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in subjects: "Organic Oxygen Compounds"  
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Multiheteromacrocycles that complex metal ions. Sixth progress report, 1 May 1979-30 April 1980. [Hemispherands; spherands]

Description: Objective is to design synthesize, and evaluate cyclic and polycyclic host organic compounds for their abilities to complex and lipophilize guest metal ions, their complexes, and their clusters. Host organic compounds consist of strategically placed solvating, coordinating, and ion-pairing sites tied together by covalent bonds through hydrocarbon units around cavities shaped to be occupied by guest metal ions or by metal ions plus their ligands. Specificity in complexation is sought by matching… more
Date: January 15, 1980
Creator: Cram, D. J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Deploymerization of coal by direct solvent attack. Semi-annual report, April 1, 1983-August 31, 1983

Description: The depolymerization of Illinois No. 6 coal by a series of solvents having different basecities (pK/sub a/) and nucleophilicities (Swain-Scott nu values) showed no dependence on either the basicity of nucleophilicity of the solvents. As expected, the conversion decreases as the temperature of the reaction is reduced, but the lower the reaction temperature, the higher the percentage of amine incorporation becomes in the products. 5 tables.
Date: September 15, 1983
Creator: Larsen, J. W. & Mohammadi, M.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Enzymatic desulfurization of coal

Description: Our current efforts to develop clean coal technology emphasize the advantages of enzymatic desulfurization techniques and have specifically addressed the potential of using partially-purified extracellular microbial enzymes or commercially available enzymes. Our work is focused on the treatment of model'' organic sulfur compounds such as dibenzothiophene (DBT) and ethylphenylsulfide (EPS). Furthermore, we are designing experiments to facilitate the enzymatic process by means of a hydrated organ… more
Date: December 15, 1988
Creator: Marquis, J.K. (Boston Univ., MA (United States). School of Medicine) & Kitchell, J.P. (Holometrix, Inc., Cambridge, MA (United States))
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Synthesis of octane enhancers during slurry-phase Fischer-Tropsch

Description: The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butytl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: (1) Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch; (2) addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing … more
Date: October 15, 1991
Creator: Marcelin, G.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Fundamental studies of catalytic processing of synthetic liquids. Final report

Description: Liquids derived from coal contain relatively high amounts of oxygenated organic compounds, mainly in the form of phenols and furans that are deleterious to the stability and quality of these liquids as fuels. Hydrodeoxygenation (HDO) using Mo/W sulfide catalysts is a promising method to accomplish this removal, but our understanding of the reactions occurring on the catalyst surface during HDO is very limited. Rather than attempting to examine the complexities of real liquids and catalysts we h… more
Date: June 15, 1994
Creator: Watson, P. R.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

The solubility of uranium hexafluoride in perfluoroethers

Description: The polyperfluoroethers are compatible with uranium hexafluoride (UF/sub 6/) and are suitable for use in diffusion pumps and in mechanical vacuum pumps which rely on oil as both the lubricant and the seal. The UF/sub 6/ is soluble in all fluids with which it is compatible. Because a number of vacuum pumps in the BOP facilities of the GCEP plant employ these perfluoroether oils as the working fluid and have oil chambers which are large, questions have been raised as to the relationships governin… more
Date: July 15, 1984
Creator: Barber, E. J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Enhanced safety in the storage of fissile materials. [Boron-loaded epoxy resin]

Description: An inexpensive boron-loaded liner of epoxy resin for fissile-material storage containers was developed that can be easily fabricated of readily available, low-cost materials. Computer calculations indicate reactivity will be reduced substantially if this neutron-absorbing liner is added to containers in a typical storage array. These calculations compare favorably with neutron-attenuation experiments with thermal and fission neutron spectra, and tests at the Fire Test Facility indicate the epox… more
Date: December 15, 1978
Creator: Williams, G. E. & Alvares, N. J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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