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The Effect of Cl$sup -$ and So$sub 4$$sup -2$ on the Paramagnetic Resonance Line Width of Mn$sup +2$ in Aqueous Solution and the Rates of Formation of the Complex Ions

Description: The line width of one of the hynerfine components in solutions of Mn(ClO/ sub 4/)/sub 2/ containing added NaCl and Na/sub 2/SO/sub 4/ was studied from 20 to 200 deg C at 9000 Mc/sec. The chloride ion contributes littie broadening at 0.1 M below 80 deg C but considerable broadening is obtained above this temperature. The sulfate contributes broadening at all temperatures. The rates of formation of inner-sphere'' and outersphere'' complexes are discussed together with their rates of relaxation. A… more
Date: September 23, 1963
Creator: Hayes, R. G. & Myers, R. J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

THE VAPOR PRESSURES OF 30 INORGANIC LIQUIDS BETWEEN ONE ATMOSPHERE AND THE CRITICAL POINT

Description: Literature values of the vapor pressures of H/sub 2/, HD, D/sub 2/, N/ sub 2/, O/sub 2/, Ne, Ar, Kr, Xe, CO, NO, CH/sub 4/, N/sub 2/O, CO/sub 2/, HCl HBr, HI, SF/sub 6/, H/sub 2/S, Cl/sub 2/, Br/sub 2/, NH/sub 3/, C/sub 2/H/sub 2/ , SO/sub 2/, SO/sub 3/, COCl/sub 2/, HF, HCN, N/sub 2/O/sub 4/, CCl/sub 4/, and SnCl/sub 4/ were compared with the Kirchhoff formula log PK = --A/T + B between the normal boiling point and the critical point, where A and B are determined for each liquid. Plots are pre… more
Date: June 13, 1963
Creator: Edwards, D.G.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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