Effect of chain rigidity on conductivity of conjugated polymers Metadata

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Title

  • Main Title Effect of chain rigidity on conductivity of conjugated polymers

Creator

  • Author: Aldissi, M.
    Creator Type: Personal

Publisher

  • Name: Los Alamos National Laboratory
    Place of Publication: New Mexico
    Additional Info: Los Alamos National Lab., NM (USA)

Date

  • Creation: 1986-01-01

Language

  • English

Description

  • Content Description: There are several ways to introduce processability to conjugated polymers, and one of them is discussed here. The basic approach involves the introduction of flexible centers in a conjugated backbone with a periodicity that allows the existence of conjugated sequences characterized by an electron mobility high enough to result in electronic conduction upon oxidation or reduction. The process consists of the use of AsF/sub 5/ as a polymerization catalyst, and AsF/sub 3/ as a non-conventional medium for the reaction. The Lewis acid coupling reactions, via which the polymerization occurs, result in soluble materials. Characteristics of the materials obtained by polymerizing acetylene and some aromatic compounds are discussed.
  • Physical Description: 7 pages

Subject

  • Keyword: Chemical Reactions
  • Keyword: Organic Compounds
  • Keyword: Polyenes
  • Keyword: Fluorine Compounds
  • Keyword: Electric Conductivity
  • Keyword: Electrical Properties
  • Keyword: Polymers
  • Keyword: Physical Properties
  • Keyword: Hydrocarbons
  • Keyword: Color
  • Keyword: Organoleptic Properties
  • Keyword: Halogen Compounds
  • Keyword: Polyacetylenes
  • Keyword: Chemical Preparation
  • Keyword: Arsenic Compounds
  • Keyword: Optical Properties
  • Keyword: Arsenic Fluorides
  • Keyword: Halides
  • Keyword: Fluorides
  • STI Subject Categories: 36 Materials Science
  • Keyword: Synthesis 360404* -- Materials-- Polymers & Plastics-- Physical Properties-- (-1987)
  • Keyword: Polymerization

Source

  • Conference: International conference on science and technology of synthetic metals, Kyoto, Japan, 1 Jun 1986

Collection

  • Name: Office of Scientific & Technical Information Technical Reports
    Code: OSTI

Institution

  • Name: UNT Libraries Government Documents Department
    Code: UNTGD

Resource Type

  • Article

Format

  • Text

Identifier

  • Other: DE86011263
  • Report No.: LA-UR-86-1565
  • Report No.: CONF-8606133-2
  • Grant Number: W-7405-ENG-36
  • Office of Scientific & Technical Information Report Number: 5633473
  • Archival Resource Key: ark:/67531/metadc1089879

Note

  • Display Note: NTIS, PC A02/MF A01; 1.
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