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Carbon-Hydrogen Bond Activation by Titanium Imido Complexes. Computational Evidence for the Role of Alkane Adducts in Selective C-H Activation

Description: This article reports calculations that probe the role of R (hydrocarbon) and R' (ligand substituent) effects on the reaction coordinate for C-H activation.
Date: January 19, 2002
Creator: Cundari, Thomas R., 1964-; Klinckman, Thomas R. & Wolczanski, Peter T.
Partner: UNT College of Arts and Sciences
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Endangered Species Act of 1973

Description: The Endangered Species Act (ESA) provides a program for the conservation of threatened and endangered plants and animals and the habitats in which they are found. The U.S. Fish and Wildlife Service (FWS) of the Department of the Interior maintains a worldwide list which, as of Feb. 20, 2008, included 1574 endangered species (599 are plants) and 351 threatened species (148 are plants). Species include birds, insects, fish, reptiles, mammals, crustaceans, flowers, grasses, and trees. Anyone can petition FWS to include a species on this list. The law requires federal agencies, in consultation with the U.S. Fish and Wildlife Service and/or the U.S. National Oceanic and Atmospheric Administration Fisheries Service, to ensure that actions they authorize, fund, or carry out are not likely to jeopardize the continued existence of any listed species or result in the destruction or adverse modification of designated critical habitat of such species. The law also prohibits any action that causes a "taking" of any listed species of endangered fish or wildlife. Likewise, import, export, interstate, and foreign commerce of listed species are all generally prohibited.
Date: January 24, 2002
Creator: United States. Congress. House.
Partner: UNT Libraries
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Development and test of single-bore CosJ Nb{sub 3}Sn dipole models with cold iron yoke

Description: Two short Nb{sub 3}Sn dipole models based on a single-bore cos-theta coil with a cold iron yoke were fabricated and tested at Fermilab. This paper summarizes the details of magnet design and fabrication procedure, and reports the test results including quench performance and quench heater studies, and the magnetic measurements.
Date: January 14, 2002
Creator: al., Alexander V Zlobin et
Partner: UNT Libraries Government Documents Department
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Commissioning and operation of the CDF silicon detector

Description: The CDF-II silicon detector has been partially commissioned and used for taking preliminary physics data. This paper is a report on commissioning and initial operations of the 5.8m{sup 2} silicon detector. This experience can be useful to the large silicon systems that are presently under construction.
Date: January 18, 2002
Creator: D'Auria, S.
Partner: UNT Libraries Government Documents Department
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Evaluation of Reservoir Wettability and its Effect on Oil Recovery

Description: The objectives of this five-year project were: (1) to achieve improved understanding of the surface and interfacial properties of crude oils and their interactions with mineral surfaces, (2) to apply the results of surface studies to improve predictions of oil production from laboratory measurements, and (3) to use the results of this research to recommend ways to improve oil recovery by waterflooding.
Date: January 29, 2002
Creator: Buckley, Jill S.
Partner: UNT Libraries Government Documents Department
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Wabash River Coal Gasification Repowering Project: A DOE Assessment

Description: The goal of the U.S. Department of Energy (DOE) Clean Coal Technology Program (CCT) is to furnish the energy marketplace with a number of advanced, more efficient, and environmentally responsible coal utilization technologies through demonstration projects. These projects seek to establish the commercial feasibility of the most promising advanced coal technologies that have developed beyond the proof-of-concept stage. This document serves as a DOE post-project assessment (PPA) of a project selected in CCT Round IV, the Wabash River Coal Gasification Repowering (WRCGR) Project, as described in a Report to Congress (U.S. Department of Energy 1992). Repowering consists of replacing an existing coal-fired boiler with one or more clean coal technologies to achieve significantly improved environmental performance. The desire to demonstrate utility repowering with a two-stage, pressurized, oxygen-blown, entrained-flow, integrated gasification combined-cycle (IGCC) system prompted Destec Energy, Inc., and PSI Energy, Inc., to form a joint venture and submit a proposal for this project. In July 1992, the Wabash River Coal Gasification Repowering Project Joint Venture (WRCGRPJV, the Participant) entered into a cooperative agreement with DOE to conduct this project. The project was sited at PSI Energy's Wabash River Generating Station, located in West Terre Haute, Indiana. The purpose of this CCT project was to demonstrate IGCC repowering using a Destec gasifier and to assess long-term reliability, availability, and maintainability of the system at a fully commercial scale. DOE provided 50 percent of the total project funding (for capital and operating costs during the demonstration period) of $438 million.
Date: January 15, 2002
Creator: National Energy Technology Laboratory (U.S.)
Partner: UNT Libraries Government Documents Department
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Novel CO2-Thickeners for Improved Mobility Control

Description: The objective of this contract was to design, synthesize, and characterize thickening agents for dense carbon dioxide and to evaluate their solubility and viscosity-enhancing potential in CO2.
Date: January 15, 2002
Creator: Enick, Dr. Robert M.; Beckman, Dr. Eric J. & Hamilton, Dr. Andrew
Partner: UNT Libraries Government Documents Department
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ViewMaps and calibration in the SIunits package

Description: The SIunits package allows for the use of world views other than the standard (std) view of dimensional quantities length, time, mass, current, temperature, and so forth. A commonly used world view says ''we work in units where c = 1,'' for example. The package must do the work to support that new relativistic world view. In this note, I want to provide concrete answers to several questions: What set of statements defines a world view; What does the SIunits Package need to know to be able to support each world view; How does this information appear in the files implementing SIunits; How can this information be derived from the defining statements, in the general case; and What facility is placed into the SIunits package to derive the needed information? An earlier document, ''World-Views in the SIunits Package,'' addressed these issues, but in the context of the needs of the earlier version of SIunits. As a starting point, let me describe the std world view as having N{sub d} dimensioned units labeled f{sub {alpha}}. Thus f{sub 1} is a meter, f{sub 2} a kilogram, f{sub 3} a second, and so forth. N{sub d} is seven but that is moot; were we to eliminate Luminosity and/or Amount of Substance, for instance, the arguments in this note would remain unchanged. And in fact for the purposes of this document we will eliminate those two, to keep any matrices displayed to a reasonable size.
Date: January 2, 2002
Creator: Fischler, Mark
Partner: UNT Libraries Government Documents Department
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Evaluation of the location and recency of faulting near prospective surface facilities in Midway Valley, Nye County, Nevada

Description: Evaluation of surface faulting that may pose a hazard to prospective surface facilities is an important element of the tectonic studies for the potential Yucca Mountain high-level radioactive waste repository in southwestern Nevada. For this purpose, a program of detailed geologic mapping and trenching was done to obtain surface and near-surface geologic data that are essential for determining the location and recency of faults at a prospective surface-facilities site located east of Exile Hill in Midway Valley, near the eastern base of Yucca Mountain. The dominant tectonic features in the Midway Valley area are the north- to northeast-trending, west-dipping normal faults that bound the Midway Valley structural block-the Bow Ridge fault on the west side of Exile Hill and the Paint-brush Canyon fault on the east side of the valley. Trenching of Quaternary sediments has exposed evidence of displacements, which demonstrate that these block-bounding faults repeatedly ruptured the surface during the middle to late Quaternary. Geologic mapping, subsurface borehole and geophysical data, and the results of trenching activities indicate the presence of north- to northeast-trending faults and northwest-trending faults in Tertiary volcanic rocks beneath alluvial and colluvial sediments near the prospective surface-facilities site. North to northeast-trending faults include the Exile Hill fault along the eastern base of Exile Hill and faults to the east beneath the surficial deposits of Midway Valley. These faults have no geomorphic expression, but two north- to northeast-trending zones of fractures exposed in excavated profiles of middle to late Pleistocene deposits at the prospective surface-facilities site appear to be associated with these faults. Northwest-trending faults include the West Portal and East Portal faults, but no disruption of Quaternary deposits by these faults is evident. The western zone of fractures is associated with the Exile Hill fault. The eastern zone of fractures is within Quaternary alluvial sediments, …
Date: January 17, 2002
Creator: Swan, F.H.; Wesling, J.R.; Angell, M.M.; Thomas, A.P.; Whitney, J.W. & Gibson, J.D.
Partner: UNT Libraries Government Documents Department
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THROUGH-THE-EARTH (TTE) COMMUNICATIONS SYSTEM AND THE IN-MINE POWER LINE (IMPL) COMMUNICATIONS SYSTEM

Description: Work has progressed on both subsystems: the Through-the-Earth (TTE) Communications system and the In-Mine Power Line (IMPL) Communications system. The TTE system: The system was fabricated and repackaged as an industrial product enclosed in a commercial rugged, waterproof housing suitable for installation in mines. Features were added to the system to appeal to the preferences of different mine managers. Arrangements were made with NIOSH to install the system in the Lake Lynn underground mine for evaluation and demonstration to potential users. The IMPL system: Voice compression was successfully implemented and incorporated into the laboratory model. Compressed voice was transmitted through a power line, expanded at the receiving end, and received with high clarity.
Date: January 1, 2002
Creator: Meiksin, Zvi H.
Partner: UNT Libraries Government Documents Department
open access

Chiral Langrangian with confinement from the QCD Langrangian

Description: An effective Langrangian for the light quark in the field of a static source is derived systematically using the exact field correlator expansion. The lowest Gaussian term is bosonized using nonlocal colorless bosonic fields and a general structure of effective chiral Langrangian is obtained containing all set of fields. The new and crucial result is that the condensation of scalar isoscalar field which is a usual onset of chiral symmetry breaking and is constant in space-time, assumes here the form of the confining string and contributes to the confining potential while the rest bosonic fields describe mesons with the q{rvec q} quark structure and pseudoscalars play the role of Nambu-Goldstone fields. Using derivative expansion the effective chiral Langrangian is deduced containing both confinement and chiral effects for heavy-light mesons. The pseudovector quark coupling constant is computed to be exactly unity in the local limit in agreement with earlier large N{sub c} arguments.
Date: January 1, 2002
Creator: Simonov, Yu A.
Partner: UNT Libraries Government Documents Department
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Magnetic designs and field quality of Nb{sub 3}Sn accelerator magnets

Description: This paper presents a new approach to accelerator magnet design, based on simple and robust single-layer coils with minimum number of turns arranged horizontally or vertically in a common iron yoke. Cos-theta and block type coil geometries as well as cold and warm iron yoke designs were studied. Coils and yokes were optimized for the maximum field, minimum field harmonics, and minimum sizes.
Date: January 14, 2002
Creator: Kashikhin, Vadim V. & Zlobin, Alexander V.
Partner: UNT Libraries Government Documents Department
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The Next Linear Collider: NLC2001

Description: Recent studies in elementary particle physics have made the need for an e{sup +}e{sup -} linear collider able to reach energies of 500 GeV and above with high luminosity more compelling than ever [1]. Observations and measurements completed in the last five years at the SLC (SLAC), LEP (CERN), and the Tevatron (FNAL) can be explained only by the existence of at least one particle or interaction that has not yet been directly observed in experiment. The Higgs boson of the Standard Model could be that particle. The data point strongly to a mass for the Higgs boson that is just beyond the reach of existing colliders. This brings great urgency and excitement to the potential for discovery at the upgraded Tevatron early in this decade, and almost assures that later experiments at the LHC will find new physics. But the next generation of experiments to be mounted by the world-wide particle physics community must not only find this new physics, they must find out what it is. These experiments must also define the next important threshold in energy. The need is to understand physics at the TeV energy scale as well as the physics at the 100-GeV energy scale is now understood. This will require both the LHC and a companion linear electron-positron collider. A first Zeroth-Order Design Report (ZDR) [2] for a second-generation electron-positron linear collider, the Next Linear Collider (NLC), was published five years ago. The NLC design is based on a high-frequency room-temperature rf accelerator. Its goal is exploration of elementary particle physics at the TeV center-of-mass energy, while learning how to design and build colliders at still higher energies. Many advances in accelerator technologies and improvements in the design of the NLC have been made since 1996. This Report is a brief update of the …
Date: January 14, 2002
Creator: al., D. Burke et
Partner: UNT Libraries Government Documents Department
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The CDF-II silicon tracking system

Description: The CDFII silicon tracking system, SVX, for Run II of the Fermilab Tevatron has up to 8 cylindrical layers with average radii spanning from {approx} (1.5 to 28.7) cm, and lengths ranging from {approx} (90 to 200) cm for a total active-area of {approx} 6 m{sup 2} and {approx} 7.2 x 10{sup 5} readout channels. SVX will improve the CDFII acceptance and efficiency for both B and high-Pt physics dependent upon b-tagging. Along with the description of the SVX we report some alignment survey data from the SVX assembly phase and the actual status of the alignment as it results from the offline data analysis. The problems encountered are also reviewed.
Date: January 18, 2002
Creator: al., F. Palmonari et
Partner: UNT Libraries Government Documents Department
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U.S. Department of Energy University Reactor Sharing Program at the University of Florida. Final report for period August 15, 2000 - May 31, 2001

Description: Department of Energy Grant Number DE-FG02-96NE38152 was supplied to the University of Florida Training Reactor (UFTR) facility through the U.S. Department of Energy's University Reactor Sharing Program. The renewal proposal submitted in January 2000 originally requested over $73,000 to support various external educational institutions using the UFTR facilities in academic year 2000-01. The actual Reactor Sharing Grant was only in the amount of $40,000, all of which has been well used by the University of Florida as host institution to support various educational institutions in the use of our reactor and associated facilities as indicated in the proposal. These various educational institutions are located primarily within the State of Florida. However, when the 600-mile distance from Pensacola to Miami is considered, it is obvious that this Grant provides access to reactor utilization for a broad geographical region and a diverse set of user institutions serving over fourteen million inhabitants throughout the State of Florida and still others throughout the Southeast.
Date: January 1, 2002
Creator: Vernetson, William G.
Partner: UNT Libraries Government Documents Department
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The Ohio State University Reactor Sharing Program [August 15, 2000 - May 31, 2001]

Description: During the period from August 15, 2000 through may 31, 2001 the Ohio State University (OSU) Research Reactor participated in the Reactor Sharing Program by providing services to nine colleges and universities and four secondary school organizations. A total of about 17 faculty and 170 students utilized their facilities. The staff of the OSU Research Reactor is generally involved in four types of experiments at the Nuclear Reactor Laboratory. Included are introductions to nuclear research, neutron activation analysis, material irradiation, and classes that measure various reactor parameters.
Date: January 4, 2002
Creator: Myser, Richard D.
Partner: UNT Libraries Government Documents Department
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R and D for a single-layer Nb{sub 3}Sn common coil dipole using the react-and-wind fabrication technique

Description: A dipole magnet based on the common coil design, using prereacted Nb{sub 3}Sn superconductor, is under development at Fermilab, for a future Very Large Hadron Collider. This magnet has some innovative design and technological features such as single layer coils, a 22 mm wide 60-strand Rutherford type cable and stainless steel collars reinforced by horizontal bridges inserted between coil blocks. Both left and right coils are wound simultaneously into the collar structure and then impregnated with epoxy. In order to optimize the design and fabrication techniques an R&D program is underway. The production of cables with the required characteristics was shown possible. Collar laminations were produced, assembled and tested in order to check the effectiveness of the bridges and the validity of the mechanical design. A mechanical model consisting of a 165 mm long section of the magnet straight section was assembled and tested. This paper summarizes the status of the program, and reports the results of fabrication and test of cable, collars and the mechanical model.
Date: January 14, 2002
Creator: al., Giorgio Ambrosio et
Partner: UNT Libraries Government Documents Department
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Phase mixing of chaotic orbits as an irreversible ''relaxation'' mechanism

Description: Orbits that are chaotic will tend to phase-mix exponentially through their accessible phase space. This phenomenon, commonly called ''chaotic mixing'', stands in marked contrast to phase mixing of regular orbits. It is inherently irreversible, and thus its associated e-folding time scale sets a condition on any process envisioned for emittance compensation. Accordingly, two questions arise. First, under what conditions does chaotic mixing manifest itself in beams? Second, when it is active, over what time scale does it operate? The work described here is part of an ongoing effort to answer these questions.
Date: January 15, 2002
Creator: al., C.L. Bohn et
Partner: UNT Libraries Government Documents Department
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