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High temperature ceramic membrane reactors for coal liquid upgrading

Description: In this project we intend to study a novel process concept, i.e, the use of ceramic membranes reactors in upgrading of coal derived liquids. Membrane reactors have been used in a number of catalytic reaction processes in order to overcome the limitations on conversion imposed by thermodynamic equilibrium. They have, furthermore, the inherent capability for combining reaction and separation in a single step. Thus they offer promise for improving and optimizing yield, selectivity and performance … more
Date: January 1, 1992
Creator: Tsotsis, T.T.
Partner: UNT Libraries Government Documents Department
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Phosphate-bonded glass cements for geothermal wells. Final report

Description: Calcium aluminosilicate glasses were found to react with phosphoric acid in three ways depending upon silica content. Above 55% SiO/sub 2/ they are insoluble while below 50% they dissolve readily. The transition compositions release calcium and aluminum ions and a silica gel phase replaces the glass. Activation energies in the order of 10 kcal/mole are associated with the dissolution. Equilibrium studies in the systems CaO-P/sub 2/O/sub 5/-H/sub 2/O, Al/sub 2/O/sub 3/-P/sub 2/O/sub 5/-H/sub 2/O… more
Date: September 1, 1979
Creator: Rockett, T.J.
Partner: UNT Libraries Government Documents Department
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High temperature ceramic membrane reactors for coal liquid upgrading

Description: In this project we will study a novel process concept, i.e., the use of ceramic membrane reactors in upgrading of coal model compounds and coal derived liquids. In general terms, the USC research team is responsible for constructing and operating the membrane reactor apparatus and for testing various inorganic membranes for the upgrading of coal derived asphaltenes and coal model compounds. The USC effort will involve the principal investigator of this project and two graduate research assistan… more
Date: January 1, 1992
Creator: Tsotsis, T.T.
Partner: UNT Libraries Government Documents Department
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Adsorption of Krypton and Xenon by Various Materials

Description: The adsorptive capacities of various inorganic adsorbents and activated charcoals for krypton and xenon were determined. Columbia-G activated charcoal had the highest capacity for both krypton and xenon at pressures from 0.01 to 125 mm Hg and temperaturens from 2 to 85 deg C. If a value of 1 is assigned to the capacity of this charcoal at 28 deg C for krypton, other charcoals range from 0.63 to 0.84, molecular sieves (except 4A) from 0.11 to 0.20, and some silica genls from 0.05 to 0.07. Variou… more
Date: December 1, 1961
Creator: Lloyd, M. H. & McNees, R. A.
Partner: UNT Libraries Government Documents Department
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Removal of silica from Raft River geothermal water

Description: Lack of sufficient quantities of clean surface or near-surface water at Raft River for cooling purposes dictates that cooled geothermal fluid, effluent from the Raft River 5 MW(e) Pilot Power Plant, must also be used as condenser coolant. Prior testing revealed that a water-treatment system would be required to reduce silica and calcium concentrations of the cooling fluid. The water-treatment system specified was to use dolomitic lime for both pH adjustment and source of magnesium. The dolomiti… more
Date: June 1, 1980
Creator: Suciu, D. F. & Miller, R. L.
Partner: UNT Libraries Government Documents Department
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Alternate materials of construction for geothermal applications. Progress report No. 14, July--September 1977

Description: A program to determine if non-metallic materials such as polymers, concrete polymer composites, and refractory cements can be utilized as materials of construction in geothermal processes is in progress. To date, several high temperature polymer concrete systems have been formulated, laboratory and field tests performed in brine, flashing brine, and steam at temperatures up to 260/sup 0/C (500/sup 0/F), and economic studies started. Laboratory data for exposure times > 2 years are available. Re… more
Date: September 1, 1977
Creator: Kukacka, L. E.; Fontana, J.; Zeldin, A.; Sugama, T.; Horn, W.; Carciello, N. et al.
Partner: UNT Libraries Government Documents Department
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Development and evaluation of die and container materials. Final report

Description: Specific compositions of high purity silicon aluminum oxynitride (Sialon) and silicon beryllium oxynitride (Sibeon) solid solutions are shown to be promising refractory materials for handling and manipulating solar grade silicon into silicon ribbon. Well controlled processing schedules were developed for fabricating high purity Sialon and Sibeon materials. Essentially the impurity content of the hot pressed ceramics was due only to impurities from the original starting powders. A ceramic shapin… more
Date: May 1, 1979
Partner: UNT Libraries Government Documents Department
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Analysis of a neutron scattering and gamma-ray production integral and experiment on silicon dioxide for neutron energies from 1 to 15 MeV

Description: Monte Carlo calculations were made to analyze the results of an integral experiment with a sample of SiO/sub 2/ to determine the adequacy of ENDF/B-IV neutron scattering and gamma-ray production cross-section data for silicon and oxygen. The experimental results analyzed included energy-dependent NE-213 detector neutron and gamma-ray count rates at a scattering angle of 90 deg and pulse-height spectra for scattered neutrons and gamma rays. The experiments were carried out with the ORELA 1- to 2… more
Date: January 1, 1978
Creator: Cramer, S. N. & Oblow, E. M.
Partner: UNT Libraries Government Documents Department
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Development of improved iron Fischer-Tropsch catalysts

Description: The objective of proposed research is development of catalysts with enhanced slurry phase activity and better selectivity to fuel range products, through a more detailed understanding and systematic studies of the effects of pretreatment procedures and promoters/binders (silica) on catalyst performance.
Date: January 15, 1990
Creator: Bukur, D.B. & Patel, S.A.
Partner: UNT Libraries Government Documents Department
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Conditioning of geothermal brine effluents for injection: use of coagulants

Description: The use of various chemical coagulants and flocculants with spent geothermal brine for enhancing the removal of colloidal solids prior to injection was studied. Brine at 80 to 85/sup 0/C was obtained from the injection line of the SDG and E/DOE Geothermal Loop Experimental Facility during a period of operation with Magmamax No. 1 Fluid. The solids consist primarily of an iron-rich amorphous silica and heavy metal sulfides, principally lead. Standard jar testing equipment was used to carry out t… more
Date: February 1, 1978
Creator: Quong, R.; Shoepflin, F. & Stout, N.D.
Partner: UNT Libraries Government Documents Department
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Metal-insulator-semiconductor photovoltaic devices

Description: The overall objective of this program is to conduct research on metal-insulator-semiconductor (MIS) solar cells to improve understanding of the basic parameters which control photovoltaic processes in these cell structures. Current work includes fabrication, characterization, and theoretical studies of single crystal silicon-based cells, with Si0/sub x/ as the insulating film and Al or Au as the front metal contact. Studies of these two systems are intended to provide needed reference systems f… more
Date: June 1, 1979
Creator: Olsen, L. C.; Garnier, J. E. & Turcotte, R. P.
Partner: UNT Libraries Government Documents Department
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Study of brine treatment. Final report

Description: Available information pertinent to the treatment of geothermal brines was collected by literature search and then evaluated and summarized for use by the electric utility and geothermal industries. The information was screened from the geothermal, oil and gas, wastewater disposal, and boiler water treatment industries. The current state of knowledge and methodology concerning the treatment of geothermal brines to control scaling and corrosion in geothermal electric power production was assessed… more
Date: November 1, 1977
Partner: UNT Libraries Government Documents Department
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Development of improved iron Fischer-Tropsch catalysts

Description: The objective of proposed research is development of catalysts with enhanced slurry phase activity and better selectivity to fuel range products, through a more detailed understanding and systematic studies of the effects of pretreatment procedures and promoters/binders (silica) on catalyst performance.
Date: July 19, 1991
Creator: Bukur, D.B.
Partner: UNT Libraries Government Documents Department
open access

Kinetics of silica polymerization

Description: The polymerization of silicic acid in geothermal brine-like aqueous solutions to produce amorphous silica in colloidal form has been studied experimentally and theoretically. A large amount of high quality experimental data has been generated over the temperature rang 23 to 100{sup 0}C. Wide ranges of dissolved silica concentration, pH, and sodium chloride concentration were covered. The catalytic effects of fluoride and the reaction inhibiting effects of aluminum and boron were studied also. T… more
Date: May 1, 1980
Creator: Weres, O.; Yee, A. & Tsao, L.
Partner: UNT Libraries Government Documents Department
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Geology of the central Mineral Mountains, Beaver County, Utah

Description: The Mineral Mountains are located in Beaver and Millard Counties, southwestern Utah. The range is a horst located in the transition zone between the Basin and Range and Colorado Plateau geologic provinces. A multiple-phase Tertiary pluton forms most of the range, with Paleozoic rocks exposed on the north and south and Precambrian metamorphic rocks on the west in the Roosevelt Hot Springs KGRA (Known Geothermal Resource Area). Precambrian banded gneiss and Cambrian carbonate rocks have been intr… more
Date: March 1, 1980
Creator: Sibbett, B.S. & Nielson, D.L.
Partner: UNT Libraries Government Documents Department
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Anion Exchange in a Large-Scale Agitated Bed

Description: An agitated ion exchange column was adapted for use in a large radiochemical separations plant. Tests with nonradioactive solutions showed that ion exchange resin could be charged to and discharged from the column through typical plant piping and without the use of mechanical valves. With the agitator turning, the bed passed solutions containing 400 ppm of finely divided silica whereas a fixed bed became plugged. The pressure drop through the column and the absorption characteristics of an anio… more
Date: September 1, 1961
Creator: Caracciolo, V. P.
Partner: UNT Libraries Government Documents Department
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Hydrodynamic/kinetic reactions in liquid-dominated geothermal systems. Final report

Description: A mobile geothermal well-site test unit at the Mercer 2 well in South Brawley, California (Imperial Valley), was constructed and tested. The equipment controlled, monitored, and recorded all process conditions of single- and dual-flash power cycles. Single- and two-phase flashed brine effluents were flowed through piping component test sections to provide hydrodynamic/kinetic data for scale formation. The unit operated at flowrates in excess of 200 gpm and is designed to accommodate flowrates u… more
Date: April 1, 1982
Creator: Nesewich, J.P. & Gracey, C.M.
Partner: UNT Libraries Government Documents Department
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Relationship of regional water quality to aquifer thermal energy storage

Description: Ground-water quality and associated geologic characteristics may affect the feasibility of aquifer thermal energy storage (ATES) system development in any hydrologic region. This study sought to determine the relationship between ground-water quality parameters and the regional potential for ATES system development. Information was collected from available literature to identify chemical and physical mechanisms that could adversely affect an ATES system. Appropriate beneficiation techniques to … more
Date: November 1, 1983
Creator: Allen, R.D.
Partner: UNT Libraries Government Documents Department
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DETERMINATIONS OF THE KINETICS AND MECHANISMS OF DEBORONIZATION AT 1135 C

Description: The mechanisms and kinetics of the loss of boron during heating at 1135 deg C under various dynamic environments were determined from powder compacts of 5 wt% elemental boron dispersed in matrices of Fe, Cr, Ni, Si, Fe/sub 2/O/sub 3/, Cr/sub 2/O/sub 3/, NiO, and SiO/sub 2/, compacts of austenitic stainless steel alloy powder containing 0.25 wt% boron, and wrought specimens of 0.13 wt% boron-- stainless steel alloy. The compacts containing 5 wt% boron were heat treated in vacuum, highpurity argo… more
Date: September 15, 1961
Creator: Cherubini, J.H.
Partner: UNT Libraries Government Documents Department
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