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Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases

Description: The Performance Demonstration Program (PDP) for headspace gases distributes blind audit samples in a gas matrix for analysis of volatile organic compounds (VOCs). Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste cha… more
Date: November 13, 2007
Creator: Office, Carlsbad Field
Partner: UNT Libraries Government Documents Department
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HYDROGEN AND VOC RETENTION IN WASTE BOXES

Description: The Hanford Waste Management Project Master Documented Safety Analysis (MDSA) (HNF-14741, 2003) identifies derived safety controls to prevent or mitigate the risks of a single-container deflagration during operations requiring moving, venting or opening transuranic (TRU)-waste containers. The issue is whether these safety controls are necessary for operations involving TRU-waste boxes that are being retrieved from burial at the Hanford Site. This paper investigates the potential for a deflagrat… more
Date: November 21, 2008
Creator: ME, PACE & RM, MARUSICH
Partner: UNT Libraries Government Documents Department
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Process development accomplishments: Waste and hazard minimization, FY 1991

Description: This report summarizes significant technical accomplishments of the Mound Waste and Hazard Minimization Program for FY 1991. The accomplishments are in one of eight major areas: environmentally responsive cleaning program; nonhalogenated solvent trials; substitutes for volatile organic compounds; hazardous material exposure minimization; nonhazardous plating development; explosive processing waste reduction; tritium capture without conversion to water; and robotic assembly. Program costs have b… more
Date: November 4, 1991
Creator: Homan, D.A.
Partner: UNT Libraries Government Documents Department
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Summary report of the drilling technologies tested at the Integrated Demonstration Project for cleanup of organic contaminants in soils and groundwater at non-arid sites

Description: The Department of Energy`s Office of Technology Development initiated an integrated demonstration of innovative technologies and systems for cleanup of volatile organic compounds in soil and groundwater at SRS. The overall goal of the program is the demonstration of multiple technologies and systems in the fields of drilling, characterization, monitoring, and remediation at a single test bed. Horizontal environmental well installation technology was one of the remediation technologies that was … more
Date: November 1, 1993
Partner: UNT Libraries Government Documents Department
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Removal of VOCs from groundwater using membrane-assisted solvent extraction

Description: A membrane-assisted solvent extraction (MASX) system coupled to a membrane-assisted distillation stripping (MADS) system for use in decontaminating groundwater is discussed. Volatile organic compounds (VOCs) are extracted in the MASX using a sunflower oil solvent. In the MADS, VOCs are stripped from the sunflower oil, and the oil is recycled to the MASX. Thermodynamic data for the sunflower oil-water-VOCs system were experimentally collected. Published membrane-mass transfer results along with … more
Date: November 1, 1992
Creator: Hutter, J. C.; Vandegrift, G. F.; Nunez, L. & Redfield, D. H.
Partner: UNT Libraries Government Documents Department
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Hazardous constituent source term. Revision 2

Description: The Department of Energy (DOE) has several facilities that either generate and/or store transuranic (TRU)-waste from weapons program research and production. Much of this waste also contains hazardous waste constituents as regulated under Subtitle C of the Resource Conservation and Recovery Act (RCRA). Toxicity characteristic metals in the waste principally include lead, occurring in leaded rubber gloves and shielding. Other RCRA metals may occur as contaminants in pyrochemical salt, soil, debr… more
Date: November 17, 1994
Partner: UNT Libraries Government Documents Department
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The Savannah River Site`s Groundwater Monitoring Program. Second quarter 1994

Description: This document contains information concerning the groundwater monitoring program at Savannah River Plant. The EPD/EMS (environmental protection department/environmental monitoring section) is responsible for monitoring constituents in the groundwater at approximately 135 waste sites in 16 areas at SRS. This report consolidates information from field reports, laboratory analysis, and quality control. The groundwater in these areas has been contaminated with radioactive materials, organic compoun… more
Date: November 1, 1994
Partner: UNT Libraries Government Documents Department
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Factors Affecting Indoor Air Concentrations of Volatile Organic Compounds at a Site of Subsurface Gasoline Contamination

Description: We report a field study of soil gas transport of volatile organic compounds (VOCs) into a slab-on-grade building found at a site contaminated with gasoline. Although the high VOC concentrations (30-60 g m{sup -3}) measured in the soil gas at depths of 0.7 m below the building suggest a potential for high levels of indoor VOC, the measured indoor air concentrations were lower than those in the soil gas by approximately six orders of magnitude ({approx} 0.03 mg m{sup -3}). This large ratio is exp… more
Date: November 1, 1995
Creator: Fischer, M. L.; Bentley, A. J.; Dunkin, K. A.; Hodgson, A. T.; Nazaroff, W. W.; Sextro, R. G. et al.
Partner: UNT Libraries Government Documents Department
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LONG-TERM STABILITY TESTING RESULTS USING SURROGATES AND SORBENTS FOR SAVANNAH RIVER SITE ORGANIC AND AQUEOUS WASTESTREAMS - 10016

Description: The U.S. Department of Energy (DOE) has tasked MSE Technology Applications, Inc. (MSE) with evaluating the long-term stability of various commercially available sorbent materials to solidify two organic surrogate wastestreams (both volatile and nonvolatile), a volatile organic surrogate with a residual aqueous phase, an aqueous surrogate, and an aqueous surrogate with a residual organic phase. The Savannah River Site (SRS) Legacy and F-Canyon plutonium/uranium extraction (PUREX) process waste s… more
Date: November 10, 2009
Creator: Burns, H.
Partner: UNT Libraries Government Documents Department
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A NEW DEVICE AND METHOD FOR MEASURING VOLATILE COMPOUNDS IN MONITORING WELLS

Description: Accurate, timely measurement of chlorinated solvents and other volatile contaminants in groundwater is crucial to support responsible environmental management. Traditionally, two distinctly different paradigms have been explored to meet this need--fixed laboratory analysis and ''real-time'' sensors. While these alternatives remain important, field based and field screening tools represent a potentially useful intermediate approach that balances some of the advantages and disadvantages of the tr… more
Date: November 6, 2006
Creator: Vangelas, K; Warren Hyde, W; Brian02 Looney, B; Kirk Cantrell, K & Tyler Gilmore, T
Partner: UNT Libraries Government Documents Department
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Probabilistic performance-assessment modeling of the mixed waste landfill at Sandia National Laboratories.

Description: A probabilistic performance assessment has been conducted to evaluate the fate and transport of radionuclides (americium-241, cesium-137, cobalt-60, plutonium-238, plutonium-239, radium-226, radon-222, strontium-90, thorium-232, tritium, uranium-238), heavy metals (lead and cadmium), and volatile organic compounds (VOCs) at the Mixed Waste Landfill (MWL). Probabilistic analyses were performed to quantify uncertainties inherent in the system and models for a 1,000-year period, and sensitivity an… more
Date: November 1, 2005
Creator: Peace, Gerald L.; Goering, Timothy James (GRAM, Inc.); Miller, Mark Laverne & Ho, Clifford Kuofei
Partner: UNT Libraries Government Documents Department
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MEMBRANE SYSTEM FOR RECOVERY OF VOLATILE ORGANIC COMPOUNDS FROM REMEDIATION OFF-GASES

Description: In situ vacuum extraction, air or steam sparging, and vitrification are widely used to remediate soil contaminated with volatile organic compounds (VOCs). All of these processes produce a VOC-laden air stream from which the VOC must be removed before the air can be discharged or recycled to the generating process. Treatment of these off-gases is often a major portion of the cost of the remediation project. Currently, carbon adsorption and catalytic incineration are the most common methods of tr… more
Date: November 17, 2003
Creator: Wijmans, J.G.
Partner: UNT Libraries Government Documents Department
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Volatilization of Fission Products from Metallic Melts in the Melt-Dilute Treatment Technology Development for Al-Based DOE Spent Nuclear Fuels

Description: The melt-dilute treatment technology is being developed to facilitate the ultimate disposition of highly enriched Al-Base DOE spent nuclear fuels in a geologic repository such as that proposed for Yucca Mountain. Currently, approximately 28 MTHM is expected to be returned to the Savannah River Site from domestic and foreign research reactors. The melt-dilute treatment technology will melt the fuel assemblies to reduce their volume and alloys them with depleted uranium to isotopically dilute the… more
Date: November 18, 1999
Creator: Adams, T.
Partner: UNT Libraries Government Documents Department
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Soil sampling and analysis plan for the Bear Creek Valley floodplain at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

Description: This Sampling and Analysis Plan (SAP) for the Bear Creek Valley (BCV) Floodplain presents the approach and rationale for characterizing potentially contaminated soils and sediments of the Bear Creek floodplain and the impact of any contaminants on the floodplain ecosystem. It is an addendum to a previously issued document, the Remedial Investigation Work Plan for Bear Creek (Y02-S600) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee (ES/ER-19&D2), which presents background information pertaini… more
Date: November 1, 1994
Partner: UNT Libraries Government Documents Department
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Chemically Selective Coated Quartz Crystal Microbalance (QCM) Array for Detection of Volatile Organic Chemicals

Description: Liquid flow cells have been fabricated to prepare an array of QCMS operating simultaneously for detection and identification of VOCS in water. TWO signals, a tlequency response and a damping voltage response, were obtained per resonator. A blank QCM was used as a reference to account for changes in liquid density and viscosity. Nine different polymer coatings applied using a spin coat technique have been examined for VOC response under liquid flow conditions. A matrix of three classes of VOCS w… more
Date: November 4, 1998
Creator: Bohuszewicz, T. V.; Frye-Mason, G. C.; Martin, S. J.; Osbourn, G. C.; Schneider, T. W. & Spates, J. J.
Partner: UNT Libraries Government Documents Department
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Rapid scanning mass spectrometer

Description: Mass spectrometers and residual gas analyzers (RGA) are used in a variety of applications for analysis of volatile and semi-volatile materials. Analysis is performed by detecting fragments of gas molecules, based on their mass to charge ratio, which are generated in the mass spectrometer. When used as a detector for a gas chromatograph, they function as a means to quantitatively identify isolated volatile species which have been separated from other species via the gas chromatograph. Vacuum Tec… more
Date: November 25, 1996
Creator: Leckey, John H. & Boeckmann, Mark D.
Partner: UNT Libraries Government Documents Department
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Catalytic effects in coal gasification. Quarterly report, April-June 1980

Description: This quarterly report, for the period April through June 1980, summarizes the activities of Sandia National Laboratories' program on mineral matter effects in coal gasification. The objective is to determine the effects of mineral matter on the devolatilization of coal and on the subsequent char gasification. We have selected a basis set of Eastern bituminous coals whose mineral matter content, as determined by x-ray analysis of low-temperature ash, ranged from less than 5% to more than 20… more
Date: November 1, 1980
Creator: Padrick, T D
Partner: UNT Libraries Government Documents Department
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X-231B technology demonstration for in situ treatment of contaminated soil: Contaminant characterization and three dimensional spatial modeling

Description: Fine-textured soils and sediments contaminated by trichloroethylene (TCE) and other chlorinated organics present a serious environmental restoration challenge at US Department of Energy (DOE) sites. DOE and Martin Marietta Energy Systems, Inc. initiated a research and demonstration project at Oak Ridge National Laboratory. The goal of the project was to demonstrate a process for closure and environmental restoration of the X-231B Solid Waste Management Unit at the DOE Portsmouth Gaseous Diffusi… more
Date: November 1, 1993
Creator: West, O. R.; Siegrist, R. L.; Mitchell, T. J.; Pickering, D. A.; Muhr, C. A.; Greene, D. W. et al.
Partner: UNT Libraries Government Documents Department
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Coal Combustion Science Quarterly Progress Report, April--June 1990

Description: This document provides a quarterly status report of the Coal Combustion Science Program that is being conducted at the Combustion, Research Facility, Sandia National Laboratories, Livermore, California. Coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 56 refs., 25 figs., 13 tabs.
Date: November 1, 1990
Creator: Hardesty, D. R. (ed.); Baxter, L. L.; Fletcher, T. H. & Mitchell, R. E.
Partner: UNT Libraries Government Documents Department
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Dual-gas tracers for subsurface characterization and NAPL detection

Description: Effective design of in situ remediation technologies often requires an understanding of the mass transfer limitations that control the removal of contaminants from the soil. In addition, the presence of nonaqueous phase liquids (NAPLs) in soils will affect the ultimate success or failure of remediation processes. Knowing the location of NAPLs within the subsurface is critical to designing the most effective remediation approach. This work focuses on demonstrating that gas tracers can detect the… more
Date: November 1, 1994
Creator: Gauglitz, P. A.; Peurrung, L. M.; Mendoza, D. P. & Pillay, G.
Partner: UNT Libraries Government Documents Department
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Integrated test plan ResonantSonic drilling system technology demonstration-1995, at the Hanford Site: Revision 1

Description: This integrated test plan describes the demonstration test of the ResonantSonic drilling system. This demonstration is part of the Office of Technology Development`s Volatile Organic Compound Arid Integrated Demonstration (VOC-Arid ID). Two main purposes of this demonstration are (1) to continue testing the ResonantSonic drilling system compatibility with the Hanford Site waste characterization programs, and (2) to transfer this method for use at the Hanford Site, other government sites, and th… more
Date: November 17, 1994
Creator: McLellan, G. W.
Partner: UNT Libraries Government Documents Department
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Use of mass spectrometric methods for field screening of VOC`s

Description: While mass spectrometric (MS) methods of chemical analysis, particularly gas chromatography-mass spectrometry (GC/MS), have been the mainstay of environmental organic analytical techniques in the laboratory through the use of EPA and other standard methods, field implementation is relatively rare. Instrumentation and methods now exist for utilizing MS and GC/MS techniques in the field for analysis of VOC`s in gas phase, aqueous, and soil media. Examples of field investigations utilizing HP 5971… more
Date: November 1, 1994
Creator: Evans, J. C.
Partner: UNT Libraries Government Documents Department
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Method of Characterizing VOC Concentration in Vented Waste Drums With Multiple Layers of Confinement Using Limited Sampling Data

Description: Characterization of transuranic waste destined for the Waste Isolation Pilot Plant currently requires detailed characterization of the volatile organic compound (VOC) concentration in the void volume headspaces (drum headspace, the large polymer bag headspace, and the innermost layers of confinement headspace) of the waste drums. A test program is underway at the Idaho National Engineering Laboratory (INEL) to determine if the drum headspace VOC concentration is representative of the concentrat… more
Date: November 1, 1994
Creator: Liekhus, Kevin J.; Vaughn, M. E.; Jensen, B. A. & Connolly, M. J.
Partner: UNT Libraries Government Documents Department
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