Metal Oxide Reactions in Complex Environments: High Electric Fields and Pressures above Ultrahigh Vacuum Page: V
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3.1. Introduction ....................................................................... 73
3.2. Experimental Methods ............................................................ 76
3.3 . R esults ............................................................................. 78
3.3.1. CleanNi3Al(110)...................................................... 78
3.3.2. AES of 7 A A1203/Ni3Al(110)....................................... 80
3.3.3. Theoretical Studies of 7 A A1203/Ni3Al(110)..................... 82
3.3.4. STM and LEED of 7 A A1203/Ni3Al(110).......................... 83
3.4. D iscussion ........................................................................ 86
3.5. C onclusions ...................................................................... 89
3.6. Chapter References ............................................................. 89
4. H20-INDUCED INSTABILITY OF A1203/Ni3Al(110) AND A1203/Ni3Al(111)
THIN FILMS UNDER NON-UHV CONDITIONS.............................. 93
4.1. Introduction ...................................................................... 93
4.2. Experimental Methods .......................................................... 97
4.3. R esults ............................................................................ 100
4.3.1. Oxidation ofNi3Al(110) and Ni3Al(111)........................... 100
4.3.2. Exposure of A1203/Ni3Al(110) and A1203/Ni3Al(111) to Water
V apor...................................................................... 104
4.4. D iscussion ......................................................................... 111
4.5. C onclusions ....................................................................... 115
4.6. Summary and Recommendations.............................................. 116
4.7. Chapter References .............................................................. 117
REFERENCE LIST............................................................................. 121
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Qin, Feili. Metal Oxide Reactions in Complex Environments: High Electric Fields and Pressures above Ultrahigh Vacuum, dissertation, August 2005; Denton, Texas. (https://digital.library.unt.edu/ark:/67531/metadc4843/m1/7/: accessed July 17, 2024), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; .