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Kinetics of the Alkylation and Acylation of Nickel Dipivaloyimethide

Description: Abstract: A study was made of the reactions of nickel dipivaloyimethide with the following reagents: tirphenylmethyl chloride, benzoyl chloride, [rho]-chloro and [rho]-methyl benzoyl chloride. Infrared spectra of the easily hydrolyzed product of tritylation seem to indicate that enol ether, the product of O-alkylation, is formed. the acyl halides reactor to give the triketones. the latter have been characterized by spectra and C, H, analysis. the kinetics of all the reactions studied were found to settle down to a second order rate law after a fast initial reaction. These reactions are catalyzed by an impurity in the acyl chloride. Then benzoyl chloride with a different purity was used, the second order rate constant for the benzoylation of nickel DPM ranged from 0.02-0.20. The air oxidation of nickel dipivaloymethide was found to compete with the acylations under the conditions of these studies. An investigation of the phenomenon showed that nickel pivalate is the major product. Pivalic acid was also detected in the product mixture. This oxidation takes place in chlorobenzene and in aromatic hydrocarbons. It occurs in 1201 when small amount on benzoyl chlorides are present.
Date: July 1959
Creator: Johnson, Kenneth Eugene & Hammond, George Simms, 1921-2005
Partner: UNT Libraries Government Documents Department

[Girl interview on Teen-Age Downbeat]

Description: Photograph of host Tom Mullarkey, another man, and a girl on the WBAP-TV Teen-Age Downbeat show. Mullarkey holds a microphone and appears to be interviewing the girl. They are standing in front of a background decorated with school pennants. A young boy can be seen to the far right of the image.
Date: July 15, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Produce section of grocery store]

Description: Photograph of a produce section of the Hills Store. In the middle is a long display of vegetables and fruits. From left to right: potatoes, pineapples, melons, and potatoes in bags. At the end of the display is a weigh station. On the back wall is a refrigerated display of more produce, like peas, cabbage, and cucumbers. Each one has a price label hanging above it from the mirror that sits behind it. Above this display large cans are stacked up and organize by label. On a small shelf on the wall above this, five more rows of cans are stacked up. On the back left wall is a similar display of produce, with empty metal buckets stacked on top of it.
Date: July 11, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Grocery Store Aisle]

Description: Photograph of aisles of products inside of a grocery store. Numbers are included above the aisles as well as key items found in the aisles. Some of the products pictured include Vigoro Rose Food and End-O-Pest. The aisles are fully stocked with products.
Date: July 11, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Location of Richardson Coiffures]

Description: Photograph of a slide advertising the beauty shop Richardson Coiffures. The background of the slide is an image of the building where the shop is located which is two stories. The building is brick with a Spanish tile roof and there are three brick pillars in the center of the image. Between these pillars are intricate metal railings on the second story and there are windows for the shops set between the pillars on both floors. In between the pillars on the first floor, there is a black rectangle with white text in it that reads "Richardson Coiffures 3313 Winthrop Ridglea".
Date: July 6, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[People on the City Hall Program]

Description: Photograph of a woman and men seated behind a curved counter. There are two microphones in front of them, and electric lights hang from the ceiling. To the right, a man is seen looking down at his hands. A WBAP-TV video camera is visible to the left of the image.
Date: July 15, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Market advertisement depicting a family]

Description: Photograph of a slide with an illustration of a family. The illustration depicts a woman with shoulder length hair standing behind a man who is wearing a tie and a young boy. The man and woman are depicted from the shoulders up while only the boy's head is visible. To the right of them is text in quotes that reads "The People's Market Place". The background of the slide is black while the text and illustration are white.
Date: July 6, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Group of people at a picnic]

Description: Photograph of people either standing or sitting in chairs under the trees at a picnic. There are picnic tables, chairs and boxes scattered around them.
Date: July 15, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Meat counter at Hills Store]

Description: Photograph of the meat department counter in Hills Store. The counter has glass sides so that the meat inside is visible. The leftmost stretch of counter is filled with different cuts of beef and the prices for the meat are at the bottom of the window and stuck in the meat itself. The middle counter is filled with different cuts of pork and the contents of the rightmost counter are not visible. There are scales and boxes of wax paper on top of the counter.
Date: July 11, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Star Telegram slide]

Description: Photograph of a slide depicting a man in a suit with a coin for a head. He is wearing a suit and running to the right. The coin has a dollar sign on it, and he is smiling. There is a small hat sitting on top of the coin, and he is holding a brief case. Writing to the right of him reads, "For pennies a day!"
Date: July 6, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Two girls outside playing volleyball]

Description: Photograph of two girls outside playing volleyball. One girl can be seen jumping to hit the volleyball as it flies over the net. Two children are watching the game in the background.
Date: July 15, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Men engage in conversation on set]

Description: Photograph of three men engaging in conversation on set. They are seated behind a curved counter. There are objects in front of them and a backdrop of the city in the background. A WBAP-TV video camera is visible to the right of the image.
Date: July 15, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Girl on Teen-Age Downbeat]

Description: Photograph of host Tom Mullarkey on the WBAP-TV Teen-Age Downbeat show. He is putting a black eye mask with an elastic band on a girl's face. Another man is standing to the left of the image. To the far right, a group of children are visible in the background.
Date: July 15, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Three men at picnic]

Description: Photograph of three men among Dr. Pepper and Coca-Cola bottles in crates and many others. They are surrounded by trees and a WBAP-TV truck is visible to the right. The man on the right, wearing a plaid shirt, is Bob Gould.
Date: July 15, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Remember]

Description: Photograph of a slide depicting a hand that is pointing to the left and has it's thumb out. A thread is tied in a bow around the end of the finger. To the left of the drawing is the word, "remember."
Date: July 6, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Photograph of produce section]

Description: Photograph of a produce section of a grocery store. In the center is a long display full of a variety of vegetables and fruits, from left to right, potatoes, pineapples, melons, and bagged potatoes. On the left wall is a display with a wall mirror holding bagged produce. The display has metal buckets stacked on top of it. The back wall has a long, mirrored display of more produce, including peas, lettuce, cucumbers, etc. On top of this display are large cans stacked up, and above that a shelf holding more large cans. There are price labels spread throughout every section. In the middle there is a weighing station. On the bottom halves of the mirrored displays there are locked cabinets. Hanging from the ceiling is three long light fixtures. On the back wall, to the right of the shelf is a painting of a large dog.
Date: July 11, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Five men in suits]

Description: Photograph of five men wearing suits and ties standing in a room. The two men on the left are facing the men standing in the middle. The three other men are looking at the camera.
Date: July 8, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[People at P.G.W. Convention]

Description: Photograph of people at the P.G.W. Convention. The space is filled with people dressed in formal attire and making conversations with one another. In the center, a woman is shaking hands with a man wearing glasses.
Date: July 8, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections

[Roy Bacus and group at long table]

Description: Photograph of Roy Bacus and a group of men sitting and eating meals together at long tables. There are many plates and cups on the table. Behind them, the walls are covered in plant wallpaper. Everyone is wearing formal attire.
Date: July 8, 1959
Creator: WBAP-TV (Television station : Fort Worth, Tex.)
Partner: UNT Libraries Special Collections
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