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Investigations of glass structure using fluorescence line narrowing and moleuclar dynamics simulations

Description: The local structure at individual ion sites in simple and multicomponent glasses is simulated using methods of molecular dynamics. Computer simulations of fluoroberyllate glasses predict a range of ion separations and coordination numbers that increases with increasing complexity of the glass composition. This occurs at both glass forming and glass modifying cation sites. Laser-induced fluorescence line-narrowing techniques provide a unique probe of the local environments of selected subsets of… more
Date: July 2, 1982
Creator: Weber, M. J. & Brawer, S. A.
Partner: UNT Libraries Government Documents Department
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Aqueous Ln(III) Luminescence Agents Derived from a Tasty Precursor

Description: The synthesis, aqueous stability and photophysical properties are reported for a novel tetradentate ligand derived from maltol, a commonly used flavor enhancer. In aqueous solution, this chelate forms stable complexes with Ln(III) cations, and sensitized emission was observed from Eu(III), Yb(III), and Nd(III). A comparison with recently reported and structurally analogous ligands reveals a slightly higher basicity but lower complex stability with Eu(III) [pEu = 14.7 (1)]. A very poor metal cen… more
Date: June 2, 2008
Creator: Jocher, C. J.; Moore, E. G.; Pierce, J. D. & Raymond, K. N.
Partner: UNT Libraries Government Documents Department
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