Kinetic Studies of the Reactions of Alkyl and Silyl Hydrides Page: VIII
ix, 125 leaves : ill.View a full description of this dissertation.
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LIST OF ILLUSTRATIONS
Figure Page
1. Plot of Fluorescence Intensity (I) of Br vs. Time (t) Obtained at Long Time
and Short Time Scale Resolutions in R + HBr Reaction............21
2. Plot of Pseudo-First-Order Rate Constant for Formation of Br vs. [HBr] in
n-propyl + HBr Reaction....................................22
3. Plot of Fluorescence Intensity (I) of Br vs. Time (t) for Si2H6 + Br Reaction 24
4. Plot of Fluorescence Intensity (I) of CI and I decay...................26
5. Plot of Pseudo-First-Order Rate Constant for Formation of I and loss of CI
vs. [HI] in HI + CI Reaction.................................27
6. Measurement of the Light Absorption by HBr at Wavelength of 186.5 nm
(lnlf/I) vs. [HBr] in the Pyrex Tube............................29
7. Measurement of the Light Absorption by HBr at Wavelength of 186 .5 nm
(lnl/I) vs. [HBr] in the Steel Reactor...........................30
8. Arrhenius Plot of n-Propyl + HBr Reaction........................33
9. Arrhenius Plot of Trimethylsilyl + HBr Reaction.....................37
10. Arrhenius Plot of Br + SijHe Reaction............................39
11. Modified van't Hoff Plot of the Equilibrium Constant of the Reaction
n-C3H7 + HBr C3Hg + Br..................................45
12. Modified van't Hoff Plot of the Equilibrium Constant of the Reaction
Si(CHj) + HBr ** Si(CH3)3H + Br.............................53
13. Arrhenius Plot of HI + CI Reaction...............................59
14. Plot of Pseudo-First-Order Rate Constants for Loss of H vs. [SiHJ......64
Vlll
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Yuan, Jessie (Jessie Win-Jae). Kinetic Studies of the Reactions of Alkyl and Silyl Hydrides, dissertation, August 1996; Denton, Texas. (https://digital.library.unt.edu/ark:/67531/metadc277864/m1/10/: accessed July 18, 2024), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; .