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MEASUREMENT OF SPECIFIC HEAT CAPACITY OF SALTSTONE

Description: One of the goals of the Saltstone variability study is to identify (and quantify the impact of) the operational and compositional variables that control or influence the important processing and performance properties of Saltstone grout mixtures. The heat capacity of the Saltstone waste form is one of the important properties of Saltstone mixes that was last measured at SRNL in 1997. It is therefore important to develop a core competency for rapid and accurate analysis of the specific heat capa… more
Date: September 29, 2008
Creator: Harbour, J & Vickie Williams, V
Partner: UNT Libraries Government Documents Department
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PARTNERSHIP FOR THE DEVELOPMENT OF NEXT GENERATION SIMULATION TOOLS TO EVALUATE CEMENTITIOUS BARRIERS AND MATERIALS USED IN NUCLEAR APPLICATION - 8388

Description: The US DOE has initiated a multidisciplinary cross cutting project to develop a reasonable and credible set of tools to predict the structural, hydraulic and chemical performance of cement barriers used in nuclear applications over extended time frames (e.g., > 100 years for operating facilities and > 1000 years for waste management). A partnership that combines DOE, NRC, academia, private sector, and international expertise has been formed to accomplish the project objectives by integrat… more
Date: January 29, 2008
Creator: Langton, C & Richard Dimenna, R
Partner: UNT Libraries Government Documents Department
open access

EVOLUTION OF CHEMICAL CONDITIONS AND ESTIMATED PLUTONIUM SOLUBILITY IN THE RESIDUAL WASTE LAYER DURING POST-CLOSURE AGING OF TANK 18

Description: This document updates the Eh-pH transitions from grout aging simulations and the plutonium waste release model of Denham (2007, Rev. 1) based on new data. New thermodynamic data for cementitious minerals are used for the grout simulations. Newer thermodynamic data, recommended by plutonium experts (Plutonium Solubility Peer Review Report, LA-UR-12-00079), are used to estimate solubilities of plutonium at various pore water compositions expected during grout aging. In addition, a new grout formu… more
Date: February 29, 2012
Creator: Denham, M.
Partner: UNT Libraries Government Documents Department
open access

ASSESSMENT OF THE POTENTIAL FOR HYDROGEN GENERATION DURING GROUTING OPERATIONS IN THE R AND P REACTOR VESSELS

Description: The R- and P-reactor buildings were retired from service and are now being prepared for deactivation and decommissioning (D&D). D&D activities will consist primarily of immobilizing contaminated components and structures in a grout-like formulation. Aluminum corrodes very rapidly when it comes in contact with the alkaline grout materials and as a result produces hydrogen gas. To address this potential deflagration/explosion hazard, the Materials Science and Technology Directorate (MS&am… more
Date: October 29, 2009
Creator: Wiersma, B.
Partner: UNT Libraries Government Documents Department
open access

SALTSTONE 2QCY09 TCLP RESULTS

Description: A Saltstone waste form was prepared in the Savannah River National Laboratory from a Tank 50H sample and Z-Area premix material for the second quarter of calendar year 2009 (2QCY09). After the prescribed 28 day cure, samples of the saltstone were collected, and the waste form was shown to meet the South Carolina Hazardous Waste Management Regulations (SCHWMR) R.61-79.261.24 and R.61-79.268.48(a) requirements for a nonhazardous waste form with respect to RCRA metals and underlying hazardous cons… more
Date: October 29, 2009
Creator: Reigel, M.
Partner: UNT Libraries Government Documents Department
open access

ASSESSMENT OF THE POTENTIAL FOR HYDROGEN GENERATION DURING GROUTING OPERATIONS IN THE R- AND P-REACTOR VESSELS

Description: The R- and P-reactor buildings were retired from service and are now being prepared for deactivation and decommissioning (D&D). D&D activities will consist primarily of immobilizing contaminated components and structures in a grout-like formulation. Aluminum corrodes very rapidly when it comes in contact with the alkaline grout materials and as a result produces hydrogen gas. To address this potential deflagration/explosion hazard, the Materials Science and Technology Directorate (MS&am… more
Date: December 29, 2009
Creator: Wiersma, B.
Partner: UNT Libraries Government Documents Department
open access

LITERATURE REVIEW ON THE SORPTION OF PLUTONIUM, URANIUM, NEPTUNIUM, AMERICIUM AND TECHNETIUM TO CORROSION PRODUCTS ON WASTE TANK LINERS

Description: The Savannah River Site (SRS) has conducted performance assessment (PA) calculations to determine the risk associated with closing liquid waste tanks. The PA estimates the risk associated with a number of scenarios, making various assumptions. Throughout all of these scenarios, it is assumed that the carbon-steel tank liners holding the liquid waste do not sorb the radionuclides. Tank liners have been shown to form corrosion products, such as Fe-oxyhydroxides (Wiersma and Subramanian 2002). Man… more
Date: February 29, 2012
Creator: Li, D. & Kaplan, D.
Partner: UNT Libraries Government Documents Department
open access

Grout Facilities Standby Plan

Description: This plan defines how the Grout Facilities will be deactivated to meet the intent of the recently renegotiated Tri-Party Agreement (TPA). The TPA calls for the use of the grout process as an emergency option only in the event that tank space is not available to resolve tank safety issues. The availability of new tanks is expected by 1997. Since a grout startup effort would take an estimated two years, a complete termination of the Grout Disposal Program is expected in December 1995. The former … more
Date: September 29, 1994
Creator: Claghorn, R. D.; Kison, P. F.; Nunamaker, D. R. & Yoakum, A. K.
Partner: UNT Libraries Government Documents Department
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