Reductive Functionalization of 3D Metal-Methyl Complexes and Characterization of a Novel Dinitrogen Dicopper (I) Complex
Description:
Reductive functionalization of methyl ligands by 3d metal catalysts and two possible side reactions has been studied. Selective oxidation of methane, which is the primary component of natural gas, to methanol (a more easily transportable liquid) using organometallic catalysis, has become more important due to the abundance of domestic natural gas. In this regard, reductive functionalization (RF) of methyl ligands in [M(diimine)2(CH3)(Cl)] (M: VII (d3) through CuII (d9)) complexes, has been stud…
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Date:
May 2017
Creator:
Fallah, Hengameh