Pressure Controlled Topochemical Polymerization in Two-Dimensional Hybrid Perovskite
Description:
Mechanical pressure offers unique control over the energy landscape of chemical reactions, opening up pathways that are inaccessible through conventional thermochemistry. We hypothesize that the reduced dimensionality defines the conformational space of the high-pressure reaction, giving rise to new selectivity that is unavailable in 3D systems. Here, we demonstrate this concept through the pressure-controlled topochemical polymerization of the diacetylene molecule deca‐3,5‐diyn‐1‐amine (DDA) i…
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Date:
December 2021
Creator:
Abu-Amara, Lama Marwan