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Sorbent preparation/modification/additives. Final report, September 1, 1992--November 30, 1993

Description: Sorbent preparation techniques used today have generally been adapted from techniques traditionally used by the lime industry. Traditional dry hydration and slaking processes have been optimized to produce materials intended for use in the building industry. These preparation techniques should be examined with an eye to optimization of properties important to the SO{sub 2} capture process. The study of calcium-based sorbents for sulfur dioxide capture is complicated by two factors: (1) little i… more
Date: February 1, 1994
Creator: Prudich, M. E. & Venkataramakrishnan, R.
Partner: UNT Libraries Government Documents Department
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Investigation of transport process involved in FGD. Final repot, September 1, 1993--August 31, 1994

Description: The objectives of this five year plan of study are to experimentally obtain a basic understanding of (1) turbulent flow structure of the mixing zone and it influence on particle dispersion, (2) the effect of particle loading on turbulent properties and mixing, (3) the effect of jet entrainment, (4) water spray-sorbent interaction, sorbent wetting and mixing, (5) investigate the flow field where certain ratios of jet velocity to flu gas velocity result in regions of negative flow and define onse… more
Date: February 1, 1995
Creator: Kadambi, J.R.; Tien, J.S.; Yurteri, C.; Kadaba, V. & Assar, M.
Partner: UNT Libraries Government Documents Department
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Handling, transport and dispersion of sorbent powder for in-furnace injection. Final report, September 1, 1993--August 31, 1994

Description: The focus of this project is on sorbent injection technologies using dry, calcium-based sorbents for high-sulfur coal flue gas desulfurization. The goal is to provide research findings on handling, transport and dispersion of sorbent powder, aimed at improving SO{sub 2} (to at least 90%) removal and increasing sorbent utilization in a cost-effective fashion. The purpose of this project is to investigate the fundamental aspects of powder technology relevant to the fine sorbent powders, and to pr… more
Date: February 1, 1995
Creator: Fan, L.S.; Abou-Zeida, E.; Liang, S.C. & Luo, Xukun
Partner: UNT Libraries Government Documents Department
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Advanced emissions control development project. Phase I, Final report, November 1, 1993--February 19, 1996

Description: The primary objective of the Advanced Emissions Control Development Program (AECDP) is to develop practical, cost-effective strategies for reducing the emissions of air toxics from coal-fired boilers. Ideally, the project aim is to effectively control air toxic emissions through the use of conventional flue gas cleanup equipment such as electrostatic precipitators (ESP`s), fabric filters (baghouse), and wet flue gas desulfurization. B&W`s Clean Environment Development Facility (CEDF) and the AE… more
Date: February 29, 1996
Partner: UNT Libraries Government Documents Department
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New high-capacity, calcium-based sorbents, calcium silicate sorbents. Final report, 1993--August 31, 1994

Description: A search is being carried out for new calcium-based S0{sub 2} sorbents for induct injection. More specifically, a search is being carried out for induct injection calcium silicate sorbents that are highly cost effective. The objectives for the current year include the study of sorbents made from Ca(OH){sub 2}, from mixtures of Ca(OH){sub 2} and SiO{sub 2}, and from portland cement. They also include the study of sorbents made from model compounds. During this year, sorbents prepared from Ca(OH)… more
Date: February 1, 1995
Creator: Kenney, M.C.; Chiang, R.K. & Fillgrove, K.L.
Partner: UNT Libraries Government Documents Department
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Evaluation of Ohio fly ash/hydrated lime slurries and Type 1 cement sorbent slurries in the U.C. Pilot spray dryer facility. Final report, September 1, 1993--August 31, 1994

Description: The objectives of this year`s work included an evaluation of the performance of fly ash/hydrated lime as well as hydrated cement sorbents for spray drying adsorption (SDA) of SO{sub 2} from a simulated high-sulfur flue gas. These sorbents were evaluated for several different hydration methods, and under different SDA operating conditions. In addition, the physical properties of surface area and porosity of the sorbents was determined. The most reactive fly ash/hydrated lime sorbent studied was … more
Date: February 1, 1995
Creator: Keener, T. C.; Khang, S. J. & Meyers, G. R.
Partner: UNT Libraries Government Documents Department
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Development of new sorbents to remove mercury and selenium from flue gas. Final report, September 1, 1993--August 31, 1994

Description: Mercury (Hg) and selenium (Se) are two of the volatile trace metals in coal, which are often not captured by conventional gas clean up devices of coal-fired boilers. An alternative is to use sorbents to capture the volatile components of trace metals after coal combustion. In this project sorbent screening tests were performed in which ten sorbents were selected to remove metallic mercury in N{sub 2}. These sorbents included activated carbon, char prepared from Ohio No. 5 coal, molecular sieves… more
Date: February 1, 1995
Creator: Shiao, S.Y.
Partner: UNT Libraries Government Documents Department
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Control of toxic metallic emissions formed during the combustion of Ohio coals. Final report, September 1, 1993--August 31, 1994

Description: The objective of the project was to characterize metallic emissions from representative coals and develop strategies for their control. Though metallic emissions from coal combustors have been extensively studied, more studies need to be performed to better characterize the interaction of various species which is required for the selection and design of sorbents for effective control of these emissions. Some coals are rich in sulfur, and utilities using these coals will have to use some form of… more
Date: February 1995
Creator: Biswas, Pratim; Owens, T. M. & Wu, Chang-Yu
Partner: UNT Libraries Government Documents Department
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The effect of additives on lime dissolution rates. Final report, September 1, 1993--August 31, 1994

Description: In spray dryer flue gas desulfurization, lime slurry is injected into a spray dryer where it contacts with the hot flue gas and desulfurization occurs. This process is complex owing to the heat and mass transfer which must take place. One of the most important fundamental steps in the scrubbing process is the rate at which lime dissolves from the solid particle in the slurry drop and becomes available for reaction with the absorbed sulfur dioxide. This dissolution rate to a large extent control… more
Date: February 1, 1995
Creator: Keener, T. C.; Khang, S. J. & Wang, J.
Partner: UNT Libraries Government Documents Department
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Kinetic studies of dry sorbents for medium temperature application. Final report, September 1, 1993--August 31, 1994

Description: The purpose of this project is to study the fundamental nature of the sorbent reactivity and reaction kinetics in the medium temperature range from 600{degrees}F to 1200{degrees}F available in the convective pass of a boiler upstream of the economizer, where dry sorbents are injected to remove SO{sub 2} from the flue gas. Research focus is on the fundamental mechanisms of sorbent-flue gas interaction under economizer and hot baghouse conditions utilizing the experimental setup and the results o… more
Date: February 1, 1995
Creator: Khang, Soon-Jai; Keener, T. C. & Wang, Zhenwei
Partner: UNT Libraries Government Documents Department
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Adsorption and desorption of sulfur dioxide on novel adsorbents for flue gas desulfurization. Final report, September 1, 1993--August 31, 1994

Description: Dry regenerative sorption processes have recently attracted increasing attention in flue gas desulfurization (FGD) because of their several advantages over the conventional wet-scrubbing processes. Dry sorbents are usually made by coating a transition or alkaline earth metal precursor on the surface of a porous support. Major disadvantages of these sorbents prepared by the conventional methods include relatively poor attrition resistance and low SO{sub 2} sorption capacity. The physical and esp… more
Date: February 1, 1995
Creator: Lin, Y. S.
Partner: UNT Libraries Government Documents Department
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Selenium emission control at high temperatures with mineral sorbents, Final report, September 1, 1993--August 13, 1994

Description: The focus of this project is on toxic heavy metal removal by sorbent injection in the upper-furnace region of a coal-fired boiler. Selenium is chosen as the candidate heavy metal to be studied because of its high volatility and associated difficulty in removal. The preliminary sorbent screening experiments were performed in a differential reactor, built in the first year of this project. A host of sorbents, such as, alumina, kaotinite, limestone and also hydrated lime were tested at a reaction … more
Date: February 1, 1995
Creator: Fan, Liang-Shih; Ghost-Dastidar, A.; Mahuli, Suhas & Agnihotri, Rajeev
Partner: UNT Libraries Government Documents Department
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Kinetics and structural evolution of sorbents at high temperatures. Final report, September 1, 1993--August 31, 1994

Description: The focus of this project is on furnace sorbent injection technology using dry, calcium-based sorbents for flue gas desulfurization. The goal is to provide fundamental research kinetics and the effects of sorbent properties, aimed at improving S0{sub 2} removal and increasing sorbent utilization in a cost-effective fashion. The fourth year work has been carried out in three phases: (1) structural evolution of sorbent, (2) modified sorbent studies, and (3) development of mathematical model. The … more
Date: February 1, 1995
Creator: Fan, Liang-Shih; Ghosh-Dastidar, Abhijit; Mahuli, Suhas & Agnihotri, Rajeev
Partner: UNT Libraries Government Documents Department
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Role of fly ash in heavy metal removal from flue gas. Final report, September 1, 1993--August 31, 1994

Description: The primary objective of this work is to study the fundamental phenomena involved in the sorption of trace chalcophilic elements by fly ash at high and medium temperatures. Chalcophiles are the low-boiling trace elements that are volatilized during pulverized coal combustion and are transferred to the gas phase, e.g., As, Pb, Cd and Se. The main focus of this work is investigating the sorption phenomena of a representative chalcophile, arsenic (As) on fly ashes at temperatures representative of… more
Date: February 1, 1995
Creator: Bavarian, Farshad; Mahuli, Suhas; Ghosh-Dastidar, Abhijit; Agnihotri, Rajeev & Fan, Liang-Shih
Partner: UNT Libraries Government Documents Department
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Engineering Development of Advanced Physical Fine Coal Cleaning Technologies: Froth Flotation

Description: The Department of Energy (DOE) awarded a contract entitled Engineering Development of Advanced Physical Fine Coal Cleaning Technology - Froth Flotation'', to ICF Kaiser Engineers with the following team members, Ohio Coal Development Office, Babcock and Wilcox, Consolidation Coal Company, Eimco Process Equipment Company, Illinois State Geological Survey, Virginia Polytechnic Institute and State University, Process Technology, Inc. This document a quarterly report prepared in accordance with the… more
Date: February 12, 1993
Partner: UNT Libraries Government Documents Department
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Engineering Development of Advanced Physical Fine Coal Cleaning Technologies: Froth Flotation

Description: Work completed produced the criteria for additional engineering analysis, computation and detailed experimental benchscale testing for areas of uncertainty. The engineering analysis, computation, bench-scale testing and component development was formulated to produce necessary design information to define a commercially operating system. In order to produce the required information by means of bench-scale testing and component development, a uniform coal sample was procured. After agreement wit… more
Date: February 12, 1993
Partner: UNT Libraries Government Documents Department
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Engineering Development of Advanced Physical Fine Coal Cleaning Technologies: Froth Flotation. Quarterly Technical Progress Report No. 15, April 1, 1992--June 30, 1992

Description: The Department of Energy (DOE) awarded a contract entitled ``Engineering Development of Advanced Physical Fine Coal Cleaning Technology - Froth Flotation``, to ICF Kaiser Engineers with the following team members, Ohio Coal Development Office, Babcock and Wilcox, Consolidation Coal Company, Eimco Process Equipment Company, Illinois State Geological Survey, Virginia Polytechnic Institute and State University, Process Technology, Inc. This document a quarterly report prepared in accordance with t… more
Date: February 12, 1993
Partner: UNT Libraries Government Documents Department
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Engineering Development of Advanced Physical Fine Coal Cleaning Technologies: Froth Flotation. Quarterly Technical Progress Report No. 13, October 1, 1991--December 31, 1991

Description: Work completed produced the criteria for additional engineering analysis, computation and detailed experimental benchscale testing for areas of uncertainty. The engineering analysis, computation, bench-scale testing and component development was formulated to produce necessary design information to define a commercially operating system. In order to produce the required information by means of bench-scale testing and component development, a uniform coal sample was procured. After agreement wit… more
Date: February 12, 1993
Partner: UNT Libraries Government Documents Department
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