Chlorotriammineplatinum(II) Ion : Acid Hydrolysis and Isotopic Exchange of Chloride Ligand
Description:
Abstract: The acid hydrolysis of [Pt(NH3)3Cl] has been shown to occur to a measurable extent. for this reaction: [APt(NH3)cCl]+ + H2O [chemical equilibrium symbol with rate constant k-1 above and k1 below] [Pt(NH3)c(H2O)]++ + Cl-, the equilibrium quotient was measured at 25 degree C and 35 degree C. At 25 degree C this quotient was 8.4 x 10-5 at [Mu] (ionic strength) = 0 and 25 x 10-5 at [mu] = .318 M. This variation is consistent with the expected changes in activity coefficients. [Delta]H …
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Date:
May 15, 1961
Creator:
Aprile, Ferruccio. & Martin, Don S., Jr.
Partner:
UNT Libraries Government Documents Department