profile data set obtained for an L-mode plasma condition in TFTR, where we characterized the nature of the long-wavel… more
Date: January 1, 1991
Creator: Fonck, R.J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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The bioenergetics of salt tolerance

Description: The aim of this project was to try to understand the adaptive mechanisms that organisms develop in order to respond to a sudden transformation in their environment to a salt shock.'' To study this problem we used a fresh water oxygenic photosynthetic cyanobacterium known as Synecoccus 6311. This organism suffers injury after this sudden exposure to high concentrations of sodium chloride equivalent to or even higher than that in sea water. Yet they are able to re-establish their photosynthetic a… more
Date: January 1, 1991
Creator: Packer, L.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Research in theoretical nuclear physics

Description: The work done during the past year covers three separate areas, low energy nuclear reactions intermediate energy physics, and nuclear structure studies. This manuscript summarizes our achievements made in these three areas.
Date: October 1, 1991
Creator: Udagawa, T.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Investigations of CuInSe sub 2 Thin Films and Contacts

Description: This report describes research into electrical contacts for copper indium diselenide (CuInSe{sub 2}) polycrystalline thin films used for solar cell applications. Molybdenum contacts have historically been the most promising for heterojunction solar cells. This program studied contact stability by investigating thermally induced bilayer reactions between molybdenum and copper, indium, and selenium. Because selenization is widely used to fabricate CuInSe{sub 2} thin films for photovoltaic cells, … more
Date: October 1, 1991
Creator: Nicolet, M. A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Complex temporal and spatial patterns in nonequilibrium systems

Description: Dynamical systems methods are being developed and used to characterize the formation and evolution of temporal and spatial patterns in systems maintained far from equilibrium. In particular, experiments and analyses are considering electrodeposition of fractal metallic clusters, pattern formation in reaction-diffusion systems, and the primary instabilities of some fluid flows. Novel reactors have been developed to search for chemical patterns (spatial variations in the chemical composition), an… more
Date: September 1, 1991
Creator: Swinney, H. L.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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(Hadamard Raman imaging)

Description: We have used newly developed holographic notch filters for obtaining both Stokes and anti-Stokes Raman images. The filters can be used as close as {plus minus}70 cm{sup {minus}1} from the Rayleigh line. We have demonstrated that they are insensitive to polarization, have 80% transmission across their clear apertures and block laser light by 10{sup 4}. The devices now have replaced sharp-cut glass filters on our microscope. We have successfully developed multispectral control and display softwar… more
Date: January 1, 1991
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Capillary liquid chromatography using laser-based and mass spectrometric detection

Description: The research performed during the past year has mainly focused on investigating and minimizing the problems listed below that limit the practical utility of these capillary electrokinetic separation techniques in chemical analysis. (1) Analyses are hindered by poor reproducibility. This is largely a result of complicated and irreproducible capillary wall-solute interactions that often result in adsorption and mobility changes. (2) While the Micellar Electrokinetic Capillary Chromatography techn… more
Date: January 1, 1991
Creator: Sepaniak, M.J. & Cook, K.D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Cationically polymerizable monomers derived from renewable sources

Description: The objective of this project is to make use of products obtained from renewable plant sources as monomers for the direct production of polymers which can be used for a wide range of plastic applications. In this report is described progress in the synthesis and polymerization of cationically polymerizable monomers and oligomers derived from botanical oils, terpenes, natural rubber, and lignin. Nine different botanical oils were obtained from various sources, characterized and then epoxidized. … more
Date: October 1, 1991
Creator: Crivello, J. V.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Ceramic technology for Advanced Heat Engines Project

Description: Significant accomplishments in fabricating ceramic components for advanced heat engine programs have provided evidence that the operation of ceramic parts in high-temperature engine environments is feasible. However, these programs have also demonstrated that additional research is needed in materials and processing development, design methodology, and database and life prediction before industry will have a sufficient technology base from which to produce reliable cost-effective ceramic engine… more
Date: July 1, 1991
Creator: Johnson, D. R.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Molecular interactions in dilute supercritical mixtures: Molecular dynamics investigation

Description: We performed a series of molecular dynamics simulations aimed at investigating the nature of the microstructure around solute molecules in a supercritical solvent, in the limit of infinite dilution (no solute-solute interactions). The choice of model system (pyrene in supercritical carbon dioxide) and state conditions (5--20 moles/liter; 37{degrees}C and 75{degrees}C) was done so as to match corresponding fluorescence experiments performed at Georgia Tech. 18 refs., 3 figs.
Date: January 1, 1991
Creator: Debenedetti, P.G.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Thin polymer icemaker development and test program

Description: We have constructed and tested a small device to produce ice in ice/water mixtures using a cold fluid as the heat sink. The device is a flexible heat exchanger constructed from a thin film of a suitable polymer. When filled with circulating liquid coolant the heat exchanger consists of an inflated series of parallel tubes; ice forms on the outside in complementary half cylinders. When the circulation is cut off, gravity drains the coolant and the static head of the water bath crushes the tubes,… more
Date: August 1, 1991
Creator: Leigh, R.W. (Pratt Inst., Brooklyn, NY (United States))
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Proposed research on advanced accelerator concepts

Description: This report summarizes technical progress and accomplishments during the proposed three-year research on advanced accelerator concepts supported by the Department of Energy under Contract No. DE-FG02-88ER40465. A vigorous theoretical program has been pursued in critical problem areas related to advanced accelerator concepts and the basic equilibrium, stability, and radiation properties of intense charged particle beams. Broadly speaking, our research has made significant contributions in the fo… more
Date: September 1, 1991
Creator: Davidson, R.C. & Wurtele, J.S.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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NQR-NMR studies of higher alcohol synthesis Cu-Co catalysts

Description: The primary objective of the project is to examine the relations between the catalytic and magnetic properties of the copper-cobalt higher alcohol synthesis catalysts. We have undertaken to investigate the magnetic character by studying the Nuclear Quadrupole resonance of copper and (Zerofield) Nuclear Magnetic Resonance of cobalt in copper cobalt catalysts.
Date: December 17, 1991
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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