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Solar-thermal energy conversion and storage: cyclohexane dehydrogenation. Progress report, 30 September 1977-30 June 1978

Description: The objective of this project is to provide research support for the benzene/cyclohexane heat pipe development program at Sandia. The kinetics of the cyclohexane decomposition (energy collection) reaction over a commercially available naphtha reforming catalyst (RD-150, Englehard Industries) in the temperature range 400 to 800/sup 0/F and pressures of 1 to 40 atmospheres were measured. Significant amounts of side products such as toluene and butane were identified at temperatures above 550/sup … more
Date: July 1, 1978
Creator: Ritter, A.B.; DeLancey, G.B.; Schneider, J. & Silla, H.
Partner: UNT Libraries Government Documents Department
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High temperature ceramic membrane reactors for coal liquid upgrading

Description: In this project we will study a novel process concept, i.e., the use of ceramic membrane reactors in upgrading of coal model compounds and coal derived liquids. In general terms, the USC research team is responsible for constructing and operating the membrane reactor apparatus and for testing various inorganic membranes for the upgrading of coal derived asphaltenes and coal model compounds. The USC effort will involve the principal investigator of this project and two graduate research assistan… more
Date: January 1, 1992
Creator: Tsotsis, T.T.
Partner: UNT Libraries Government Documents Department
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Experimental process system development unit for producing semiconductor-grade silicon using the silane-to-silicon process. Quarterly progress report, October-December 1979

Description: This program consists of the engineering design, fabrication, assembly, operation, economic analysis, and process support R and D for an Experimental Process System Development Unit (EPSDU). EPSDU equipment specification, vendor development, and evaluation of quotations represent a significant effort which will permit the start of ordering EPSDU equipment during the next quarter. Initial mini-burner test results are encouraging. It appears that a fairly simple and cost-effective waste treatment… more
Date: January 1, 1979
Partner: UNT Libraries Government Documents Department
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Advancement of flash hydrogasification. Quarterly technical progress report, October-December 1984

Description: The design of test hardware and process development unit (PDU) modifications had been completed previously. Task VII involves the fabrication of test hardware and the modification of an existing 1-ton/h hydroliquefaction PDU at Rockwell's facilities for use as a hydrogasifier test facility. Test hardware fabrication has been completed. Modifications to the PDU were completed in July 1984. The modified facility can accommodate both 10- and 20-ft-long hydrogasifier reactors so that residence time… more
Date: September 1, 1985
Creator: Falk, A. Y.
Partner: UNT Libraries Government Documents Department
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Exploratory research on solvent refined coal liquefaction. Annual technical progress report, January 1-December 31, 1979

Description: This report summarizes the progress of the Exploratory Research on Solvent Refined Coal Liquefaction project by The Pittsburg and Midway Coal Mining Co.'s Merriam Laboratory during 1979. In a series of experiments with varying feed gas composition, low levels (5 to 10 mole %) of carbon monoxide had little effect on the SRC II processing of Pittsburgh Seam coal (Powhatan No. 5 Mine) while higher levels (20 to 40 mole %) resulted in a general degradation of operability and reduced oil yields. Add… more
Date: September 1, 1980
Partner: UNT Libraries Government Documents Department
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Development of BEACON technology. Quarterly report, April-June 1982

Description: The BEACON process involves the catalytic deposition of a highly reactive form of carbon from a gas stream which contains carbon monoxide. The carbon-depleted gas is combusted with air to produce power, and the carbon is reacted with steam to produce methane or hydrogen. Experiments were continued this quarter with the objective of improving the carbon deposition efficiency using a Paraho retort off-gas mixture. Analysis has shown that the use of the Paraho off-gas to make hydrogen would be att… more
Date: March 1, 1983
Partner: UNT Libraries Government Documents Department
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Methanation in catalyst-sprayed tube wall reactors: a review

Description: The design and operation of catalyst-sprayed tube wall reactors for methanation are discussed. Reactor tubes were either coated on the inner surface or on the outer surface with a Raney nickel catalyst. A liquid coolant, which was opposite the catalyst-reactant gas-side, removed the heat of methanation. Catalyst performance, reactor operating conditions, spent catalyst analyses, and other results are presented for five PDU tests.
Date: September 1, 1980
Creator: Pennline, H. W.; Schehl, R. R.; Haynes, W. P. & Forney, A. J.
Partner: UNT Libraries Government Documents Department
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Low-cost solar array project. Task I. Silicon material. Investigation of the hydrogenation of SiCl/sub 4/

Description: Reaction kinetic measurements on the hydrochlorination of SiCl/sub 4/ and m.g. silicon metal were last reported as a function of reaction temperature, reactor pressure, H/sub 2//SiCl/sub 4/ ratio and silicon metal particle size distribution, 3 SiCl/sub 4/ + 2 H/sub 2/ + Si reversible 4 SiHCl/sub 3/. The effect of impurities in the m.g. silicon metal on the rate of this reaction has been investigated in this quarter. The m.g. silicon was replaced with high purity, electronic grade silicon metal … more
Date: October 7, 1980
Creator: Mui, J. Y. P. & Seyferth, D.
Partner: UNT Libraries Government Documents Department
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Simulation of ethylbenzene dehydrogenation in microporous catalytic membrane reactors

Description: Current state-of-the-art inorganic oxide membranes offer the potential of being modified to yield catalytic properties. The resulting modules may be configured to simultaneously induce catalytic reactions with product concentration and separation in a single processing step. Processes utilizing such catalytically active membrane reactors have the potential for dramatically increasing yield of reactions which are currently limited by either thermodynamic equilibria, product inhibition, or kineti… more
Date: April 1, 1989
Partner: UNT Libraries Government Documents Department
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Novel duplex vapor-electrochemical method for silicon solar cells. Quarterly progress report No. 7, August 1, 1977--October 31, 1977

Description: Silicon obtained by the SiF/sub 4/-Na reaction was analyzed by spark source mass spectrometry (SSMS). A partial listing of the results is given below. The concentration units in parentheses are ppM wt. B(0.1), Al(0.8), Ga(0.06), P(0.2), F(0.1), Na(1.0), V(0.04), Mo(0.3), Ti(2.0), Zr(2.0), Mn(0.1), Ni(2.0), Zn(0.01), Cu(20.0), Cr(11.0), Fe(55.0). An excellent starting material for silicon solar cells is obtained on the basis of the low levels of B, Al, Ga, P and As. The source of the Fe and Cr i… more
Date: December 1, 1977
Creator: Kapur, V.K.; Nanis, L. & Sanjurjo, A.
Partner: UNT Libraries Government Documents Department
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Process and analytical studies of enhanced low severity co-processing using selective coal pretreatment

Description: This report describes progress on research during the eleventh quarter of this contract dealing with applications of coal pretreatment techniques in coal/oil co-processing and direct hydroliquefaction. The objectives of the project are to investigate various coal pretreatment techniques and to determine the effect of these pretreatment procedures on the reactivity of the coal. Reactivity enhancement will be evaluated under both direct hydroliquefaction and co-processing conditions. Coal convers… more
Date: 1991-06~
Creator: Baldwin, R. M.; Gaur, S. & Miller, R. L.
Partner: UNT Libraries Government Documents Department
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Methane oxidation over dual redox catalysts

Description: The objective of this research is to develop approaches to direct catalytic oxidation of methane over oxides that are doubly doped with transition metal ions. The desired process aims at employing a double redox mechanism, where one redox couple is utilized for activation of oxygen and another for the trapping of CH{sub 3} radicals. The methyl radicals can either recombine, giving C{sub 2} hydrocarbons, or be converted, via electron transfer reaction, to carbocations. The latter species can rea… more
Date: September 1, 1989
Creator: Klier, Kamil; Herman, Richard G. & Sojka, Zbigniew
Partner: UNT Libraries Government Documents Department
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Particulate behavior in a controlled-profile pulverized coal-fired reactor: A study of coupled turbulent particle dispersion and thermal radiation transport

Description: This report describes recent progress in a fundamental, three-year investigation of the coupled problem of turbulent particle dispersion and thermal radiation transport. The project's objective is to make measurements of particle size, velocity, number density, temperature and wall radiant heat flux in a parametrically-controlled reactor presently existent at Brigham Young University (BYU). Although the study proposed here is primarily designed to provide experimental data not currently availab… more
Date: January 1, 1992
Creator: Queiroz, M. & Webb, B.W.
Partner: UNT Libraries Government Documents Department
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Development of BEACON technology. Quarterly report, October-December 1982

Description: The BEACON process involves the catalytic deposition of a highly reactive form of carbon from a gas stream which contains carbon monoxide. The carbon-depleted gas is combusted with air to produce power, and the carbon is reacted with steam to produce methane or hydrogen. During the quarter both SOHIO and TRW worked on catalysts which would suppress methane formation during steaming thus increasing the amount of hydrogen formed. At SOHIO a C77-K2 catalyst promoted with a Class II compound showed… more
Date: April 1, 1983
Partner: UNT Libraries Government Documents Department
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The development of an integrated multistage fluid bed retorting process. [KENTORT II process--50-lb/hr]

Description: This report summarizes the progress made on the development of an integrated multistage fluidized bed retorting process (KENTORT II). The KENTORT II process includes integral fluidized bed zone for pyrolysis, gasification, and combustion of the oil shale. The purpose of this program is to design and test the KENTORT II process at the 50-lb/hr scale. The work performed during this year involved projects that will contribute physical and chemical data for the final design of the 50-lb/hr retort. … more
Date: January 1, 1992
Creator: Carter, S.; Vego, A.; Taulbee, D. & Stehn, J.
Partner: UNT Libraries Government Documents Department
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Two-stage process for conversion of synthesis gas to high quality transportation fuels. Quarterly report, 8 June-30 September 1983

Description: The design of two large hot-flow models, to be used for slurry bubble-column hydrodynamic studies, is described. Scoping experiments were performed in smaller models to study the effects of feed-gas distributor type, column diameter, and liquid medium on gas holdup and bubble sizes. In addition, a literature review of bubble-column hydrodynamics is presented. Modifications to improve the operation and flexibility of the existing two stage pilot plant have been designed and construction initiate… more
Date: November 1, 1983
Creator: Kuo, J.C.W.
Partner: UNT Libraries Government Documents Department
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Development of BEACON technology. Quarterly report, January-March 1982

Description: The BEACON process involves the catalytic deposition of a highly reactive form of carbon from a gas stream which contains carbon monoxide. The carbon-depleted gas is combusted with air to produce power, and the carbon is reacted with steam to produce methane or hydrogen. Process conditions favoring the production of hydrogen were explored this quarter. Excess steam was found to suppress methane formation, and reduction of catalyst methanation activity was demonstrated. The effect of carbon load… more
Date: December 1, 1982
Partner: UNT Libraries Government Documents Department
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Kinetics of coal pyrolysis and devolatilization

Description: The objective of these experimental and modeling studies is to develop an improved understanding of the kinetics of coal devolatilization which is relevant to suspension firing of powdered coal. These fundamental kinetic studies address several topics related to pulverized coal combustion and include both homogeneous and heterogeneous reactions. The principal topics include: (1) the pyrolysis and devolatilization of coal; and (2) the formation of char. Research activities include small-scale ex… more
Date: January 1, 1987
Partner: UNT Libraries Government Documents Department
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Advancement of flash hydrogasification. Quarterly technical progress report, July-September 1984

Description: The design of test hardware and process development unit (PDU) modifications had been completed previously. Task VII involves the fabrication of test hardware and the modification of an existing 1-ton/h hydroliquefaction PDU at Rockwell's facilities for use as a hydrogasifier test facility. Modifications to the PDU have been completed. The modified facility is designed to accommodate both 10- and 20-ft-long hydrogasifier reactors so that residence times will be in the range of 2 to 6 s when coa… more
Date: September 1, 1985
Creator: Falk, A. Y.
Partner: UNT Libraries Government Documents Department
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The development of precipitated iron catalysts with improved stability

Description: The objective of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors. The performance targets are 88% CO+H{sub 2} conversion with less than 1% deactivation/day for 1 month and a methane and ethane selectivity of no more than 7% (based on hydrocarbons and oxygenates only) at a space velocity of at least 2 normal li… more
Date: May 6, 1992
Creator: Abrevaya, H.
Partner: UNT Libraries Government Documents Department
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Biological production of organic solvents from cellulosic wastes. Progress report, September 15, 1976--September 14, 1977

Description: The objectives of this project are to optimize a modular process to convert cellulosic wastes to butanol and other oil-sparing chemicals. Research to date has focused on developing analytical methods, establishing a good data base and improving cellulase yields. Reliable assay methods for the Thermoactinomyces cellulase complex have been developed, measuring glucose and reducing sugar from filter paper and Avicel for total cellulase activity, viscosity change with carboxymethyl cellulose for th… more
Date: June 1, 1977
Creator: Pye, E.K.; Humphrey, A.E. & Forro, J.R.
Partner: UNT Libraries Government Documents Department
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Theoretical and experimental studies of fixed-bed coal gasification reactors. Final report

Description: A laboratory fixed-bed gasification reactor was designed and built with the objective of collecting operational data for model validation and parameter estimation. The reactor consists of a 4 inch stainless steel tube filled with coal or char. Air and steam is fed at one end of the reactor and the dynamic progress of gasification in the coal or char bed is observed through thermocouples mounted at various radial and axial locations. Product gas compositions are also monitored as a function of t… more
Date: September 1, 1983
Creator: Joseph, B.; Bhattacharya, A.; Salam, L. & Dudukovic, M.P.
Partner: UNT Libraries Government Documents Department
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Report on review of hot-gas-desulfurization simulation models

Description: The removal of hydrogen sulfide and other sulfur gaseous compounds from the fuel gas of coal gasification plants using iron and zinc oxides has been accomplished with promising success. Associated with this desulfurization process is the problem of regeneration of the metal sulfides formed back to the oxide state for reuse. For the efficient design and optimum operation of process plants, it is imperative that the reaction mechanism for the gas-solid reactions be known as also the gas and solid… more
Date: February 1, 1982
Creator: Saxena, S. C.
Partner: UNT Libraries Government Documents Department
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Low cost solar array project. Quarterly progress report, January-March 1980

Description: The overall objective of the LSA Silicon Material Task is to establish a chemical process for producing silicon at a rate and rice commensurate with the production goals of the LSA project for solar-cell modules. As part of -- overall Silicon Material Task, Union Carbide developed the silane-silicon process and advanced the technology to the point where it has a definite potential for providing high-purity polysilicon on a commercial scale at a price of $14/kg by 1986 (1980 dollars). This work,… more
Date: January 1, 1980
Partner: UNT Libraries Government Documents Department
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