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Hindered Diffusion of Asphaltenes at Elevated Temperature and Pressure Progress Report

Description: During this time period, we performed experiments to examine the effects of solvent composition on the diffusion controlled uptake of quinoline into alumina catalyst pellets. Of particular interest was the effect of solvent aromaticity on the diffusive uptake process. The uptake experiments were performed at a temperature of 300 C for the adsorptive diffusion of quinoline in a solvent mixture of mineral oil and 1-methyl naphthalene onto alumina catalyst pellets. These experiments were conducted… more
Date: April 1, 1999
Creator: Guin, James A. & Vadlamani, Surya
Partner: UNT Libraries Government Documents Department
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Hindered Diffusion of Asphaltenes at Elevated Temperature and Pressure Progress Report

Description: The mathematical model which we have developed previously for diffusion controlled adsorption was extended to allow for the inclusion of the effects of extraparticle film mass transfer resistance as embodied in a finite Sherwood number. A Mathcad based program was used to simulate the experimental data using summation of a large number of terms in the infinite series solution. Parametric studies and accompanying plots revealed that the effects of film resistance on the uptake process were found… more
Date: April 1, 2001
Creator: Guin, James A.; Ramakrishnan, Ganesh; Asada, Keiji & Mosley, Brian
Partner: UNT Libraries Government Documents Department
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Hindered Diffusion of Asphaltenes at Elevated Temperature and Pressure Progress Report

Description: During this past six months we continued our ongoing studies of the diffusion controlled uptake of coal and petroleum asphaltenes into a porous carbon catalyst. Toluene was used as the solvent for experiments at 20 C and 75 C while 1-methylnaphthalene was the solvent for the higher temperature experiments at 100 C, 150 C and 250 C. All runs were made at a pressure of 250 psi (inert He gas). Experiments were performed at 20 C and 75 C, for the petroleum asphaltene/toluene system. For the coal as… more
Date: April 7, 2000
Creator: Guin, James A.; Ramakrishnan, Ganesh & Asada, Keiji
Partner: UNT Libraries Government Documents Department
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